1P nuclear magnetic resonance and infrared spectroscopic evidence for co-ordinatively unsaturated zerovalent tungsten generated by interaction of W(CO)5L (L = PPh3 or PBun 3) with AlBr3

Y. Ben Taarit; J. L. Bilhou; M. Lecomte; Jean-Marie Maurice Basset

doi:10.1039/C39780000038

¹P nuclear magnetic resonance and infrared spectroscopic evidence for co-ordinatively unsaturated zerovalent tungsten generated by interaction of W(CO)₅L (L = PPh₃ or PBuⁿ ₃) with AlBr₃

Y. Ben Taarit^*, J. L. Bilhou, M. Lecomte, Jean-Marie Maurice Basset

^*Corresponding author for this work

Physical Sciences and Engineering

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3 Scopus citations

Abstract

With the metathesis catalyst W(CO)₅L·AlBr₃, AlBr₃ acts first as a Lewis acid to give a 1 : 1 adduct which further yields a co-ordinatively unsaturated, relatively stable zerovalent tungsten.

Original language	English (US)
Pages (from-to)	38-39
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	2
DOIs	https://doi.org/10.1039/C39780000038
State	Published - Jan 1 1978

ASJC Scopus subject areas

Molecular Medicine

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@article{3fb5e0561d904533a72e9f83389ee82b,

title = "1P nuclear magnetic resonance and infrared spectroscopic evidence for co-ordinatively unsaturated zerovalent tungsten generated by interaction of W(CO)5L (L = PPh3 or PBun 3) with AlBr3",

abstract = "With the metathesis catalyst W(CO)5L·AlBr3, AlBr3 acts first as a Lewis acid to give a 1 : 1 adduct which further yields a co-ordinatively unsaturated, relatively stable zerovalent tungsten.",

author = "Taarit, {Y. Ben} and Bilhou, {J. L.} and M. Lecomte and Basset, {Jean-Marie Maurice}",

year = "1978",

month = jan,

day = "1",

doi = "10.1039/C39780000038",

language = "English (US)",

pages = "38--39",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "2",

}

¹P nuclear magnetic resonance and infrared spectroscopic evidence for co-ordinatively unsaturated zerovalent tungsten generated by interaction of W(CO)₅L (L = PPh₃ or PBuⁿ ₃) with AlBr₃. / Taarit, Y. Ben; Bilhou, J. L.; Lecomte, M. et al.
In: Journal of the Chemical Society, Chemical Communications, No. 2, 01.01.1978, p. 38-39.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - 1P nuclear magnetic resonance and infrared spectroscopic evidence for co-ordinatively unsaturated zerovalent tungsten generated by interaction of W(CO)5L (L = PPh3 or PBun 3) with AlBr3

AU - Taarit, Y. Ben

AU - Bilhou, J. L.

AU - Lecomte, M.

AU - Basset, Jean-Marie Maurice

PY - 1978/1/1

Y1 - 1978/1/1

N2 - With the metathesis catalyst W(CO)5L·AlBr3, AlBr3 acts first as a Lewis acid to give a 1 : 1 adduct which further yields a co-ordinatively unsaturated, relatively stable zerovalent tungsten.

AB - With the metathesis catalyst W(CO)5L·AlBr3, AlBr3 acts first as a Lewis acid to give a 1 : 1 adduct which further yields a co-ordinatively unsaturated, relatively stable zerovalent tungsten.

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U2 - 10.1039/C39780000038

DO - 10.1039/C39780000038

M3 - Article

SN - 0022-4936

SP - 38

EP - 39

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 2

ER -

¹P nuclear magnetic resonance and infrared spectroscopic evidence for co-ordinatively unsaturated zerovalent tungsten generated by interaction of W(CO)₅L (L = PPh₃ or PBuⁿ ₃) with AlBr₃

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