Synthesen und strukturen von übergangsmetall-komplexen mit dithiophosphinato- und trithiophosphonato-liganden

Maryam Shafaei-Fallah; Weifeng Shi; Dieter Fenske; Alexander Rothenberger

doi:10.1002/zaac.200600023

Synthesen und strukturen von übergangsmetall-komplexen mit dithiophosphinato- und trithiophosphonato-liganden

Translated title of the contribution: Syntheses and structures of transition metal complexes with dithiophosphinato and trithiophosphinato ligands

Maryam Shafaei-Fallah^*, Weifeng Shi, Dieter Fenske, Alexander Rothenberger

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

The reactions of MnCl₂ with Ph₂P(S)(SSiMe ₃) produced [Mn(S₂PPh₂)₂(thf) ₂] (1) and [Mn(S₂PPh₂)₂(dme)] (2) (DME = 1,2-Dimethoxyethane). The compounds [Co₆(S₃PPh) ₂(μ⁴-S)₂(μ³-S) ₂(PPh₃)₄] (3), [Co₂(S ₃PPh)₂(PPh₃)₂] (4), [Ni(S ₂PPh)(PPhEt₂)₂] (5), [Ni(S₃PPh) (PPhEt₂)₂] (6) and [Cu₄(S₃PPh) ₂(dppp)₂] (8) [dppp = 1,3-Bis(diphenylphosphanyl)propane] were obtained from reactions of first-row transition metal halides with PhP(S)(SSiMe₃)₂ in the presence of tertiary phosphines. In a reaction of PhP(S)(SSiMe₃)₂ with PhPEt₂ PhPEt₂PS₂Ph (7) was isolated. All compounds were characterized by X-ray crystallography.

Translated title of the contribution	Syntheses and structures of transition metal complexes with dithiophosphinato and trithiophosphinato ligands
Original language	German
Pages (from-to)	1091-1096
Number of pages	6
Journal	Zeitschrift fur Anorganische und Allgemeine Chemie
Volume	632
Issue number	6
DOIs	https://doi.org/10.1002/zaac.200600023
State	Published - 2006
Externally published	Yes

Keywords

Cobalt
Crystal structures
Manganese
Nickel
P ligands
S ligands

ASJC Scopus subject areas

Inorganic Chemistry

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10.1002/zaac.200600023

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@article{50022f1f9d1a4545afef060f08e4f7a7,

title = "Synthesen und strukturen von {\"u}bergangsmetall-komplexen mit dithiophosphinato- und trithiophosphonato-liganden",

abstract = "The reactions of MnCl2 with Ph2P(S)(SSiMe 3) produced [Mn(S2PPh2)2(thf) 2] (1) and [Mn(S2PPh2)2(dme)] (2) (DME = 1,2-Dimethoxyethane). The compounds [Co6(S3PPh) 2(μ4-S)2(μ3-S) 2(PPh3)4] (3), [Co2(S 3PPh)2(PPh3)2] (4), [Ni(S 2PPh)(PPhEt2)2] (5), [Ni(S3PPh) (PPhEt2)2] (6) and [Cu4(S3PPh) 2(dppp)2] (8) [dppp = 1,3-Bis(diphenylphosphanyl)propane] were obtained from reactions of first-row transition metal halides with PhP(S)(SSiMe3)2 in the presence of tertiary phosphines. In a reaction of PhP(S)(SSiMe3)2 with PhPEt2 PhPEt2PS2Ph (7) was isolated. All compounds were characterized by X-ray crystallography.",

keywords = "Cobalt, Crystal structures, Manganese, Nickel, P ligands, S ligands",

author = "Maryam Shafaei-Fallah and Weifeng Shi and Dieter Fenske and Alexander Rothenberger",

year = "2006",

doi = "10.1002/zaac.200600023",

language = "German",

volume = "632",

pages = "1091--1096",

journal = "Zeitschrift fur Anorganische und Allgemeine Chemie",

issn = "0044-2313",

publisher = "Wiley",

number = "6",

}

TY - JOUR

T1 - Synthesen und strukturen von übergangsmetall-komplexen mit dithiophosphinato- und trithiophosphonato-liganden

AU - Shafaei-Fallah, Maryam

AU - Shi, Weifeng

AU - Fenske, Dieter

AU - Rothenberger, Alexander

PY - 2006

Y1 - 2006

N2 - The reactions of MnCl2 with Ph2P(S)(SSiMe 3) produced [Mn(S2PPh2)2(thf) 2] (1) and [Mn(S2PPh2)2(dme)] (2) (DME = 1,2-Dimethoxyethane). The compounds [Co6(S3PPh) 2(μ4-S)2(μ3-S) 2(PPh3)4] (3), [Co2(S 3PPh)2(PPh3)2] (4), [Ni(S 2PPh)(PPhEt2)2] (5), [Ni(S3PPh) (PPhEt2)2] (6) and [Cu4(S3PPh) 2(dppp)2] (8) [dppp = 1,3-Bis(diphenylphosphanyl)propane] were obtained from reactions of first-row transition metal halides with PhP(S)(SSiMe3)2 in the presence of tertiary phosphines. In a reaction of PhP(S)(SSiMe3)2 with PhPEt2 PhPEt2PS2Ph (7) was isolated. All compounds were characterized by X-ray crystallography.

AB - The reactions of MnCl2 with Ph2P(S)(SSiMe 3) produced [Mn(S2PPh2)2(thf) 2] (1) and [Mn(S2PPh2)2(dme)] (2) (DME = 1,2-Dimethoxyethane). The compounds [Co6(S3PPh) 2(μ4-S)2(μ3-S) 2(PPh3)4] (3), [Co2(S 3PPh)2(PPh3)2] (4), [Ni(S 2PPh)(PPhEt2)2] (5), [Ni(S3PPh) (PPhEt2)2] (6) and [Cu4(S3PPh) 2(dppp)2] (8) [dppp = 1,3-Bis(diphenylphosphanyl)propane] were obtained from reactions of first-row transition metal halides with PhP(S)(SSiMe3)2 in the presence of tertiary phosphines. In a reaction of PhP(S)(SSiMe3)2 with PhPEt2 PhPEt2PS2Ph (7) was isolated. All compounds were characterized by X-ray crystallography.

KW - Cobalt

KW - Crystal structures

KW - Manganese

KW - Nickel

KW - P ligands

KW - S ligands

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U2 - 10.1002/zaac.200600023

DO - 10.1002/zaac.200600023

M3 - Article

AN - SCOPUS:33646520875

SN - 0044-2313

VL - 632

SP - 1091

EP - 1096

JO - Zeitschrift fur Anorganische und Allgemeine Chemie

JF - Zeitschrift fur Anorganische und Allgemeine Chemie

IS - 6

ER -

Synthesen und strukturen von übergangsmetall-komplexen mit dithiophosphinato- und trithiophosphonato-liganden

Abstract

Keywords

ASJC Scopus subject areas

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