Synthesis and characterization of Y2Ru2O7 and Y2-xPrxRu2O7 for cathode application in intermediate temperature solid oxide fuel cells

Chiara Abate; Keith Duncan; Vincenzo Esposito; Enrico Traversa; Eric D. Wachsman

doi:10.1149/1.2215560

Synthesis and characterization of Y₂Ru₂O₇ and Y_2-xPr_xRu₂O₇ for cathode application in intermediate temperature solid oxide fuel cells

Chiara Abate^*, Keith Duncan, Vincenzo Esposito, Enrico Traversa, Eric D. Wachsman

^*Corresponding author for this work

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

5 Scopus citations

Abstract

Nanocrystalline powders of Y₂Ru₂O₇ and Y_2-xPr_xRu₂O₇ were prepared by a co-precipitation method. Pr was chosen as the Asite dopant in order to increase the electrical conductivity of Y₂Ru₂O₇. Phase and morphology were studied by XRD and FE-SEM, which showed both systems exhibit a particle size of about 100 nm, and the doped powders were single pyrochlore phase. The electrical conductivity of a dense bar of Y_2-x Pr _xRu₂O₇ was measured at several temperatures by d.c. 4-probe method, while the electrochemical properties of Y_2-x Pr_xRu₂O₇ pyrochlores were tested in contact to ESB electrolytes, using Electrochemical Impedance Spectroscopy (EIS) in air. The Y_2-xPr_xRu₂O₇ on ESB electrolyte solid-state cells presents a significant decrease of electrodes impedance. copyright The Electrochemical Society.

Original language	English (US)
Title of host publication	Solid State Ionic Devices IV
Publisher	Electrochemical Society Inc.
Pages	255-261
Number of pages	7
Edition	7
ISBN (Print)	1566774942, 9781566774949
DOIs	https://doi.org/10.1149/1.2215560
State	Published - 2006
Externally published	Yes
Event	4th International Symposium on Solid-State Ionic Devices - 208th Meeting of the Electrochemical Society - Los Angeles, CA, United States Duration: Oct 16 2005 → Oct 21 2005

Publication series

Name	ECS Transactions
Number	7
Volume	1
ISSN (Print)	1938-5862
ISSN (Electronic)	1938-6737

Other

Other	4th International Symposium on Solid-State Ionic Devices - 208th Meeting of the Electrochemical Society
Country/Territory	United States
City	Los Angeles, CA
Period	10/16/05 → 10/21/05

ASJC Scopus subject areas

General Engineering

Access to Document

10.1149/1.2215560

Cite this

@inproceedings{228aa131a3b04a319fec50942e4298c8,

title = "Synthesis and characterization of Y2Ru2O7 and Y2-xPrxRu2O7 for cathode application in intermediate temperature solid oxide fuel cells",

abstract = "Nanocrystalline powders of Y2Ru2O7 and Y2-xPrxRu2O7 were prepared by a co-precipitation method. Pr was chosen as the Asite dopant in order to increase the electrical conductivity of Y2Ru2O7. Phase and morphology were studied by XRD and FE-SEM, which showed both systems exhibit a particle size of about 100 nm, and the doped powders were single pyrochlore phase. The electrical conductivity of a dense bar of Y2-x Pr xRu2O7 was measured at several temperatures by d.c. 4-probe method, while the electrochemical properties of Y2-x PrxRu2O7 pyrochlores were tested in contact to ESB electrolytes, using Electrochemical Impedance Spectroscopy (EIS) in air. The Y2-xPrxRu2O7 on ESB electrolyte solid-state cells presents a significant decrease of electrodes impedance. copyright The Electrochemical Society.",

author = "Chiara Abate and Keith Duncan and Vincenzo Esposito and Enrico Traversa and Wachsman, {Eric D.}",

year = "2006",

doi = "10.1149/1.2215560",

language = "English (US)",

isbn = "1566774942",

series = "ECS Transactions",

publisher = "Electrochemical Society Inc.",

number = "7",

pages = "255--261",

booktitle = "Solid State Ionic Devices IV",

edition = "7",

note = "4th International Symposium on Solid-State Ionic Devices - 208th Meeting of the Electrochemical Society ; Conference date: 16-10-2005 Through 21-10-2005",

}

Abate, C, Duncan, K, Esposito, V, Traversa, E & Wachsman, ED 2006, Synthesis and characterization of Y₂Ru₂O₇ and Y_2-xPr_xRu₂O₇ for cathode application in intermediate temperature solid oxide fuel cells. in Solid State Ionic Devices IV. 7 edn, ECS Transactions, no. 7, vol. 1, Electrochemical Society Inc., pp. 255-261, 4th International Symposium on Solid-State Ionic Devices - 208th Meeting of the Electrochemical Society, Los Angeles, CA, United States, 10/16/05. https://doi.org/10.1149/1.2215560

Synthesis and characterization of Y₂Ru₂O₇ and Y_2-xPr_xRu₂O₇ for cathode application in intermediate temperature solid oxide fuel cells. / Abate, Chiara; Duncan, Keith; Esposito, Vincenzo et al.
Solid State Ionic Devices IV. 7. ed. Electrochemical Society Inc., 2006. p. 255-261 (ECS Transactions; Vol. 1, No. 7).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

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T1 - Synthesis and characterization of Y2Ru2O7 and Y2-xPrxRu2O7 for cathode application in intermediate temperature solid oxide fuel cells

AU - Abate, Chiara

AU - Duncan, Keith

AU - Esposito, Vincenzo

AU - Traversa, Enrico

AU - Wachsman, Eric D.

PY - 2006

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N2 - Nanocrystalline powders of Y2Ru2O7 and Y2-xPrxRu2O7 were prepared by a co-precipitation method. Pr was chosen as the Asite dopant in order to increase the electrical conductivity of Y2Ru2O7. Phase and morphology were studied by XRD and FE-SEM, which showed both systems exhibit a particle size of about 100 nm, and the doped powders were single pyrochlore phase. The electrical conductivity of a dense bar of Y2-x Pr xRu2O7 was measured at several temperatures by d.c. 4-probe method, while the electrochemical properties of Y2-x PrxRu2O7 pyrochlores were tested in contact to ESB electrolytes, using Electrochemical Impedance Spectroscopy (EIS) in air. The Y2-xPrxRu2O7 on ESB electrolyte solid-state cells presents a significant decrease of electrodes impedance. copyright The Electrochemical Society.

AB - Nanocrystalline powders of Y2Ru2O7 and Y2-xPrxRu2O7 were prepared by a co-precipitation method. Pr was chosen as the Asite dopant in order to increase the electrical conductivity of Y2Ru2O7. Phase and morphology were studied by XRD and FE-SEM, which showed both systems exhibit a particle size of about 100 nm, and the doped powders were single pyrochlore phase. The electrical conductivity of a dense bar of Y2-x Pr xRu2O7 was measured at several temperatures by d.c. 4-probe method, while the electrochemical properties of Y2-x PrxRu2O7 pyrochlores were tested in contact to ESB electrolytes, using Electrochemical Impedance Spectroscopy (EIS) in air. The Y2-xPrxRu2O7 on ESB electrolyte solid-state cells presents a significant decrease of electrodes impedance. copyright The Electrochemical Society.

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