Synthesis and morphology research of framework Ti-rich TS-1 containing no extraframework Ti species in the presence of CO2

Guowei Zhu; Lei Ni; Wei Qi; Shuang Ding; Xiaoxin Li; Runwei Wang; Shilun Qiu

doi:10.1016/j.inoche.2013.11.026

Synthesis and morphology research of framework Ti-rich TS-1 containing no extraframework Ti species in the presence of CO2

Guowei Zhu, Lei Ni, Wei Qi, Shuang Ding, Xiaoxin Li, Runwei Wang, Shilun Qiu

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

A new method to synthesis TS-1 has been developed using the carbon dioxide (CO2) as an alkalinity regulator that resulted in the increased framework Ti contents. The prepared catalyst had a Si/Ti ratio as low as 40 in contrast to the ratio of 56 prepared through conventional synthesis. The twin crystals with the length of 2 μm were formed via introduction of CO 2. The catalytic activity of TS-1 is remarkably enhanced compared with the conventional synthesis. © 2013 Elsevier B.V.

Original language	English (US)
Pages (from-to)	129-132
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	40
DOIs	https://doi.org/10.1016/j.inoche.2013.11.026
State	Published - Feb 2014
Externally published	Yes

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledged KAUST grant number(s): CRG-1-2012-LAI-009
Acknowledgements: This work was supported by the National Basic Research Program of China (2011CB808703, 2012CB821700), "111" project (B07016) and Award Project of KAUST (CRG-1-2012-LAI-009).
This publication acknowledges KAUST support, but has no KAUST affiliated authors.

Access to Document

10.1016/j.inoche.2013.11.026

Cite this

@article{8f0ca4e11fb4445593f0513536e71004,

title = "Synthesis and morphology research of framework Ti-rich TS-1 containing no extraframework Ti species in the presence of CO2",

abstract = "A new method to synthesis TS-1 has been developed using the carbon dioxide (CO2) as an alkalinity regulator that resulted in the increased framework Ti contents. The prepared catalyst had a Si/Ti ratio as low as 40 in contrast to the ratio of 56 prepared through conventional synthesis. The twin crystals with the length of 2 μm were formed via introduction of CO 2. The catalytic activity of TS-1 is remarkably enhanced compared with the conventional synthesis. {\textcopyright} 2013 Elsevier B.V.",

author = "Guowei Zhu and Lei Ni and Wei Qi and Shuang Ding and Xiaoxin Li and Runwei Wang and Shilun Qiu",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledged KAUST grant number(s): CRG-1-2012-LAI-009 Acknowledgements: This work was supported by the National Basic Research Program of China (2011CB808703, 2012CB821700), {"}111{"} project (B07016) and Award Project of KAUST (CRG-1-2012-LAI-009). This publication acknowledges KAUST support, but has no KAUST affiliated authors.",

year = "2014",

month = feb,

doi = "10.1016/j.inoche.2013.11.026",

language = "English (US)",

volume = "40",

pages = "129--132",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Synthesis and morphology research of framework Ti-rich TS-1 containing no extraframework Ti species in the presence of CO2

AU - Zhu, Guowei

AU - Ni, Lei

AU - Qi, Wei

AU - Ding, Shuang

AU - Li, Xiaoxin

AU - Wang, Runwei

AU - Qiu, Shilun

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledged KAUST grant number(s): CRG-1-2012-LAI-009 Acknowledgements: This work was supported by the National Basic Research Program of China (2011CB808703, 2012CB821700), "111" project (B07016) and Award Project of KAUST (CRG-1-2012-LAI-009). This publication acknowledges KAUST support, but has no KAUST affiliated authors.

PY - 2014/2

Y1 - 2014/2

N2 - A new method to synthesis TS-1 has been developed using the carbon dioxide (CO2) as an alkalinity regulator that resulted in the increased framework Ti contents. The prepared catalyst had a Si/Ti ratio as low as 40 in contrast to the ratio of 56 prepared through conventional synthesis. The twin crystals with the length of 2 μm were formed via introduction of CO 2. The catalytic activity of TS-1 is remarkably enhanced compared with the conventional synthesis. © 2013 Elsevier B.V.

AB - A new method to synthesis TS-1 has been developed using the carbon dioxide (CO2) as an alkalinity regulator that resulted in the increased framework Ti contents. The prepared catalyst had a Si/Ti ratio as low as 40 in contrast to the ratio of 56 prepared through conventional synthesis. The twin crystals with the length of 2 μm were formed via introduction of CO 2. The catalytic activity of TS-1 is remarkably enhanced compared with the conventional synthesis. © 2013 Elsevier B.V.

UR - http://hdl.handle.net/10754/599831

UR - https://linkinghub.elsevier.com/retrieve/pii/S1387700313005340

UR - http://www.scopus.com/inward/record.url?scp=84890844196&partnerID=8YFLogxK

U2 - 10.1016/j.inoche.2013.11.026

DO - 10.1016/j.inoche.2013.11.026

M3 - Article

SN - 1387-7003

VL - 40

SP - 129

EP - 132

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -

Synthesis and morphology research of framework Ti-rich TS-1 containing no extraframework Ti species in the presence of CO2

Abstract

Bibliographical note

Access to Document

Other files and links

Fingerprint

Cite this