TY - JOUR
T1 - Supramolecular approach to metal-support interactions
T2 - Formation and decarbonylation of allyl alcohol by an oxide-supported (σ-allyl) rhodium(III) complex
AU - Scott, Susannah L.
AU - Crippen, Craig
AU - Santini, Catherine C.
AU - Basset, Jean-Marie Maurice
PY - 1995/12/1
Y1 - 1995/12/1
N2 - Silica- or alumina-supported bis(allyl)rhodium(III) reacts with PMe 3, producing an unstable mono(allyl)rhodium(III) fragment which undergoes C-O bond formation to give allyl alcohol which is then decarbonylated, as demonstrated by IR spectroscopy, isotopic labelling, elemental analysis and 31P solid-state MAS NMR.
AB - Silica- or alumina-supported bis(allyl)rhodium(III) reacts with PMe 3, producing an unstable mono(allyl)rhodium(III) fragment which undergoes C-O bond formation to give allyl alcohol which is then decarbonylated, as demonstrated by IR spectroscopy, isotopic labelling, elemental analysis and 31P solid-state MAS NMR.
UR - http://www.scopus.com/inward/record.url?scp=37049083822&partnerID=8YFLogxK
U2 - 10.1039/C39950001875
DO - 10.1039/C39950001875
M3 - Article
AN - SCOPUS:37049083822
SN - 0577-6171
SP - 1875
EP - 1876
JO - Journal of the Chemical Society D: Chemical Communications
JF - Journal of the Chemical Society D: Chemical Communications
IS - 18
ER -