Spectroscopic Signatures for Interlayer Coupling in MoS 2 –WSe 2 van der Waals Stacking

Ming-Hui Chiu, Ming-yang Li, Wengjing Zhang, Wei-Ting Hsu, Wen-Hao Chang, Mauricio Terrones, Humberto Terrones, Lain-Jong Li

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285 Scopus citations


Stacking of MoS2 and WSe2 monolayers is conducted by transferring triangular MoS2 monolayers on top of WSe2 monolayers, all grown by chemical vapor deposition (CVD). Raman spectroscopy and photoluminescence (PL) studies reveal that these mechanically stacked monolayers are not closely coupled, but after a thermal treatment at 300 degrees C, it is possible to produce van der Waals solids consisting of two interacting transition metal dichalcogenide (TMD) monolayers. The layer-number sensitive Raman out-of-plane mode A(1g)(2) for WSe2 (309 cm(-1)) is found sensitive to the coupling between two TMD monolayers. The presence of interlayer excitonic emissions and the changes in other intrinsic Raman modes such as E '' for MoS2 at 286 cm(-1) and A(1g)(2) for MoS2 at around 463 cm(-1) confirm the enhancement of the interlayer coupling.
Original languageEnglish (US)
Pages (from-to)9649-9656
Number of pages8
JournalACS Nano
Issue number9
StatePublished - Sep 10 2014

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KAUST Repository Item: Exported on 2020-10-01


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