Synthese und kristallstruktur von [(Me3Si)2BiCu(PMe3)3], dem ersten komplex mit einer bismut-kupfer-bindung

Dieter Fenske; Alexander Rothenberger; Stephan Wieber

doi:10.1002/zaac.200300062

Synthese und kristallstruktur von [(Me₃Si)₂BiCu(PMe₃)₃], dem ersten komplex mit einer bismut-kupfer-bindung

Translated title of the contribution: Synthesis and crystal structure of [(Me₃Si)₂BiCu(PMe₃)₃] - The first complex with a bismuth-copper bond

Dieter Fenske^*, Alexander Rothenberger, Stephan Wieber

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

20 Scopus citations

Abstract

The reaction of CuO^tBu with PMe₃ and Bi(SiMe₃)₃ in hexane yields the phosphine-stabilized complex [(Me₃Si)₂Bi-Cu(PMe₃)₃]. This synthesis gave rise to the first binuclear Bi-Cu compound to be structurally characterized by X-ray crystallography.

Translated title of the contribution	Synthesis and crystal structure of [(Me₃Si)₂BiCu(PMe₃)₃] - The first complex with a bismuth-copper bond
Original language	German
Pages (from-to)	929-930
Number of pages	2
Journal	Zeitschrift fur Anorganische und Allgemeine Chemie
Volume	629
Issue number	6
DOIs	https://doi.org/10.1002/zaac.200300062
State	Published - 2003
Externally published	Yes

Keywords

Bismuth
Cluster
Copper
Crystal structure

ASJC Scopus subject areas

Inorganic Chemistry

Access to Document

10.1002/zaac.200300062

Cite this

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title = "Synthese und kristallstruktur von [(Me3Si)2BiCu(PMe3)3], dem ersten komplex mit einer bismut-kupfer-bindung",

abstract = "The reaction of CuOtBu with PMe3 and Bi(SiMe3)3 in hexane yields the phosphine-stabilized complex [(Me3Si)2Bi-Cu(PMe3)3]. This synthesis gave rise to the first binuclear Bi-Cu compound to be structurally characterized by X-ray crystallography.",

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AU - Rothenberger, Alexander

AU - Wieber, Stephan

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KW - Cluster

KW - Copper

KW - Crystal structure

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