Syntheses, structures, and nonlinear optical properties of two crown-like heteroselenometallic compounds [Et4N]4[(μ5- WSe4)(CuX)5(μ-X)2] (X= Cl, Br)

Shaobin Miao; Zhan Yu; Qian Feng Zhang; Yinglin Song; Alexander Rothenberger; Wa Hung Leung

doi:10.1007/s10876-006-0073-x

Syntheses, structures, and nonlinear optical properties of two crown-like heteroselenometallic compounds [Et₄N]₄[(μ₅- WSe₄)(CuX)₅(μ-X)₂] (X= Cl, Br)

Shaobin Miao, Zhan Yu, Qian Feng Zhang^*, Yinglin Song, Alexander Rothenberger, Wa Hung Leung

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

Two isostructural crown-like heteroselenometallic cluster compounds, [Et₄N]₄[(μ₅-WSe₄)(CuX) ₅(μ-X)₂] (X = Cl 1, Br 2), were prepared from the reactions of [Et₄N]₂[WSe₄] with CuX and [Et₄N]X• xH₂O in the presence of 2-picoline and characterized by single-crystal diffraction analysis. The [(μ₅- WSe₄)(Cu-X)₅(μ-X)₂]^4- anions in the cluster compounds consists of five CuX fragments coordinated to the five edges of the tetrahedral [WSe₄]^2- moiety along with two bridging halides connected to each of the two pairs of the symmetric copper atoms, exhibiting a novel crown-like core structure. The nonlinear optical absorption and refraction of cluster compound 2 were determined to be α₂ = 6.15 × 10^-10 m/W and n ₂ = 4.18 × 10^-11 esu, respectively.

Original language	English (US)
Pages (from-to)	495-507
Number of pages	13
Journal	Journal of Cluster Science
Volume	17
Issue number	3
DOIs	https://doi.org/10.1007/s10876-006-0073-x
State	Published - Sep 2006
Externally published	Yes

Bibliographical note

Funding Information:
This project was supported by the Natural Science Foundation of China (grant no. 90301005) and the Hong Kong Research Grants Council. Dr. Q. -F. Zhang thanks Science and Technological Fund of Anhui Province for Outstanding Youth (grant no. 06046100) and the Alexander von Humboldt Foundation for the assistance. We are grateful to Prof. D. Fenske for generous support of our research activities.

Keywords

Copper
Optical nonlinearity
Selenide cluster
Structure
Synthesis
Tetraselenomate

ASJC Scopus subject areas

General Chemistry
Condensed Matter Physics
Biochemistry
General Materials Science

Access to Document

10.1007/s10876-006-0073-x

Cite this

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title = "Syntheses, structures, and nonlinear optical properties of two crown-like heteroselenometallic compounds [Et4N]4[(μ5- WSe4)(CuX)5(μ-X)2] (X= Cl, Br)",

abstract = "Two isostructural crown-like heteroselenometallic cluster compounds, [Et4N]4[(μ5-WSe4)(CuX) 5(μ-X)2] (X = Cl 1, Br 2), were prepared from the reactions of [Et4N]2[WSe4] with CuX and [Et4N]X• xH2O in the presence of 2-picoline and characterized by single-crystal diffraction analysis. The [(μ5- WSe4)(Cu-X)5(μ-X)2]4- anions in the cluster compounds consists of five CuX fragments coordinated to the five edges of the tetrahedral [WSe4]2- moiety along with two bridging halides connected to each of the two pairs of the symmetric copper atoms, exhibiting a novel crown-like core structure. The nonlinear optical absorption and refraction of cluster compound 2 were determined to be α2 = 6.15 × 10-10 m/W and n 2 = 4.18 × 10-11 esu, respectively.",

keywords = "Copper, Optical nonlinearity, Selenide cluster, Structure, Synthesis, Tetraselenomate",

author = "Shaobin Miao and Zhan Yu and Zhang, {Qian Feng} and Yinglin Song and Alexander Rothenberger and Leung, {Wa Hung}",

note = "Funding Information: This project was supported by the Natural Science Foundation of China (grant no. 90301005) and the Hong Kong Research Grants Council. Dr. Q. -F. Zhang thanks Science and Technological Fund of Anhui Province for Outstanding Youth (grant no. 06046100) and the Alexander von Humboldt Foundation for the assistance. We are grateful to Prof. D. Fenske for generous support of our research activities.",

year = "2006",

month = sep,

doi = "10.1007/s10876-006-0073-x",

language = "English (US)",

volume = "17",

pages = "495--507",

journal = "Journal of Cluster Science",

issn = "1040-7278",

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TY - JOUR

T1 - Syntheses, structures, and nonlinear optical properties of two crown-like heteroselenometallic compounds [Et4N]4[(μ5- WSe4)(CuX)5(μ-X)2] (X= Cl, Br)

AU - Miao, Shaobin

AU - Yu, Zhan

AU - Zhang, Qian Feng

AU - Song, Yinglin

AU - Rothenberger, Alexander

AU - Leung, Wa Hung

N1 - Funding Information: This project was supported by the Natural Science Foundation of China (grant no. 90301005) and the Hong Kong Research Grants Council. Dr. Q. -F. Zhang thanks Science and Technological Fund of Anhui Province for Outstanding Youth (grant no. 06046100) and the Alexander von Humboldt Foundation for the assistance. We are grateful to Prof. D. Fenske for generous support of our research activities.

PY - 2006/9

Y1 - 2006/9

N2 - Two isostructural crown-like heteroselenometallic cluster compounds, [Et4N]4[(μ5-WSe4)(CuX) 5(μ-X)2] (X = Cl 1, Br 2), were prepared from the reactions of [Et4N]2[WSe4] with CuX and [Et4N]X• xH2O in the presence of 2-picoline and characterized by single-crystal diffraction analysis. The [(μ5- WSe4)(Cu-X)5(μ-X)2]4- anions in the cluster compounds consists of five CuX fragments coordinated to the five edges of the tetrahedral [WSe4]2- moiety along with two bridging halides connected to each of the two pairs of the symmetric copper atoms, exhibiting a novel crown-like core structure. The nonlinear optical absorption and refraction of cluster compound 2 were determined to be α2 = 6.15 × 10-10 m/W and n 2 = 4.18 × 10-11 esu, respectively.

AB - Two isostructural crown-like heteroselenometallic cluster compounds, [Et4N]4[(μ5-WSe4)(CuX) 5(μ-X)2] (X = Cl 1, Br 2), were prepared from the reactions of [Et4N]2[WSe4] with CuX and [Et4N]X• xH2O in the presence of 2-picoline and characterized by single-crystal diffraction analysis. The [(μ5- WSe4)(Cu-X)5(μ-X)2]4- anions in the cluster compounds consists of five CuX fragments coordinated to the five edges of the tetrahedral [WSe4]2- moiety along with two bridging halides connected to each of the two pairs of the symmetric copper atoms, exhibiting a novel crown-like core structure. The nonlinear optical absorption and refraction of cluster compound 2 were determined to be α2 = 6.15 × 10-10 m/W and n 2 = 4.18 × 10-11 esu, respectively.

KW - Copper

KW - Optical nonlinearity

KW - Selenide cluster

KW - Structure

KW - Synthesis

KW - Tetraselenomate

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DO - 10.1007/s10876-006-0073-x

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