Treatment of (EtO)2SeO with Aerosil silica dehydroxylated at 500 °C results in the formation of a unique surface derivative [≡SiO-Se(O)OEt] (1), which has been fully characterized by elemental analysis, IR, labelling reaction and solid-state NMR spectroscopy. This is the first example of a silica-supported selenium(IV) derivative. (
Bibliographical noteFunding Information:
The study has been supported by an independent research grant from Internal Grant Agency of Ministry of Health of the Czech Republic No. NT/14270. This study was presented in part at the 91st Physiological Days, February 2015, Brno, Czech Republic.
- Supported catalysis
- Surface chemistry
ASJC Scopus subject areas
- Inorganic Chemistry