Stereochemical behaviour of cis- and trans-cyclo-octene in metathesis

C. Larroche; J. P. Laval; A. Lattes; M. Leconte; F. Quignard; J. M. Basset

doi:10.1039/c39830000220

Stereochemical behaviour of cis- and trans-cyclo-octene in metathesis

C. Larroche^*, J. P. Laval, A. Lattes, M. Leconte, F. Quignard, J. M. Basset

^*Corresponding author for this work

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7 Scopus citations

Abstract

With the catalyst Mo(NO)₂Cl₂(PPh₃) ₂ + EtAlCl₂, cis- and trans-cyclo-octenes give respectively cis- and trans-polyoctenes; cyclic and acyclic olefins have a similar stereochemical behaviour in metathesis but, depending on the strain of the ring, the expected retention of configuration of the starting olefin may be attenuated.

Original language	English (US)
Pages (from-to)	220-221
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	5
DOIs	https://doi.org/10.1039/c39830000220
State	Published - 1983
Externally published	Yes

ASJC Scopus subject areas

Molecular Medicine

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title = "Stereochemical behaviour of cis- and trans-cyclo-octene in metathesis",

abstract = "With the catalyst Mo(NO)2Cl2(PPh3) 2 + EtAlCl2, cis- and trans-cyclo-octenes give respectively cis- and trans-polyoctenes; cyclic and acyclic olefins have a similar stereochemical behaviour in metathesis but, depending on the strain of the ring, the expected retention of configuration of the starting olefin may be attenuated.",

author = "C. Larroche and Laval, {J. P.} and A. Lattes and M. Leconte and F. Quignard and Basset, {J. M.}",

year = "1983",

doi = "10.1039/c39830000220",

language = "English (US)",

pages = "220--221",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "5",

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T1 - Stereochemical behaviour of cis- and trans-cyclo-octene in metathesis

AU - Larroche, C.

AU - Laval, J. P.

AU - Lattes, A.

AU - Leconte, M.

AU - Quignard, F.

AU - Basset, J. M.

PY - 1983

Y1 - 1983

N2 - With the catalyst Mo(NO)2Cl2(PPh3) 2 + EtAlCl2, cis- and trans-cyclo-octenes give respectively cis- and trans-polyoctenes; cyclic and acyclic olefins have a similar stereochemical behaviour in metathesis but, depending on the strain of the ring, the expected retention of configuration of the starting olefin may be attenuated.

AB - With the catalyst Mo(NO)2Cl2(PPh3) 2 + EtAlCl2, cis- and trans-cyclo-octenes give respectively cis- and trans-polyoctenes; cyclic and acyclic olefins have a similar stereochemical behaviour in metathesis but, depending on the strain of the ring, the expected retention of configuration of the starting olefin may be attenuated.

UR - http://www.scopus.com/inward/record.url?scp=37049096202&partnerID=8YFLogxK

U2 - 10.1039/c39830000220

DO - 10.1039/c39830000220

M3 - Article

AN - SCOPUS:37049096202

SN - 0022-4936

SP - 220

EP - 221

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 5

ER -

Stereochemical behaviour of cis- and trans-cyclo-octene in metathesis

Abstract

ASJC Scopus subject areas

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