Synthesis and characterization of novel alcohol-soluble ladderlike poly(silsesquioxane)s containing side-chain hydroxy groups

Chunqing Liu; Yang Liu; Zhongrong Shen; Ping Xie; Daorong Dai; Rongben Zhang; Chaobin He; Taisheng Chung

doi:10.1002/1521-3935(20010601)202:9<1576::AID-MACP1576>3.0.CO;2-E

Synthesis and characterization of novel alcohol-soluble ladderlike poly(silsesquioxane)s containing side-chain hydroxy groups

Chunqing Liu, Yang Liu, Zhongrong Shen, Ping Xie, Daorong Dai, Rongben Zhang^*, Chaobin He, Taisheng Chung

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

39 Scopus citations

Abstract

Two novel kinds of alcohol-soluble ladderlike poly(silsequioxane)s containing side-chain hydroxy groups (OH-T₂) were prepared successfully for the first time by hydrolysis of ladderlike poly(silses-quioxane)s with side-chain ester groups (Ester-T₁ and Ester-T₂), which were synthhhesized by stepwise coupling polymerization. A variety of characterization methods including FT-IR, ¹H NMR, ¹³C NMR, ²⁹Si NMR, differential scanning calorimetry (VPO), gel permeation chromatography (GPC), and X-ray diffraction (XRD) were combined to demonstrate that the obtained alcohol-soluble polymers have ladderlike structures. although some structural defects still existed.

Original language	English (US)
Pages (from-to)	1576-1580
Number of pages	5
Journal	Macromolecular Chemistry and Physics
Volume	202
Issue number	9
DOIs	https://doi.org/10.1002/1521-3935(20010601)202:9<1576::AID-MACP1576>3.0.CO;2-E
State	Published - Jul 6 2001
Externally published	Yes

ASJC Scopus subject areas

Condensed Matter Physics
Physical and Theoretical Chemistry
Polymers and Plastics
Organic Chemistry
Materials Chemistry

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10.1002/1521-3935(20010601)202:9<1576::AID-MACP1576>3.0.CO;2-E

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title = "Synthesis and characterization of novel alcohol-soluble ladderlike poly(silsesquioxane)s containing side-chain hydroxy groups",

abstract = "Two novel kinds of alcohol-soluble ladderlike poly(silsequioxane)s containing side-chain hydroxy groups (OH-T2) were prepared successfully for the first time by hydrolysis of ladderlike poly(silses-quioxane)s with side-chain ester groups (Ester-T1 and Ester-T2), which were synthhhesized by stepwise coupling polymerization. A variety of characterization methods including FT-IR, 1H NMR, 13C NMR, 29Si NMR, differential scanning calorimetry (VPO), gel permeation chromatography (GPC), and X-ray diffraction (XRD) were combined to demonstrate that the obtained alcohol-soluble polymers have ladderlike structures. although some structural defects still existed.",

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year = "2001",

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T1 - Synthesis and characterization of novel alcohol-soluble ladderlike poly(silsesquioxane)s containing side-chain hydroxy groups

AU - Liu, Chunqing

AU - Liu, Yang

AU - Shen, Zhongrong

AU - Xie, Ping

AU - Dai, Daorong

AU - Zhang, Rongben

AU - He, Chaobin

AU - Chung, Taisheng

PY - 2001/7/6

Y1 - 2001/7/6

N2 - Two novel kinds of alcohol-soluble ladderlike poly(silsequioxane)s containing side-chain hydroxy groups (OH-T2) were prepared successfully for the first time by hydrolysis of ladderlike poly(silses-quioxane)s with side-chain ester groups (Ester-T1 and Ester-T2), which were synthhhesized by stepwise coupling polymerization. A variety of characterization methods including FT-IR, 1H NMR, 13C NMR, 29Si NMR, differential scanning calorimetry (VPO), gel permeation chromatography (GPC), and X-ray diffraction (XRD) were combined to demonstrate that the obtained alcohol-soluble polymers have ladderlike structures. although some structural defects still existed.

AB - Two novel kinds of alcohol-soluble ladderlike poly(silsequioxane)s containing side-chain hydroxy groups (OH-T2) were prepared successfully for the first time by hydrolysis of ladderlike poly(silses-quioxane)s with side-chain ester groups (Ester-T1 and Ester-T2), which were synthhhesized by stepwise coupling polymerization. A variety of characterization methods including FT-IR, 1H NMR, 13C NMR, 29Si NMR, differential scanning calorimetry (VPO), gel permeation chromatography (GPC), and X-ray diffraction (XRD) were combined to demonstrate that the obtained alcohol-soluble polymers have ladderlike structures. although some structural defects still existed.

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Synthesis and characterization of novel alcohol-soluble ladderlike poly(silsesquioxane)s containing side-chain hydroxy groups

Abstract

ASJC Scopus subject areas

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