SUPPORTED CLUSTERS AND MECHANISM OF CO REDUCTION.

J. M. Basset; B. Besson; A. Choplin; F. Hugues; M. Leconte; D. Rojas; A. K. Smith; A. Theolier; Y. Chauvin; D. Commereuc; R. Psaro; R. Ugo; G. M. Zanderighi

SUPPORTED CLUSTERS AND MECHANISM OF CO REDUCTION.

J. M. Basset^*, B. Besson, A. Choplin, F. Hugues, M. Leconte, D. Rojas, A. K. Smith, A. Theolier, Y. Chauvin, D. Commereuc, R. Psaro, R. Ugo, G. M. Zanderighi

^*Corresponding author for this work

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

22 Scopus citations

Abstract

The reactivity of molecular clusters with the surface of oxides such as silica, alumina is at the origin of a new class of hybrid catalysts which exhibit unusual activities and selectivities in comparison with conventional homogeneous and heterogeneous catalysts. It is the purpose of this paper to deal with this aspect of cluster chemistry in connection with the mechanism of CO reduction in heterogeneous catalysis. Such a surface reaction between a molecular carbonyl and the surface of an inorganic oxide raises a number of questions which are relevant to Fischer-Tropsch synthesis, since it has been claimed that molecular cluster carbonyls are the effective catalysts for hydrocondensation of CO to hydrocarbons or alcohols.

Original language	English (US)
Title of host publication	Fundamental Research in Homogeneous Catalysis
Editors	Mauro Graziani, Matteo Giongo
Publisher	Plenum Press
Pages	19-53
Number of pages	35
ISBN (Print)	0306415127
State	Published - 1984
Externally published	Yes

Publication series

Name	Fundamental Research in Homogeneous Catalysis
Volume	4
ISSN (Print)	0271-1842

ASJC Scopus subject areas

General Engineering

Cite this

Basset, J. M., Besson, B., Choplin, A., Hugues, F., Leconte, M., Rojas, D., Smith, A. K., Theolier, A., Chauvin, Y., Commereuc, D., Psaro, R., Ugo, R., & Zanderighi, G. M. (1984). SUPPORTED CLUSTERS AND MECHANISM OF CO REDUCTION. In M. Graziani, & M. Giongo (Eds.), Fundamental Research in Homogeneous Catalysis (pp. 19-53). (Fundamental Research in Homogeneous Catalysis; Vol. 4). Plenum Press.

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SUPPORTED CLUSTERS AND MECHANISM OF CO REDUCTION. / Basset, J. M.; Besson, B.; Choplin, A. et al.
Fundamental Research in Homogeneous Catalysis. ed. / Mauro Graziani; Matteo Giongo. Plenum Press, 1984. p. 19-53 (Fundamental Research in Homogeneous Catalysis; Vol. 4).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

TY - GEN

T1 - SUPPORTED CLUSTERS AND MECHANISM OF CO REDUCTION.

AU - Basset, J. M.

AU - Besson, B.

AU - Choplin, A.

AU - Hugues, F.

AU - Leconte, M.

AU - Rojas, D.

AU - Smith, A. K.

AU - Theolier, A.

AU - Chauvin, Y.

AU - Commereuc, D.

AU - Psaro, R.

AU - Ugo, R.

AU - Zanderighi, G. M.

PY - 1984

Y1 - 1984

N2 - The reactivity of molecular clusters with the surface of oxides such as silica, alumina is at the origin of a new class of hybrid catalysts which exhibit unusual activities and selectivities in comparison with conventional homogeneous and heterogeneous catalysts. It is the purpose of this paper to deal with this aspect of cluster chemistry in connection with the mechanism of CO reduction in heterogeneous catalysis. Such a surface reaction between a molecular carbonyl and the surface of an inorganic oxide raises a number of questions which are relevant to Fischer-Tropsch synthesis, since it has been claimed that molecular cluster carbonyls are the effective catalysts for hydrocondensation of CO to hydrocarbons or alcohols.

AB - The reactivity of molecular clusters with the surface of oxides such as silica, alumina is at the origin of a new class of hybrid catalysts which exhibit unusual activities and selectivities in comparison with conventional homogeneous and heterogeneous catalysts. It is the purpose of this paper to deal with this aspect of cluster chemistry in connection with the mechanism of CO reduction in heterogeneous catalysis. Such a surface reaction between a molecular carbonyl and the surface of an inorganic oxide raises a number of questions which are relevant to Fischer-Tropsch synthesis, since it has been claimed that molecular cluster carbonyls are the effective catalysts for hydrocondensation of CO to hydrocarbons or alcohols.

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AN - SCOPUS:0021590206

SN - 0306415127

T3 - Fundamental Research in Homogeneous Catalysis

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EP - 53

BT - Fundamental Research in Homogeneous Catalysis

A2 - Graziani, Mauro

A2 - Giongo, Matteo

PB - Plenum Press

ER -

SUPPORTED CLUSTERS AND MECHANISM OF CO REDUCTION.

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ASJC Scopus subject areas

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