Synthesis and characterization of a novel oligosiloxane containing alternative ladderlike structure via charge-transfer interaction

Quan Yuan; Shengxiang Ji; Rongben Zhang; Chaobin He; Neal Taishung Chung

doi:10.1002/pi.678

Synthesis and characterization of a novel oligosiloxane containing alternative ladderlike structure via charge-transfer interaction

Quan Yuan, Shengxiang Ji, Rongben Zhang^*, Chaobin He, Neal Taishung Chung

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

A novel oligosiloxane containing alternative ladderlike structure involving viologen groups has been prepared via donor-acceptor interaction-assisted template polymerization. The monomer used as the electron-donor component, N,N′-bis(3-methyldimethoxyl-silylpropyl)-4,4′-bipyridinium dihexafluorophosphate and its precursor, N,N′-bis(3-methyldimethoxyl-silylpropyl)-4,4′-bipyridinium dibromide were first synthesized successfully in high yield. This oligosiloxane, which displays interesting electrochromic properties, has been characterized by FTIR, UV-vis, ¹HNMR, ²⁹SiNMR, X-ray diffraction (XRD), and vapour pressure osmometry (VPO).

Original language	English (US)
Pages (from-to)	643-650
Number of pages	8
Journal	Polymer International
Volume	50
Issue number	6
DOIs	https://doi.org/10.1002/pi.678
State	Published - Jun 1 2001
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2001 Society of Chemical Industry.

Keywords

Charge-transfer interaction
Oligosiloxane

ASJC Scopus subject areas

Polymers and Plastics
Organic Chemistry
Materials Chemistry

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10.1002/pi.678

Cite this

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title = "Synthesis and characterization of a novel oligosiloxane containing alternative ladderlike structure via charge-transfer interaction",

abstract = "A novel oligosiloxane containing alternative ladderlike structure involving viologen groups has been prepared via donor-acceptor interaction-assisted template polymerization. The monomer used as the electron-donor component, N,N′-bis(3-methyldimethoxyl-silylpropyl)-4,4′-bipyridinium dihexafluorophosphate and its precursor, N,N′-bis(3-methyldimethoxyl-silylpropyl)-4,4′-bipyridinium dibromide were first synthesized successfully in high yield. This oligosiloxane, which displays interesting electrochromic properties, has been characterized by FTIR, UV-vis, 1HNMR, 29SiNMR, X-ray diffraction (XRD), and vapour pressure osmometry (VPO).",

keywords = "Charge-transfer interaction, Oligosiloxane",

author = "Quan Yuan and Shengxiang Ji and Rongben Zhang and Chaobin He and Chung, {Neal Taishung}",

note = "Publisher Copyright: {\textcopyright} 2001 Society of Chemical Industry.",

year = "2001",

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doi = "10.1002/pi.678",

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T1 - Synthesis and characterization of a novel oligosiloxane containing alternative ladderlike structure via charge-transfer interaction

AU - Yuan, Quan

AU - Ji, Shengxiang

AU - Zhang, Rongben

AU - He, Chaobin

AU - Chung, Neal Taishung

PY - 2001/6/1

Y1 - 2001/6/1

N2 - A novel oligosiloxane containing alternative ladderlike structure involving viologen groups has been prepared via donor-acceptor interaction-assisted template polymerization. The monomer used as the electron-donor component, N,N′-bis(3-methyldimethoxyl-silylpropyl)-4,4′-bipyridinium dihexafluorophosphate and its precursor, N,N′-bis(3-methyldimethoxyl-silylpropyl)-4,4′-bipyridinium dibromide were first synthesized successfully in high yield. This oligosiloxane, which displays interesting electrochromic properties, has been characterized by FTIR, UV-vis, 1HNMR, 29SiNMR, X-ray diffraction (XRD), and vapour pressure osmometry (VPO).

AB - A novel oligosiloxane containing alternative ladderlike structure involving viologen groups has been prepared via donor-acceptor interaction-assisted template polymerization. The monomer used as the electron-donor component, N,N′-bis(3-methyldimethoxyl-silylpropyl)-4,4′-bipyridinium dihexafluorophosphate and its precursor, N,N′-bis(3-methyldimethoxyl-silylpropyl)-4,4′-bipyridinium dibromide were first synthesized successfully in high yield. This oligosiloxane, which displays interesting electrochromic properties, has been characterized by FTIR, UV-vis, 1HNMR, 29SiNMR, X-ray diffraction (XRD), and vapour pressure osmometry (VPO).

KW - Charge-transfer interaction

KW - Oligosiloxane

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U2 - 10.1002/pi.678

DO - 10.1002/pi.678

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JF - Polymer International

IS - 6

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Synthesis and characterization of a novel oligosiloxane containing alternative ladderlike structure via charge-transfer interaction

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

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