Spontaneous intra-electron transfer within rGO@Fe₂O₃-MnO catalyst promotes long-term NO_x reduction at ambient conditions

Iron (Fe)-based catalysts are widely used for taming nitrogen oxides (NO_x) containing flue gas, but the regeneration and long-term reusability remains a concern. The reusability can be acquired by external additives, and resultantly can not only increase the cost but can also add to process complexity as well as secondary pollutants. Herein, a self-sustainable material is designed to regenerate the catalyst for long-term reusability without adding to process complexity. The catalyst is based on reduced graphene-oxide impregnated by Fe₂O₃-MnO (rGO@Fe₂O₃-MnO; G-F-M) for spontaneous intra electron (e^-)-transfer from Mn to Fe. The developed catalyst; G-M-F exhibited 93.7% NO_x reduction, which suggests its high catalytic activity. The morphological and structure characterizations confirmed the Fe/Mn loading, contributing to e^--transfer between Mn and Fe due to its conductivity. The synthesized G-F-M showed higher NO_x reduction about 2.5 folds, than rGO@Fe₂O₃ (G-FeO) and rGO@MnO_x (G-MnO_x). The performance of G-M-F without and with an electrochemical system was also compared, and the difference was only 5%, which is an evidence of the spontaneous e^- transfer between the Mn and Fe-NO_x complex. The designed catalyst can be used for a long time without external assistance, and its efficiency was not affected significantly (<3.7%) in the presence of high oxygen contents (8%). The as-prepared G-M-F catalyst has great potential for executing a dual role NOx removal and self-regeneration of catalyst (SRC), promoting a sustainable remediation approach for large-scale applications.