Stable iron-incorporated mesoporous silica materials (MFS-9) prepared in strong acidic media

Yu Han; Xiangju Meng; Hongbo Guan; Yi Yu; Lan Zhao; Xianzhu Xu; Xiaoyu Yang; Shou Wu; Nan Li; Feng Shou Xiao

doi:10.1016/S1387-1811(02)00590-5

Stable iron-incorporated mesoporous silica materials (MFS-9) prepared in strong acidic media

Yu Han, Xiangju Meng, Hongbo Guan, Yi Yu, Lan Zhao, Xianzhu Xu, Xiaoyu Yang, Shou Wu, Nan Li, Feng Shou Xiao

Research output: Contribution to journal › Article › peer-review

60 Scopus citations

Abstract

Iron-incorporated mesoporous silica materials (MFS-9) have been successfully prepared in strong acidic media by a two-step synthesis procedure, which has an hexagonal structure with uniform mesopores and exhibits superior hydrothermal stability and high catalytic activities for the hydroxylation of phenol and also of bulky trimethylphenol. Xray diffraction data show that mesoporous ferrisilicate (MFS-9) can retain its mesoporous structure in boiling water up to 100 h. Characterization of MFS-9 by a variety of spectroscopic techniques, including electron spin resonance, UV- vis and UV-Raman spectroscopies, suggests that Fe species in the framework of MFS-9 are mainly tetrahedrally coordinated even after calcination at 823 K. © 2002 Elsevier Science Inc. All rights reserved.

Original language	English (US)
Pages (from-to)	191-198
Number of pages	8
Journal	Microporous and Mesoporous Materials
Volume	57
Issue number	2
DOIs	https://doi.org/10.1016/S1387-1811(02)00590-5
State	Published - Jan 16 2003
Externally published	Yes

Bibliographical note

Generated from Scopus record by KAUST IRTS on 2023-09-21

ASJC Scopus subject areas

Mechanics of Materials
General Materials Science
General Chemistry
Condensed Matter Physics

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10.1016/S1387-1811(02)00590-5

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title = "Stable iron-incorporated mesoporous silica materials (MFS-9) prepared in strong acidic media",

abstract = "Iron-incorporated mesoporous silica materials (MFS-9) have been successfully prepared in strong acidic media by a two-step synthesis procedure, which has an hexagonal structure with uniform mesopores and exhibits superior hydrothermal stability and high catalytic activities for the hydroxylation of phenol and also of bulky trimethylphenol. Xray diffraction data show that mesoporous ferrisilicate (MFS-9) can retain its mesoporous structure in boiling water up to 100 h. Characterization of MFS-9 by a variety of spectroscopic techniques, including electron spin resonance, UV- vis and UV-Raman spectroscopies, suggests that Fe species in the framework of MFS-9 are mainly tetrahedrally coordinated even after calcination at 823 K. {\textcopyright} 2002 Elsevier Science Inc. All rights reserved.",

author = "Yu Han and Xiangju Meng and Hongbo Guan and Yi Yu and Lan Zhao and Xianzhu Xu and Xiaoyu Yang and Shou Wu and Nan Li and Xiao, {Feng Shou}",

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T1 - Stable iron-incorporated mesoporous silica materials (MFS-9) prepared in strong acidic media

AU - Han, Yu

AU - Meng, Xiangju

AU - Guan, Hongbo

AU - Yu, Yi

AU - Zhao, Lan

AU - Xu, Xianzhu

AU - Yang, Xiaoyu

AU - Wu, Shou

AU - Li, Nan

AU - Xiao, Feng Shou

N1 - Generated from Scopus record by KAUST IRTS on 2023-09-21

PY - 2003/1/16

Y1 - 2003/1/16

N2 - Iron-incorporated mesoporous silica materials (MFS-9) have been successfully prepared in strong acidic media by a two-step synthesis procedure, which has an hexagonal structure with uniform mesopores and exhibits superior hydrothermal stability and high catalytic activities for the hydroxylation of phenol and also of bulky trimethylphenol. Xray diffraction data show that mesoporous ferrisilicate (MFS-9) can retain its mesoporous structure in boiling water up to 100 h. Characterization of MFS-9 by a variety of spectroscopic techniques, including electron spin resonance, UV- vis and UV-Raman spectroscopies, suggests that Fe species in the framework of MFS-9 are mainly tetrahedrally coordinated even after calcination at 823 K. © 2002 Elsevier Science Inc. All rights reserved.

AB - Iron-incorporated mesoporous silica materials (MFS-9) have been successfully prepared in strong acidic media by a two-step synthesis procedure, which has an hexagonal structure with uniform mesopores and exhibits superior hydrothermal stability and high catalytic activities for the hydroxylation of phenol and also of bulky trimethylphenol. Xray diffraction data show that mesoporous ferrisilicate (MFS-9) can retain its mesoporous structure in boiling water up to 100 h. Characterization of MFS-9 by a variety of spectroscopic techniques, including electron spin resonance, UV- vis and UV-Raman spectroscopies, suggests that Fe species in the framework of MFS-9 are mainly tetrahedrally coordinated even after calcination at 823 K. © 2002 Elsevier Science Inc. All rights reserved.

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U2 - 10.1016/S1387-1811(02)00590-5

DO - 10.1016/S1387-1811(02)00590-5

M3 - Article

SN - 1387-1811

VL - 57

SP - 191

EP - 198

JO - Microporous and Mesoporous Materials

JF - Microporous and Mesoporous Materials

IS - 2

ER -

Stable iron-incorporated mesoporous silica materials (MFS-9) prepared in strong acidic media

Abstract

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ASJC Scopus subject areas

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