Synthesis and immobilization of polystyreneb-polyvinyltriethoxysilane micelles

Saisai Zhu; Hui Zhu; Ru Xia; Xiaoshuang Feng; Peng Chen; Jiasheng Qian; Ming Cao; Bin Yang; Jibin Miao; Lifen Su; Changjiang Song

doi:10.1007/s11595-018-1809-9

Synthesis and immobilization of polystyreneb-polyvinyltriethoxysilane micelles

Saisai Zhu, Hui Zhu, Ru Xia, Xiaoshuang Feng, Peng Chen, Jiasheng Qian, Ming Cao, Bin Yang, Jibin Miao, Lifen Su, Changjiang Song

Physical Sciences and Engineering

Research output: Contribution to journal › Article › peer-review

Abstract

Diblock copolymers polystyrene-block-polyvinyltriethoxysilane (PS-b-PVTES) were synthesized via atom transfer radical polymerization (ATRP), which self-assembled into spherical micelles in solvent of THF-methanol mixtures. The self-assembled micelles were immobilized by cross-linking reaction of VTES in a shell layer of micelles. The chemical structures of block copolymers and morphology of micelles were characterized in detail. It was found that the size of immobilized micelles was strongly affected by the copolymer concentration, composition of mixture solvent, and block ratios.

Original language	English (US)
Pages (from-to)	221-225
Number of pages	5
Journal	Journal of Wuhan University of Technology-Mater. Sci. Ed.
Volume	33
Issue number	1
DOIs	https://doi.org/10.1007/s11595-018-1809-9
State	Published - Jan 31 2018

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: Funded by the National Natural Science Foundation of China (Nos. 51403001, 20804001, 20974001, 21174001, 51273001), the Research Fund for the Doctoral Program of Higher Education of China (No.20113401110003), “211 Project” and “Incubation Fund for Excellent Young Researcher” of Anhui University

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@article{1518d84a3fd34d35a86168800f561939,

title = "Synthesis and immobilization of polystyreneb-polyvinyltriethoxysilane micelles",

abstract = "Diblock copolymers polystyrene-block-polyvinyltriethoxysilane (PS-b-PVTES) were synthesized via atom transfer radical polymerization (ATRP), which self-assembled into spherical micelles in solvent of THF-methanol mixtures. The self-assembled micelles were immobilized by cross-linking reaction of VTES in a shell layer of micelles. The chemical structures of block copolymers and morphology of micelles were characterized in detail. It was found that the size of immobilized micelles was strongly affected by the copolymer concentration, composition of mixture solvent, and block ratios.",

author = "Saisai Zhu and Hui Zhu and Ru Xia and Xiaoshuang Feng and Peng Chen and Jiasheng Qian and Ming Cao and Bin Yang and Jibin Miao and Lifen Su and Changjiang Song",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: Funded by the National Natural Science Foundation of China (Nos. 51403001, 20804001, 20974001, 21174001, 51273001), the Research Fund for the Doctoral Program of Higher Education of China (No.20113401110003), “211 Project” and “Incubation Fund for Excellent Young Researcher” of Anhui University",

year = "2018",

month = jan,

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doi = "10.1007/s11595-018-1809-9",

language = "English (US)",

volume = "33",

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journal = "Journal of Wuhan University of Technology-Mater. Sci. Ed.",

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TY - JOUR

T1 - Synthesis and immobilization of polystyreneb-polyvinyltriethoxysilane micelles

AU - Zhu, Saisai

AU - Zhu, Hui

AU - Xia, Ru

AU - Feng, Xiaoshuang

AU - Chen, Peng

AU - Qian, Jiasheng

AU - Cao, Ming

AU - Yang, Bin

AU - Miao, Jibin

AU - Su, Lifen

AU - Song, Changjiang

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: Funded by the National Natural Science Foundation of China (Nos. 51403001, 20804001, 20974001, 21174001, 51273001), the Research Fund for the Doctoral Program of Higher Education of China (No.20113401110003), “211 Project” and “Incubation Fund for Excellent Young Researcher” of Anhui University

PY - 2018/1/31

Y1 - 2018/1/31

N2 - Diblock copolymers polystyrene-block-polyvinyltriethoxysilane (PS-b-PVTES) were synthesized via atom transfer radical polymerization (ATRP), which self-assembled into spherical micelles in solvent of THF-methanol mixtures. The self-assembled micelles were immobilized by cross-linking reaction of VTES in a shell layer of micelles. The chemical structures of block copolymers and morphology of micelles were characterized in detail. It was found that the size of immobilized micelles was strongly affected by the copolymer concentration, composition of mixture solvent, and block ratios.

AB - Diblock copolymers polystyrene-block-polyvinyltriethoxysilane (PS-b-PVTES) were synthesized via atom transfer radical polymerization (ATRP), which self-assembled into spherical micelles in solvent of THF-methanol mixtures. The self-assembled micelles were immobilized by cross-linking reaction of VTES in a shell layer of micelles. The chemical structures of block copolymers and morphology of micelles were characterized in detail. It was found that the size of immobilized micelles was strongly affected by the copolymer concentration, composition of mixture solvent, and block ratios.

UR - http://hdl.handle.net/10754/627280

UR - http://link.springer.com/article/10.1007/s11595-018-1809-9

UR - http://www.scopus.com/inward/record.url?scp=85041289928&partnerID=8YFLogxK

U2 - 10.1007/s11595-018-1809-9

DO - 10.1007/s11595-018-1809-9

M3 - Article

SN - 1000-2413

VL - 33

SP - 221

EP - 225

JO - Journal of Wuhan University of Technology-Mater. Sci. Ed.

JF - Journal of Wuhan University of Technology-Mater. Sci. Ed.

IS - 1

ER -

Synthesis and immobilization of polystyreneb-polyvinyltriethoxysilane micelles

Abstract

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