Structural Evolution of the R-T Phase Boundary in KNN-Based Ceramics

Xiang Lv, Jiagang Wu, Dingquan Xiao, Jianguo Zhu, Xixiang Zhang

Research output: Contribution to journalArticlepeer-review

25 Scopus citations


Although a rhombohedral-tetragonal (R-T) phase boundary is known to substantially enhance the piezoelectric properties of potassium-sodium niobate ceramics, the structural evolution of the R-T phase boundary itself is still unclear. In this work, the structural evolution of R-T phase boundary from -150 °C to 200 °C is investigated in (0.99-x)K0.5Na0.5Nb1-ySbyO3-0.01CaSnO3-xBi0.5K0.5HfO3 (where x=0~0.05 with y=0.035, and y=0~0.07 with x=0.03) ceramics. Through temperature-dependent powder X-ray diffraction (XRD) patterns and Raman spectra, the structural evolution was determined to be Rhombohedral (R, TC). In addition, the enhanced electrical properties (e.g., a direct piezoelectric coefficient (d33) of ~450±5 pC/N, a conversion piezoelectric coefficient (d33*) of ~580±5 pm/V, an electromechanical coupling factor (kp) of ~0.50±0.02, and TC~250 °C), fatigue-free behavior, and good thermal stability were exhibited by the ceramics possessing the R-T phase boundary. This work improves understanding of the physical mechanism behind the R-T phase boundary in KNN-based ceramics and is an important step towards their adoption in practical applications. This article is protected by copyright. All rights reserved.
Original languageEnglish (US)
Pages (from-to)1191-1200
Number of pages10
JournalJournal of the American Ceramic Society
Issue number3
StatePublished - Oct 20 2017

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: National Science Foundation of China, Grant/Award Number: 51722208, 51332003, 51272164; King Abdullah University of Science and Technology (KAUST)


Dive into the research topics of 'Structural Evolution of the R-T Phase Boundary in KNN-Based Ceramics'. Together they form a unique fingerprint.

Cite this