Surface generation of a cobalt-derived water oxidation electrocatalyst developed in a neutral HCO3 -/CO2 system

Khurram Saleem Joya; Kazuhiro Takanabe; Huub J M De Groot

doi:10.1002/aenm.201400252

Surface generation of a cobalt-derived water oxidation electrocatalyst developed in a neutral HCO3 -/CO2 system

Khurram Saleem Joya, Kazuhiro Takanabe, Huub J M De Groot

Research output: Contribution to journal › Article › peer-review

73 Scopus citations

Abstract

Neutral HCO3 -/CO2 is a new electrolyte system for in situ generation of robust and efficient Co-derived (Co-Ci) water oxidation electrocatalysts. The Co-Ci/indium tin oxide system shows a remarkable 2.0 mA cm-2 oxygen evolution current density that is sustained for several hours. 7.5 nmol of electroactive species per cm2 generates about 109 μmol of O2 at a rate of 0.51 per mol of catalyst per second.

Original language	English (US)
Pages (from-to)	1400252
Journal	Advanced Energy Materials
Volume	4
Issue number	16
DOIs	https://doi.org/10.1002/aenm.201400252
State	Published - Jun 4 2014

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: K.S.J. acknowledges research funding from the Higher Education Commission (HEC), Government of Pakistan and Leiden University/BioSolar Cells for the research support and facilities. The authors are thankful to Dr. Marcel Hesselberth for the SEM analyzes and Mr. Verhoeven Tiny is gratefully acknowledged for the XPS experiments. The help of Dr. Shahid Rasool and Angel Garcia (KCC, KAUST) in performing online GC measurements for O2 characterization, and Dr. Naeem-Ur-Rehman Minhas (Characterization Lab, KAUST) for EDX analyzes is greatly acknowledged.

ASJC Scopus subject areas

Renewable Energy, Sustainability and the Environment
General Materials Science

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1002/aenm.201400252

Cite this

@article{f2878b733a3c43719e380bf10d3aa01f,

title = "Surface generation of a cobalt-derived water oxidation electrocatalyst developed in a neutral HCO3 -/CO2 system",

abstract = "Neutral HCO3 -/CO2 is a new electrolyte system for in situ generation of robust and efficient Co-derived (Co-Ci) water oxidation electrocatalysts. The Co-Ci/indium tin oxide system shows a remarkable 2.0 mA cm-2 oxygen evolution current density that is sustained for several hours. 7.5 nmol of electroactive species per cm2 generates about 109 μmol of O2 at a rate of 0.51 per mol of catalyst per second.",

author = "Joya, {Khurram Saleem} and Kazuhiro Takanabe and {De Groot}, {Huub J M}",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: K.S.J. acknowledges research funding from the Higher Education Commission (HEC), Government of Pakistan and Leiden University/BioSolar Cells for the research support and facilities. The authors are thankful to Dr. Marcel Hesselberth for the SEM analyzes and Mr. Verhoeven Tiny is gratefully acknowledged for the XPS experiments. The help of Dr. Shahid Rasool and Angel Garcia (KCC, KAUST) in performing online GC measurements for O2 characterization, and Dr. Naeem-Ur-Rehman Minhas (Characterization Lab, KAUST) for EDX analyzes is greatly acknowledged.",

year = "2014",

month = jun,

day = "4",

doi = "10.1002/aenm.201400252",

language = "English (US)",

volume = "4",

pages = "1400252",

journal = "Advanced Energy Materials",

issn = "1614-6832",

publisher = "Wiley-VCH Verlag",

number = "16",

}

TY - JOUR

T1 - Surface generation of a cobalt-derived water oxidation electrocatalyst developed in a neutral HCO3 -/CO2 system

AU - Joya, Khurram Saleem

AU - Takanabe, Kazuhiro

AU - De Groot, Huub J M

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: K.S.J. acknowledges research funding from the Higher Education Commission (HEC), Government of Pakistan and Leiden University/BioSolar Cells for the research support and facilities. The authors are thankful to Dr. Marcel Hesselberth for the SEM analyzes and Mr. Verhoeven Tiny is gratefully acknowledged for the XPS experiments. The help of Dr. Shahid Rasool and Angel Garcia (KCC, KAUST) in performing online GC measurements for O2 characterization, and Dr. Naeem-Ur-Rehman Minhas (Characterization Lab, KAUST) for EDX analyzes is greatly acknowledged.

PY - 2014/6/4

Y1 - 2014/6/4

N2 - Neutral HCO3 -/CO2 is a new electrolyte system for in situ generation of robust and efficient Co-derived (Co-Ci) water oxidation electrocatalysts. The Co-Ci/indium tin oxide system shows a remarkable 2.0 mA cm-2 oxygen evolution current density that is sustained for several hours. 7.5 nmol of electroactive species per cm2 generates about 109 μmol of O2 at a rate of 0.51 per mol of catalyst per second.

AB - Neutral HCO3 -/CO2 is a new electrolyte system for in situ generation of robust and efficient Co-derived (Co-Ci) water oxidation electrocatalysts. The Co-Ci/indium tin oxide system shows a remarkable 2.0 mA cm-2 oxygen evolution current density that is sustained for several hours. 7.5 nmol of electroactive species per cm2 generates about 109 μmol of O2 at a rate of 0.51 per mol of catalyst per second.

UR - http://hdl.handle.net/10754/563590

UR - http://doi.wiley.com/10.1002/aenm.201400252

UR - http://www.scopus.com/inward/record.url?scp=84911433816&partnerID=8YFLogxK

U2 - 10.1002/aenm.201400252

DO - 10.1002/aenm.201400252

M3 - Article

SN - 1614-6832

VL - 4

SP - 1400252

JO - Advanced Energy Materials

JF - Advanced Energy Materials

IS - 16

ER -

Surface generation of a cobalt-derived water oxidation electrocatalyst developed in a neutral HCO3 -/CO2 system

Abstract

Bibliographical note

ASJC Scopus subject areas

UN SDGs

Access to Document

Other files and links

Fingerprint

Cite this