Surface organometallic chemistry of tin: Grafting reaction of Sn(CH3)4 in HY zeolite supercage

Xuxu Wang; Huixia Zhao; Frédéric Lefebvre; Jean Marie Basset

doi:10.1246/cl.2000.1164

Surface organometallic chemistry of tin: Grafting reaction of Sn(CH₃)₄ in HY zeolite supercage

Xuxu Wang^*, Huixia Zhao, Frédéric Lefebvre, Jean Marie Basset

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

Tetramethyltin reacts rapidly, even at low temperature, with the hydroxy groups in the supercages of HY zeolite, resulting in the formation of well-defined -Sn(CH₃)₃ fragments in the supercages. This reaction is very selective as there is no reaction with the hydroxy groups in the sodalite cages and prisms.

Original language	English (US)
Pages (from-to)	1164-1165
Number of pages	2
Journal	Chemistry Letters
Issue number	10
DOIs	https://doi.org/10.1246/cl.2000.1164
State	Published - 2000
Externally published	Yes

ASJC Scopus subject areas

General Chemistry

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title = "Surface organometallic chemistry of tin: Grafting reaction of Sn(CH3)4 in HY zeolite supercage",

abstract = "Tetramethyltin reacts rapidly, even at low temperature, with the hydroxy groups in the supercages of HY zeolite, resulting in the formation of well-defined -Sn(CH3)3 fragments in the supercages. This reaction is very selective as there is no reaction with the hydroxy groups in the sodalite cages and prisms.",

author = "Xuxu Wang and Huixia Zhao and Fr{\'e}d{\'e}ric Lefebvre and Basset, {Jean Marie}",

year = "2000",

doi = "10.1246/cl.2000.1164",

language = "English (US)",

pages = "1164--1165",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "Oxford University Press",

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T1 - Surface organometallic chemistry of tin

T2 - Grafting reaction of Sn(CH3)4 in HY zeolite supercage

AU - Wang, Xuxu

AU - Zhao, Huixia

AU - Lefebvre, Frédéric

AU - Basset, Jean Marie

PY - 2000

Y1 - 2000

N2 - Tetramethyltin reacts rapidly, even at low temperature, with the hydroxy groups in the supercages of HY zeolite, resulting in the formation of well-defined -Sn(CH3)3 fragments in the supercages. This reaction is very selective as there is no reaction with the hydroxy groups in the sodalite cages and prisms.

AB - Tetramethyltin reacts rapidly, even at low temperature, with the hydroxy groups in the supercages of HY zeolite, resulting in the formation of well-defined -Sn(CH3)3 fragments in the supercages. This reaction is very selective as there is no reaction with the hydroxy groups in the sodalite cages and prisms.

UR - http://www.scopus.com/inward/record.url?scp=0034335899&partnerID=8YFLogxK

U2 - 10.1246/cl.2000.1164

DO - 10.1246/cl.2000.1164

M3 - Article

AN - SCOPUS:0034335899

SN - 0366-7022

SP - 1164

EP - 1165

JO - Chemistry Letters

JF - Chemistry Letters

IS - 10

ER -

Surface organometallic chemistry of tin: Grafting reaction of Sn(CH₃)₄ in HY zeolite supercage

Abstract

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