Structural diversity through ligand flexibility: Two novel metal-organic nets via ligand-to-ligand cross-linking of "paddlewheels"

Wenge Qiu; Jason A. Perman; Lukasz Wojtas; Mohamed Eddaoudi; Michael J. Zaworotko

doi:10.1039/c0cc03270k

Structural diversity through ligand flexibility: Two novel metal-organic nets via ligand-to-ligand cross-linking of "paddlewheels"

Wenge Qiu, Jason A. Perman, Lukasz Wojtas, Mohamed Eddaoudi, Michael J. Zaworotko

Physical Sciences and Engineering

Research output: Contribution to journal › Article › peer-review

61 Scopus citations

Abstract

Solvothermal reaction of a partially flexible ligand, H₄L, and Cu(NO₃)₂·2.5H₂O afforded two cross-linked Kagomé lattices of formula [Cu₂(L)]_n: an acs net sustained by novel trigonal prismatic supermolecular building blocks (SBBs) and the first example of a partially pillared Kagomé net.

Original language	English (US)
Pages (from-to)	8734-8736
Number of pages	3
Journal	CHEMICAL COMMUNICATIONS
Volume	46
Issue number	46
DOIs	https://doi.org/10.1039/c0cc03270k
State	Published - Dec 14 2010

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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abstract = "Solvothermal reaction of a partially flexible ligand, H4L, and Cu(NO3)2·2.5H2O afforded two cross-linked Kagom{\'e} lattices of formula [Cu2(L)]n: an acs net sustained by novel trigonal prismatic supermolecular building blocks (SBBs) and the first example of a partially pillared Kagom{\'e} net.",

author = "Wenge Qiu and Perman, {Jason A.} and Lukasz Wojtas and Mohamed Eddaoudi and Zaworotko, {Michael J.}",

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T1 - Structural diversity through ligand flexibility

T2 - Two novel metal-organic nets via ligand-to-ligand cross-linking of "paddlewheels"

AU - Qiu, Wenge

AU - Perman, Jason A.

AU - Wojtas, Lukasz

AU - Eddaoudi, Mohamed

AU - Zaworotko, Michael J.

PY - 2010/12/14

Y1 - 2010/12/14

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AB - Solvothermal reaction of a partially flexible ligand, H4L, and Cu(NO3)2·2.5H2O afforded two cross-linked Kagomé lattices of formula [Cu2(L)]n: an acs net sustained by novel trigonal prismatic supermolecular building blocks (SBBs) and the first example of a partially pillared Kagomé net.

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DO - 10.1039/c0cc03270k

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Structural diversity through ligand flexibility: Two novel metal-organic nets via ligand-to-ligand cross-linking of "paddlewheels"

Abstract

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