Synthesis and characterization of fused pyrrolo[3,2- d:4,5- d' ]bisthiazole-containing polymers

Mohammed Al-Hashimi; John G. Labram; Scott Watkins; Majid Motevalli; Thomas D. Anthopoulos; Martin Heeney

doi:10.1021/ol102344m

Synthesis and characterization of fused pyrrolo[3,2- d:4,5- d' ]bisthiazole-containing polymers

Mohammed Al-Hashimi, John G. Labram, Scott Watkins, Majid Motevalli, Thomas D. Anthopoulos, Martin Heeney

Research output: Contribution to journal › Article › peer-review

37 Scopus citations

Abstract

The synthesis of a novel electron-deficient fused pyrrolo[3,2-d:4,5-d'] bisthiazole is reported from 2-bromothiazole. This was copolymerized with thiophene, selenophene, thienothiophene, and bithiophene by microwave-assisted Stille polycondensation. The resulting polymers exhibited small optical band gaps combined with low-lying HOMO energy levels and demonstrated semiconducting behavior in organic field effect transistors. © 2010 American Chemical Society.

Original language	English (US)
Pages (from-to)	5478-5481
Number of pages	4
Journal	Organic Letters
Volume	12
Issue number	23
DOIs	https://doi.org/10.1021/ol102344m
State	Published - Dec 3 2010
Externally published	Yes

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Generated from Scopus record by KAUST IRTS on 2023-02-14

ASJC Scopus subject areas

Biochemistry
Organic Chemistry
Physical and Theoretical Chemistry

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title = "Synthesis and characterization of fused pyrrolo[3,2- d:4,5- d' ]bisthiazole-containing polymers",

abstract = "The synthesis of a novel electron-deficient fused pyrrolo[3,2-d:4,5-d'] bisthiazole is reported from 2-bromothiazole. This was copolymerized with thiophene, selenophene, thienothiophene, and bithiophene by microwave-assisted Stille polycondensation. The resulting polymers exhibited small optical band gaps combined with low-lying HOMO energy levels and demonstrated semiconducting behavior in organic field effect transistors. {\textcopyright} 2010 American Chemical Society.",

author = "Mohammed Al-Hashimi and Labram, {John G.} and Scott Watkins and Majid Motevalli and Anthopoulos, {Thomas D.} and Martin Heeney",

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T1 - Synthesis and characterization of fused pyrrolo[3,2- d:4,5- d' ]bisthiazole-containing polymers

AU - Al-Hashimi, Mohammed

AU - Labram, John G.

AU - Watkins, Scott

AU - Motevalli, Majid

AU - Anthopoulos, Thomas D.

AU - Heeney, Martin

N1 - Generated from Scopus record by KAUST IRTS on 2023-02-14

PY - 2010/12/3

Y1 - 2010/12/3

N2 - The synthesis of a novel electron-deficient fused pyrrolo[3,2-d:4,5-d'] bisthiazole is reported from 2-bromothiazole. This was copolymerized with thiophene, selenophene, thienothiophene, and bithiophene by microwave-assisted Stille polycondensation. The resulting polymers exhibited small optical band gaps combined with low-lying HOMO energy levels and demonstrated semiconducting behavior in organic field effect transistors. © 2010 American Chemical Society.

AB - The synthesis of a novel electron-deficient fused pyrrolo[3,2-d:4,5-d'] bisthiazole is reported from 2-bromothiazole. This was copolymerized with thiophene, selenophene, thienothiophene, and bithiophene by microwave-assisted Stille polycondensation. The resulting polymers exhibited small optical band gaps combined with low-lying HOMO energy levels and demonstrated semiconducting behavior in organic field effect transistors. © 2010 American Chemical Society.

UR - https://pubs.acs.org/doi/10.1021/ol102344m

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DO - 10.1021/ol102344m

M3 - Article

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SN - 1523-7060

VL - 12

SP - 5478

EP - 5481

JO - Organic Letters

JF - Organic Letters

IS - 23

ER -

Synthesis and characterization of fused pyrrolo[3,2- d:4,5- d' ]bisthiazole-containing polymers

Abstract

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