Solution-processable polymers of intrinsic microporosity for gas-phase carbon dioxide photoreduction.

Floriana Moruzzi; Weimin Zhang; Balaji Purushothaman; Soranyel Gonzalez-Carrero; Catherine M Aitchison; Benjamin Willner; Fabien Ceugniet; yuanbao lin; Jan Kosco; Hu Chen; Junfu Tian; Maryam Alsufyani; Joshua S Gibson; Ed Rattner; Yasmine Baghdadi; Salvador Eslava; Marios Neophytou; James R. Durrant; Ludmilla Steier; Iain McCulloch

doi:10.1038/s41467-023-39161-6

Solution-processable polymers of intrinsic microporosity for gas-phase carbon dioxide photoreduction.

Floriana Moruzzi, Weimin Zhang, Balaji Purushothaman, Soranyel Gonzalez-Carrero, Catherine M Aitchison, Benjamin Willner, Fabien Ceugniet, yuanbao lin, Jan Kosco, Hu Chen, Junfu Tian, Maryam Alsufyani, Joshua S Gibson, Ed Rattner, Yasmine Baghdadi, Salvador Eslava, Marios Neophytou, James R. Durrant, Ludmilla Steier, Iain McCulloch

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12 Scopus citations

Abstract

Four solution-processable, linear conjugated polymers of intrinsic porosity are synthesised and tested for gas phase carbon dioxide photoreduction. The polymers’ photoreduction efficiency is investigated as a function of their porosity, optical properties, energy levels and photoluminescence. All polymers successfully form carbon monoxide as the main product, without the addition of metal co-catalysts. The best performing single component polymer yields a rate of 66 μmol h−1 m−2, which we attribute to the polymer exhibiting macroporosity and the longest exciton lifetimes. The addition of copper iodide, as a source of a copper co-catalyst in the polymers shows an increase in rate, with the best performing polymer achieving a rate of 175 μmol h−1 m−2. The polymers are active for over 100 h under operating conditions. This work shows the potential of processable polymers of intrinsic porosity for use in the gas phase photoreduction of carbon dioxide towards solar fuels.

Original language	English (US)
Journal	Nature Communications
Volume	14
Issue number	1
DOIs	https://doi.org/10.1038/s41467-023-39161-6
State	Published - Jun 10 2023

Bibliographical note

KAUST Repository Item: Exported on 2023-06-14
Acknowledged KAUST grant number(s): CRG10
Acknowledgements: The authors would like to acknowledge financial support from KAUST Office of Sponsored Research CRG10, by EU Horizon 2020 grant agreement no. 952911, BOOSTER, grant agreement no. 862474, RoLA-FLEX, and grant agreement no. 101007084 CITYSOLAR, as well as EPSRC Projects EP/T026219/1, EP/W017091/1 and EP/S030727/1. The authors would like to acknowledge the Henry Royce Institute (through UK Engineering and Physical Science Research Council grant EP/R010145/1) for capital equipment.

ASJC Scopus subject areas

General Biochemistry, Genetics and Molecular Biology
General Chemistry
General Physics and Astronomy

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10.1038/s41467-023-39161-6

https://repository.kaust.edu.sa/bitstream/10754/692581/3/s41467-023-39161-6%20%281%29.pdf

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Moruzzi, F., Zhang, W., Purushothaman, B., Gonzalez-Carrero, S., Aitchison, C. M., Willner, B., Ceugniet, F., lin, Y., Kosco, J., Chen, H., Tian, J., Alsufyani, M., Gibson, J. S., Rattner, E., Baghdadi, Y., Eslava, S., Neophytou, M., Durrant, J. R., Steier, L., & McCulloch, I. (2023). Solution-processable polymers of intrinsic microporosity for gas-phase carbon dioxide photoreduction. Nature Communications, 14(1). https://doi.org/10.1038/s41467-023-39161-6

