Synthesis and self-assembly study of two-armed polymers containing crown ether core

Xiao Shuang Feng; Li Feng Yan; Jie Wen; Cai Yuan Pan

doi:10.1016/S0032-3861(02)00116-7

Synthesis and self-assembly study of two-armed polymers containing crown ether core

Xiao Shuang Feng, Li Feng Yan, Jie Wen, Cai Yuan Pan

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

Two functional crown ether initiator, bis[4′-(2-bromobutyryl)]dibenzo-18-crown-6 (BBDC) was synthesized through the condensation of dibenzo-18-crown-6 with 2-bromobutyric acid in the presence of polyphosphoric acid. Atom transfer radical polymerizations of styrene (St), methyl acrylate, methyl methacrylate and butyl acrylate were carried out in bulk to produce the polymers with well-controlled molecular weights and narrow molecular weight distributions (1.12-1.32). Based on 1H NMR results, both the two bromides of BBDC initiated the polymerizations. The well-defined two-armed polymers were self-assemblized in the presence of potassium cations. Their morphologies of the film obtained were studied by atomic force microscopy with tapping mode. © 2002 Elsevier Science Ltd. All rights reserved.

Original language	English (US)
Pages (from-to)	3131-3137
Number of pages	7
Journal	Polymer
Volume	43
Issue number	10
DOIs	https://doi.org/10.1016/S0032-3861(02)00116-7
State	Published - Mar 18 2002
Externally published	Yes

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Generated from Scopus record by KAUST IRTS on 2023-09-21

ASJC Scopus subject areas

Organic Chemistry
Polymers and Plastics

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10.1016/S0032-3861(02)00116-7

Cite this

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title = "Synthesis and self-assembly study of two-armed polymers containing crown ether core",

abstract = "Two functional crown ether initiator, bis[4′-(2-bromobutyryl)]dibenzo-18-crown-6 (BBDC) was synthesized through the condensation of dibenzo-18-crown-6 with 2-bromobutyric acid in the presence of polyphosphoric acid. Atom transfer radical polymerizations of styrene (St), methyl acrylate, methyl methacrylate and butyl acrylate were carried out in bulk to produce the polymers with well-controlled molecular weights and narrow molecular weight distributions (1.12-1.32). Based on 1H NMR results, both the two bromides of BBDC initiated the polymerizations. The well-defined two-armed polymers were self-assemblized in the presence of potassium cations. Their morphologies of the film obtained were studied by atomic force microscopy with tapping mode. {\textcopyright} 2002 Elsevier Science Ltd. All rights reserved.",

author = "Feng, {Xiao Shuang} and Yan, {Li Feng} and Jie Wen and Pan, {Cai Yuan}",

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T1 - Synthesis and self-assembly study of two-armed polymers containing crown ether core

AU - Feng, Xiao Shuang

AU - Yan, Li Feng

AU - Wen, Jie

AU - Pan, Cai Yuan

N1 - Generated from Scopus record by KAUST IRTS on 2023-09-21

PY - 2002/3/18

Y1 - 2002/3/18

N2 - Two functional crown ether initiator, bis[4′-(2-bromobutyryl)]dibenzo-18-crown-6 (BBDC) was synthesized through the condensation of dibenzo-18-crown-6 with 2-bromobutyric acid in the presence of polyphosphoric acid. Atom transfer radical polymerizations of styrene (St), methyl acrylate, methyl methacrylate and butyl acrylate were carried out in bulk to produce the polymers with well-controlled molecular weights and narrow molecular weight distributions (1.12-1.32). Based on 1H NMR results, both the two bromides of BBDC initiated the polymerizations. The well-defined two-armed polymers were self-assemblized in the presence of potassium cations. Their morphologies of the film obtained were studied by atomic force microscopy with tapping mode. © 2002 Elsevier Science Ltd. All rights reserved.

AB - Two functional crown ether initiator, bis[4′-(2-bromobutyryl)]dibenzo-18-crown-6 (BBDC) was synthesized through the condensation of dibenzo-18-crown-6 with 2-bromobutyric acid in the presence of polyphosphoric acid. Atom transfer radical polymerizations of styrene (St), methyl acrylate, methyl methacrylate and butyl acrylate were carried out in bulk to produce the polymers with well-controlled molecular weights and narrow molecular weight distributions (1.12-1.32). Based on 1H NMR results, both the two bromides of BBDC initiated the polymerizations. The well-defined two-armed polymers were self-assemblized in the presence of potassium cations. Their morphologies of the film obtained were studied by atomic force microscopy with tapping mode. © 2002 Elsevier Science Ltd. All rights reserved.

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U2 - 10.1016/S0032-3861(02)00116-7

DO - 10.1016/S0032-3861(02)00116-7

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VL - 43

SP - 3131

EP - 3137

JO - Polymer

JF - Polymer

IS - 10

ER -

Synthesis and self-assembly study of two-armed polymers containing crown ether core

Abstract

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ASJC Scopus subject areas

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