Synthesis and characterization of expected and unexpected topologies of homochiral porous metal(II) malate frameworks

Maxim P. Yutkin; Marina S. Zavakhina; Denis G. Samsonenko; Danil N. Dybtsev; Vladimir P. Fedin

doi:10.1016/j.ica.2012.08.012

Synthesis and characterization of expected and unexpected topologies of homochiral porous metal(II) malate frameworks

Maxim P. Yutkin, Marina S. Zavakhina, Denis G. Samsonenko, Danil N. Dybtsev, Vladimir P. Fedin^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

25 Scopus citations

Abstract

Three new homochiral metal-organic frameworks (MOFs) based on malate anions and N-donor linkers of different length have been prepared. [Co ₂(mal)₂(bpy)]·2H₂O (1), [Ni ₂(mal)₂(bpy)]·2H₂O (2), [Ni ₂(mal)₂(bpe)]·3H₂O (3) (mal = S-malate, bpy = 4,4′-bipyridyl, bpe = trans-1,2-bis(4-pyridyl)ethylene) were characterized by a number of analytical methods including single crystal X-ray analysis. Optical purity of compounds 2 and 3 was confirmed by polarimetry experiments. Compounds 1 and 2 contribute to the family of isoreticular M(II) malates and aspartates ([M₂(asp)₂L] and [M ₂(mal)₂L], M = Cu, Co, Ni; L = ditopic rigid organic ligand) where all structural units (metal cations, chiral ligands and bridging ligands) could be changed with retention of the topology in the resulting framework. Compound 3 has a different structure and contributes to a different family of isoreticular homochiral MOFs.

Original language	English (US)
Pages (from-to)	367-372
Number of pages	6
Journal	Inorganica Chimica Acta
Volume	394
DOIs	https://doi.org/10.1016/j.ica.2012.08.012
State	Published - Jan 1 2013
Externally published	Yes

Keywords

Cobalt(II)
Homochiral coordination polymers
Malates
Metal-organic frameworks
Nickel(II)

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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title = "Synthesis and characterization of expected and unexpected topologies of homochiral porous metal(II) malate frameworks",

abstract = "Three new homochiral metal-organic frameworks (MOFs) based on malate anions and N-donor linkers of different length have been prepared. [Co 2(mal)2(bpy)]·2H2O (1), [Ni 2(mal)2(bpy)]·2H2O (2), [Ni 2(mal)2(bpe)]·3H2O (3) (mal = S-malate, bpy = 4,4′-bipyridyl, bpe = trans-1,2-bis(4-pyridyl)ethylene) were characterized by a number of analytical methods including single crystal X-ray analysis. Optical purity of compounds 2 and 3 was confirmed by polarimetry experiments. Compounds 1 and 2 contribute to the family of isoreticular M(II) malates and aspartates ([M2(asp)2L] and [M 2(mal)2L], M = Cu, Co, Ni; L = ditopic rigid organic ligand) where all structural units (metal cations, chiral ligands and bridging ligands) could be changed with retention of the topology in the resulting framework. Compound 3 has a different structure and contributes to a different family of isoreticular homochiral MOFs.",

keywords = "Cobalt(II), Homochiral coordination polymers, Malates, Metal-organic frameworks, Nickel(II)",

author = "Yutkin, {Maxim P.} and Zavakhina, {Marina S.} and Samsonenko, {Denis G.} and Dybtsev, {Danil N.} and Fedin, {Vladimir P.}",

year = "2013",

month = jan,

day = "1",

doi = "10.1016/j.ica.2012.08.012",

language = "English (US)",

volume = "394",

pages = "367--372",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier",

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TY - JOUR

T1 - Synthesis and characterization of expected and unexpected topologies of homochiral porous metal(II) malate frameworks

AU - Yutkin, Maxim P.

AU - Zavakhina, Marina S.

AU - Samsonenko, Denis G.

AU - Dybtsev, Danil N.

AU - Fedin, Vladimir P.

PY - 2013/1/1

Y1 - 2013/1/1

N2 - Three new homochiral metal-organic frameworks (MOFs) based on malate anions and N-donor linkers of different length have been prepared. [Co 2(mal)2(bpy)]·2H2O (1), [Ni 2(mal)2(bpy)]·2H2O (2), [Ni 2(mal)2(bpe)]·3H2O (3) (mal = S-malate, bpy = 4,4′-bipyridyl, bpe = trans-1,2-bis(4-pyridyl)ethylene) were characterized by a number of analytical methods including single crystal X-ray analysis. Optical purity of compounds 2 and 3 was confirmed by polarimetry experiments. Compounds 1 and 2 contribute to the family of isoreticular M(II) malates and aspartates ([M2(asp)2L] and [M 2(mal)2L], M = Cu, Co, Ni; L = ditopic rigid organic ligand) where all structural units (metal cations, chiral ligands and bridging ligands) could be changed with retention of the topology in the resulting framework. Compound 3 has a different structure and contributes to a different family of isoreticular homochiral MOFs.

AB - Three new homochiral metal-organic frameworks (MOFs) based on malate anions and N-donor linkers of different length have been prepared. [Co 2(mal)2(bpy)]·2H2O (1), [Ni 2(mal)2(bpy)]·2H2O (2), [Ni 2(mal)2(bpe)]·3H2O (3) (mal = S-malate, bpy = 4,4′-bipyridyl, bpe = trans-1,2-bis(4-pyridyl)ethylene) were characterized by a number of analytical methods including single crystal X-ray analysis. Optical purity of compounds 2 and 3 was confirmed by polarimetry experiments. Compounds 1 and 2 contribute to the family of isoreticular M(II) malates and aspartates ([M2(asp)2L] and [M 2(mal)2L], M = Cu, Co, Ni; L = ditopic rigid organic ligand) where all structural units (metal cations, chiral ligands and bridging ligands) could be changed with retention of the topology in the resulting framework. Compound 3 has a different structure and contributes to a different family of isoreticular homochiral MOFs.

KW - Cobalt(II)

KW - Homochiral coordination polymers

KW - Malates

KW - Metal-organic frameworks

KW - Nickel(II)

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DO - 10.1016/j.ica.2012.08.012

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SN - 0020-1693

VL - 394

SP - 367

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JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

ER -

Synthesis and characterization of expected and unexpected topologies of homochiral porous metal(II) malate frameworks

Abstract

Keywords

ASJC Scopus subject areas

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