Suzuki-Miyaura cross-coupling reactions in aqueous media: Green and sustainable syntheses of biaryls

Vivek Polshettiwar; Audrey Decottignies; Christophe Len; Aziz Fihri

doi:10.1002/cssc.200900221

Suzuki-Miyaura cross-coupling reactions in aqueous media: Green and sustainable syntheses of biaryls

Vivek Polshettiwar, Audrey Decottignies, Christophe Len, Aziz Fihri

Physical Sciences and Engineering

Research output: Contribution to journal › Article › peer-review

348 Scopus citations

Abstract

Carbon-carbon cross-coupling reactions are among the most important processes in organic chemistry, and Suzuki-Miyaura reactions are among the most widely used protocols for the formation of carbon-carbon bonds. These reactions are generally catalyzed by soluble palladium complexes with various ligands. However, the use of toxic organic solvents remains a scientific challenge and an aspect of economical and ecological relevance. This Review will summarize various recently developed significant methods by which the Suzuki-Miyaura coupling was conducted in aqueous media, and analyzes if they are "real green" protocols. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Original language	English (US)
Pages (from-to)	502-522
Number of pages	21
Journal	ChemSusChem
Volume	3
Issue number	5
DOIs	https://doi.org/10.1002/cssc.200900221
State	Published - Feb 28 2010

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: We thank G. Santini for his support of this work and the Region Picardie for their financial support.

ASJC Scopus subject areas

General Energy
Environmental Chemistry
General Materials Science
General Chemical Engineering

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Cite this

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AU - Fihri, Aziz

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N2 - Carbon-carbon cross-coupling reactions are among the most important processes in organic chemistry, and Suzuki-Miyaura reactions are among the most widely used protocols for the formation of carbon-carbon bonds. These reactions are generally catalyzed by soluble palladium complexes with various ligands. However, the use of toxic organic solvents remains a scientific challenge and an aspect of economical and ecological relevance. This Review will summarize various recently developed significant methods by which the Suzuki-Miyaura coupling was conducted in aqueous media, and analyzes if they are "real green" protocols. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Suzuki-Miyaura cross-coupling reactions in aqueous media: Green and sustainable syntheses of biaryls

Abstract

Bibliographical note

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