Structure and magnetism of the first cyano-bridged hetero-one-dimensional GdIII-CrIII complexes

Albert Figuerola, Carmen Diaz, Mohamed S.El Fallah, Joan Ribas*, Miguel Maestro, José Mahía

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

98 Scopus citations

Abstract

A reaction between Gd(NO3)3·6H2O, K3[Cr(CN)6] and dmf or bpy has allowed the synthesis of two new ferrimagnetic GdIII-CrIII chains which are the first low-dimensional 4f-CrIII systems; magnetic susceptibilty data indicate antiferromagnetic coupling between GdIII and CrIII.

Original languageEnglish (US)
Pages (from-to)1204-1205
Number of pages2
JournalCHEMICAL COMMUNICATIONS
Volume1
Issue number13
DOIs
StatePublished - 2001
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • General Chemistry
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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