Surface organometallic chemistry on oxides: The first well-defined selenium(IV) derivative grafted onto silica

Hélène Provendier; Catherine C. Santini; Jean Marie Basset; Laurent Carmona

doi:10.1002/ejic.200200609

Surface organometallic chemistry on oxides: The first well-defined selenium(IV) derivative grafted onto silica

Hélène Provendier, Catherine C. Santini^*, Jean Marie Basset, Laurent Carmona

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

Treatment of (EtO)₂SeO with Aerosil silica dehydroxylated at 500 °C results in the formation of a unique surface derivative [≡SiO-Se(O)OEt] (1), which has been fully characterized by elemental analysis, IR, labelling reaction and solid-state NMR spectroscopy. This is the first example of a silica-supported selenium(IV) derivative. (

Original language	English (US)
Pages (from-to)	2139-2144
Number of pages	6
Journal	European Journal of Inorganic Chemistry
Issue number	11
DOIs	https://doi.org/10.1002/ejic.200200609
State	Published - Jun 2003
Externally published	Yes

Bibliographical note

Funding Information:
The study has been supported by an independent research grant from Internal Grant Agency of Ministry of Health of the Czech Republic No. NT/14270. This study was presented in part at the 91st Physiological Days, February 2015, Brno, Czech Republic.

Keywords

Acetaldehyde
Oxidation
Selenium
Supported catalysis
Surface chemistry

ASJC Scopus subject areas

Inorganic Chemistry

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10.1002/ejic.200200609

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@article{a8c308ae6c5649f49a961c9c7b933683,

title = "Surface organometallic chemistry on oxides: The first well-defined selenium(IV) derivative grafted onto silica",

abstract = "Treatment of (EtO)2SeO with Aerosil silica dehydroxylated at 500 °C results in the formation of a unique surface derivative [≡SiO-Se(O)OEt] (1), which has been fully characterized by elemental analysis, IR, labelling reaction and solid-state NMR spectroscopy. This is the first example of a silica-supported selenium(IV) derivative. (",

keywords = "Acetaldehyde, Oxidation, Selenium, Supported catalysis, Surface chemistry",

author = "H{\'e}l{\`e}ne Provendier and Santini, {Catherine C.} and Basset, {Jean Marie} and Laurent Carmona",

note = "Funding Information: The study has been supported by an independent research grant from Internal Grant Agency of Ministry of Health of the Czech Republic No. NT/14270. This study was presented in part at the 91st Physiological Days, February 2015, Brno, Czech Republic.",

year = "2003",

month = jun,

doi = "10.1002/ejic.200200609",

language = "English (US)",

pages = "2139--2144",

journal = "European Journal of Inorganic Chemistry",

issn = "1434-1948",

publisher = "Wiley-VCH Verlag",

number = "11",

}

TY - JOUR

T1 - Surface organometallic chemistry on oxides

T2 - The first well-defined selenium(IV) derivative grafted onto silica

AU - Provendier, Hélène

AU - Santini, Catherine C.

AU - Basset, Jean Marie

AU - Carmona, Laurent

N1 - Funding Information: The study has been supported by an independent research grant from Internal Grant Agency of Ministry of Health of the Czech Republic No. NT/14270. This study was presented in part at the 91st Physiological Days, February 2015, Brno, Czech Republic.

PY - 2003/6

Y1 - 2003/6

N2 - Treatment of (EtO)2SeO with Aerosil silica dehydroxylated at 500 °C results in the formation of a unique surface derivative [≡SiO-Se(O)OEt] (1), which has been fully characterized by elemental analysis, IR, labelling reaction and solid-state NMR spectroscopy. This is the first example of a silica-supported selenium(IV) derivative. (

AB - Treatment of (EtO)2SeO with Aerosil silica dehydroxylated at 500 °C results in the formation of a unique surface derivative [≡SiO-Se(O)OEt] (1), which has been fully characterized by elemental analysis, IR, labelling reaction and solid-state NMR spectroscopy. This is the first example of a silica-supported selenium(IV) derivative. (

KW - Acetaldehyde

KW - Oxidation

KW - Selenium

KW - Supported catalysis

KW - Surface chemistry

UR - http://www.scopus.com/inward/record.url?scp=0038271700&partnerID=8YFLogxK

U2 - 10.1002/ejic.200200609

DO - 10.1002/ejic.200200609

M3 - Article

AN - SCOPUS:0038271700

SN - 1434-1948

SP - 2139

EP - 2144

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

IS - 11

ER -

Surface organometallic chemistry on oxides: The first well-defined selenium(IV) derivative grafted onto silica

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

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