Syntheses, structures and optical nonlinearities of heteroselenometallic W-Se-Cu cluster compounds containing bridging phosphane ligands

Zhan Yu; Qian Feng Zhang; Yinglin Song; Wai Yeung Wong; Alexander Rothenberger; Wa Hung Leung

doi:10.1002/ejic.200601114

Syntheses, structures and optical nonlinearities of heteroselenometallic W-Se-Cu cluster compounds containing bridging phosphane ligands

Zhan Yu, Qian Feng Zhang^*, Yinglin Song, Wai Yeung Wong, Alexander Rothenberger, Wa Hung Leung

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

Treatment of [Et₄N]₂[WSe₄] with the trinuclear trigonal-bipyramidal copper(I) complexes [Cu₃(μ ₃-X)₂(μ-L)₃]X [X = I, L = bis(diphenylphosphanyl)methane (dppm) (1a); X = CI, L = bis(diphenylphosphanyl) amine (dppa) (1b)] affords the tetranuclear cluster compounds [(μ₃-WSe₄)Cu₃(μ-X)(μ-L)2] [X = I, L = dppm (2a); X = CI, L = dppa (2b)], which exhibit an open butterfly configuration. Interaction of [Et₄N]₂[WSe₄] with [Cu(MeCN)₄][PF₆] and L gives the pentanuclear cluster compounds [(μ₄-WSe₄)Cu₄(μ-L) ₄][PF₆]₂ [L = dppm (3a), dppa (3b)] which contain an open co-planar WCu₄ core. The solid-state structures of cluster compounds 2a, 2b, and 3a have been established by X-ray crystallography. The nonlinear optical properties of 2a and 3a have been examined by z-scan techniques with 7-ns pulses at 532 nm. The pentanuclear co-planar cluster 3a exhibits a large optical limiting effect (the limiting threshold is about 0.40 J cm^-2).

Original language	English (US)
Pages (from-to)	2189-2197
Number of pages	9
Journal	European Journal of Inorganic Chemistry
Issue number	15
DOIs	https://doi.org/10.1002/ejic.200601114
State	Published - 2007
Externally published	Yes

Keywords

Cluster compounds
Copper
Heterometallic complexes
Nonlinear optical properties
Selenium

ASJC Scopus subject areas

Inorganic Chemistry

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10.1002/ejic.200601114

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@article{0ec7432085254d52bcfad15bfb044f10,

title = "Syntheses, structures and optical nonlinearities of heteroselenometallic W-Se-Cu cluster compounds containing bridging phosphane ligands",

abstract = "Treatment of [Et4N]2[WSe4] with the trinuclear trigonal-bipyramidal copper(I) complexes [Cu3(μ 3-X)2(μ-L)3]X [X = I, L = bis(diphenylphosphanyl)methane (dppm) (1a); X = CI, L = bis(diphenylphosphanyl) amine (dppa) (1b)] affords the tetranuclear cluster compounds [(μ3-WSe4)Cu3(μ-X)(μ-L)2] [X = I, L = dppm (2a); X = CI, L = dppa (2b)], which exhibit an open butterfly configuration. Interaction of [Et4N]2[WSe4] with [Cu(MeCN)4][PF6] and L gives the pentanuclear cluster compounds [(μ4-WSe4)Cu4(μ-L) 4][PF6]2 [L = dppm (3a), dppa (3b)] which contain an open co-planar WCu4 core. The solid-state structures of cluster compounds 2a, 2b, and 3a have been established by X-ray crystallography. The nonlinear optical properties of 2a and 3a have been examined by z-scan techniques with 7-ns pulses at 532 nm. The pentanuclear co-planar cluster 3a exhibits a large optical limiting effect (the limiting threshold is about 0.40 J cm-2).",

keywords = "Cluster compounds, Copper, Heterometallic complexes, Nonlinear optical properties, Selenium",

author = "Zhan Yu and Zhang, {Qian Feng} and Yinglin Song and Wong, {Wai Yeung} and Alexander Rothenberger and Leung, {Wa Hung}",

year = "2007",

doi = "10.1002/ejic.200601114",

language = "English (US)",

pages = "2189--2197",

journal = "European Journal of Inorganic Chemistry",

issn = "1434-1948",

publisher = "Wiley-VCH Verlag",

number = "15",

}

TY - JOUR

T1 - Syntheses, structures and optical nonlinearities of heteroselenometallic W-Se-Cu cluster compounds containing bridging phosphane ligands

AU - Yu, Zhan

AU - Zhang, Qian Feng

AU - Song, Yinglin

AU - Wong, Wai Yeung

AU - Rothenberger, Alexander

AU - Leung, Wa Hung

PY - 2007

Y1 - 2007

N2 - Treatment of [Et4N]2[WSe4] with the trinuclear trigonal-bipyramidal copper(I) complexes [Cu3(μ 3-X)2(μ-L)3]X [X = I, L = bis(diphenylphosphanyl)methane (dppm) (1a); X = CI, L = bis(diphenylphosphanyl) amine (dppa) (1b)] affords the tetranuclear cluster compounds [(μ3-WSe4)Cu3(μ-X)(μ-L)2] [X = I, L = dppm (2a); X = CI, L = dppa (2b)], which exhibit an open butterfly configuration. Interaction of [Et4N]2[WSe4] with [Cu(MeCN)4][PF6] and L gives the pentanuclear cluster compounds [(μ4-WSe4)Cu4(μ-L) 4][PF6]2 [L = dppm (3a), dppa (3b)] which contain an open co-planar WCu4 core. The solid-state structures of cluster compounds 2a, 2b, and 3a have been established by X-ray crystallography. The nonlinear optical properties of 2a and 3a have been examined by z-scan techniques with 7-ns pulses at 532 nm. The pentanuclear co-planar cluster 3a exhibits a large optical limiting effect (the limiting threshold is about 0.40 J cm-2).

AB - Treatment of [Et4N]2[WSe4] with the trinuclear trigonal-bipyramidal copper(I) complexes [Cu3(μ 3-X)2(μ-L)3]X [X = I, L = bis(diphenylphosphanyl)methane (dppm) (1a); X = CI, L = bis(diphenylphosphanyl) amine (dppa) (1b)] affords the tetranuclear cluster compounds [(μ3-WSe4)Cu3(μ-X)(μ-L)2] [X = I, L = dppm (2a); X = CI, L = dppa (2b)], which exhibit an open butterfly configuration. Interaction of [Et4N]2[WSe4] with [Cu(MeCN)4][PF6] and L gives the pentanuclear cluster compounds [(μ4-WSe4)Cu4(μ-L) 4][PF6]2 [L = dppm (3a), dppa (3b)] which contain an open co-planar WCu4 core. The solid-state structures of cluster compounds 2a, 2b, and 3a have been established by X-ray crystallography. The nonlinear optical properties of 2a and 3a have been examined by z-scan techniques with 7-ns pulses at 532 nm. The pentanuclear co-planar cluster 3a exhibits a large optical limiting effect (the limiting threshold is about 0.40 J cm-2).

KW - Cluster compounds

KW - Copper

KW - Heterometallic complexes

KW - Nonlinear optical properties

KW - Selenium

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DO - 10.1002/ejic.200601114

M3 - Article

AN - SCOPUS:34250696958

SN - 1434-1948

SP - 2189

EP - 2197

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

IS - 15

ER -

Syntheses, structures and optical nonlinearities of heteroselenometallic W-Se-Cu cluster compounds containing bridging phosphane ligands

Abstract

Keywords

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