Structural, optical, and electronic studies of wide-bandgap lead halide perovskites

Riccardo Comin; Grant Walters; Emmanuel Sol Thibau; Oleksandr Voznyy; Zheng-Hong Lu; Edward H. Sargent

doi:10.1039/C5TC01718A

Structural, optical, and electronic studies of wide-bandgap lead halide perovskites

Riccardo Comin, Grant Walters, Emmanuel Sol Thibau, Oleksandr Voznyy, Zheng-Hong Lu, Edward H. Sargent

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162 Scopus citations

Abstract

© The Royal Society of Chemistry 2015. We investigate the family of mixed Br/Cl organolead halide perovskites which enable light emission in the blue-violet region of the visible spectrum. We report the structural, optical and electronic properties of this air-stable family of perovskites, demonstrating full bandgap tunability in the 400-550 nm range and enhanced exciton strength upon Cl substitution. We complement this study by tracking the evolution of the band levels across the gap, thereby providing a foundational framework for future optoelectronic applications of these materials.

Original language	English (US)
Pages (from-to)	8839-8843
Number of pages	5
Journal	J. Mater. Chem. C
Volume	3
Issue number	34
DOIs	https://doi.org/10.1039/C5TC01718A
State	Published - 2015
Externally published	Yes

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledged KAUST grant number(s): KUS-11-009-21
Acknowledgements: This publication is based in part on work supported by Award KUS-11-009-21, made by the King Abdullah University of Science and Technology (KAUST), by the Ontario Research Fund Research Excellence Program, and by the Natural Sciences and Engineering Research Council.
This publication acknowledges KAUST support, but has no KAUST affiliated authors.

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10.1039/C5TC01718A

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title = "Structural, optical, and electronic studies of wide-bandgap lead halide perovskites",

abstract = "{\textcopyright} The Royal Society of Chemistry 2015. We investigate the family of mixed Br/Cl organolead halide perovskites which enable light emission in the blue-violet region of the visible spectrum. We report the structural, optical and electronic properties of this air-stable family of perovskites, demonstrating full bandgap tunability in the 400-550 nm range and enhanced exciton strength upon Cl substitution. We complement this study by tracking the evolution of the band levels across the gap, thereby providing a foundational framework for future optoelectronic applications of these materials.",

author = "Riccardo Comin and Grant Walters and Thibau, {Emmanuel Sol} and Oleksandr Voznyy and Zheng-Hong Lu and Sargent, {Edward H.}",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledged KAUST grant number(s): KUS-11-009-21 Acknowledgements: This publication is based in part on work supported by Award KUS-11-009-21, made by the King Abdullah University of Science and Technology (KAUST), by the Ontario Research Fund Research Excellence Program, and by the Natural Sciences and Engineering Research Council. This publication acknowledges KAUST support, but has no KAUST affiliated authors.",

year = "2015",

doi = "10.1039/C5TC01718A",

language = "English (US)",

volume = "3",

pages = "8839--8843",

journal = "J. Mater. Chem. C",

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publisher = "Royal Society of Chemistry",

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T1 - Structural, optical, and electronic studies of wide-bandgap lead halide perovskites

AU - Comin, Riccardo

AU - Walters, Grant

AU - Thibau, Emmanuel Sol

AU - Voznyy, Oleksandr

AU - Lu, Zheng-Hong

AU - Sargent, Edward H.

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledged KAUST grant number(s): KUS-11-009-21 Acknowledgements: This publication is based in part on work supported by Award KUS-11-009-21, made by the King Abdullah University of Science and Technology (KAUST), by the Ontario Research Fund Research Excellence Program, and by the Natural Sciences and Engineering Research Council. This publication acknowledges KAUST support, but has no KAUST affiliated authors.

PY - 2015

Y1 - 2015

N2 - © The Royal Society of Chemistry 2015. We investigate the family of mixed Br/Cl organolead halide perovskites which enable light emission in the blue-violet region of the visible spectrum. We report the structural, optical and electronic properties of this air-stable family of perovskites, demonstrating full bandgap tunability in the 400-550 nm range and enhanced exciton strength upon Cl substitution. We complement this study by tracking the evolution of the band levels across the gap, thereby providing a foundational framework for future optoelectronic applications of these materials.

AB - © The Royal Society of Chemistry 2015. We investigate the family of mixed Br/Cl organolead halide perovskites which enable light emission in the blue-violet region of the visible spectrum. We report the structural, optical and electronic properties of this air-stable family of perovskites, demonstrating full bandgap tunability in the 400-550 nm range and enhanced exciton strength upon Cl substitution. We complement this study by tracking the evolution of the band levels across the gap, thereby providing a foundational framework for future optoelectronic applications of these materials.

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U2 - 10.1039/C5TC01718A

DO - 10.1039/C5TC01718A

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SN - 2050-7526

VL - 3

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EP - 8843

JO - J. Mater. Chem. C

JF - J. Mater. Chem. C

IS - 34

ER -

Structural, optical, and electronic studies of wide-bandgap lead halide perovskites

Abstract

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