@article{26663ac055e149d287652c19b1bb655e,

title = "Solution-processable polymers of intrinsic microporosity for gas-phase carbon dioxide photoreduction.",

abstract = "Four solution-processable, linear conjugated polymers of intrinsic porosity are synthesised and tested for gas phase carbon dioxide photoreduction. The polymers{\textquoteright} photoreduction efficiency is investigated as a function of their porosity, optical properties, energy levels and photoluminescence. All polymers successfully form carbon monoxide as the main product, without the addition of metal co-catalysts. The best performing single component polymer yields a rate of 66 μmol h−1 m−2, which we attribute to the polymer exhibiting macroporosity and the longest exciton lifetimes. The addition of copper iodide, as a source of a copper co-catalyst in the polymers shows an increase in rate, with the best performing polymer achieving a rate of 175 μmol h−1 m−2. The polymers are active for over 100 h under operating conditions. This work shows the potential of processable polymers of intrinsic porosity for use in the gas phase photoreduction of carbon dioxide towards solar fuels.",

author = "Floriana Moruzzi and Weimin Zhang and Balaji Purushothaman and Soranyel Gonzalez-Carrero and Aitchison, {Catherine M} and Benjamin Willner and Fabien Ceugniet and yuanbao lin and Jan Kosco and Hu Chen and Junfu Tian and Maryam Alsufyani and Gibson, {Joshua S} and Ed Rattner and Yasmine Baghdadi and Salvador Eslava and Marios Neophytou and Durrant, {James R.} and Ludmilla Steier and Iain McCulloch",

note = "KAUST Repository Item: Exported on 2023-06-14 Acknowledged KAUST grant number(s): CRG10 Acknowledgements: The authors would like to acknowledge financial support from KAUST Office of Sponsored Research CRG10, by EU Horizon 2020 grant agreement no. 952911, BOOSTER, grant agreement no. 862474, RoLA-FLEX, and grant agreement no. 101007084 CITYSOLAR, as well as EPSRC Projects EP/T026219/1, EP/W017091/1 and EP/S030727/1. The authors would like to acknowledge the Henry Royce Institute (through UK Engineering and Physical Science Research Council grant EP/R010145/1) for capital equipment.",

year = "2023",

month = jun,

day = "10",

doi = "10.1038/s41467-023-39161-6",

language = "English (US)",

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journal = "Nature Communications",

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Moruzzi, F, Zhang, W, Purushothaman, B, Gonzalez-Carrero, S, Aitchison, CM, Willner, B, Ceugniet, F, lin, Y, Kosco, J, Chen, H, Tian, J, Alsufyani, M, Gibson, JS, Rattner, E, Baghdadi, Y, Eslava, S, Neophytou, M, Durrant, JR, Steier, L & McCulloch, I 2023, 'Solution-processable polymers of intrinsic microporosity for gas-phase carbon dioxide photoreduction.', Nature Communications, vol. 14, no. 1. https://doi.org/10.1038/s41467-023-39161-6

TY - JOUR

T1 - Solution-processable polymers of intrinsic microporosity for gas-phase carbon dioxide photoreduction.

AU - Moruzzi, Floriana

AU - Zhang, Weimin

AU - Purushothaman, Balaji

AU - Gonzalez-Carrero, Soranyel

AU - Aitchison, Catherine M

AU - Willner, Benjamin

AU - Ceugniet, Fabien

AU - lin, yuanbao

AU - Kosco, Jan

AU - Chen, Hu

AU - Tian, Junfu

AU - Alsufyani, Maryam

AU - Gibson, Joshua S

AU - Rattner, Ed

AU - Baghdadi, Yasmine

AU - Eslava, Salvador

AU - Neophytou, Marios

AU - Durrant, James R.

AU - Steier, Ludmilla

AU - McCulloch, Iain

N1 - KAUST Repository Item: Exported on 2023-06-14 Acknowledged KAUST grant number(s): CRG10 Acknowledgements: The authors would like to acknowledge financial support from KAUST Office of Sponsored Research CRG10, by EU Horizon 2020 grant agreement no. 952911, BOOSTER, grant agreement no. 862474, RoLA-FLEX, and grant agreement no. 101007084 CITYSOLAR, as well as EPSRC Projects EP/T026219/1, EP/W017091/1 and EP/S030727/1. The authors would like to acknowledge the Henry Royce Institute (through UK Engineering and Physical Science Research Council grant EP/R010145/1) for capital equipment.

PY - 2023/6/10

Y1 - 2023/6/10

N2 - Four solution-processable, linear conjugated polymers of intrinsic porosity are synthesised and tested for gas phase carbon dioxide photoreduction. The polymers’ photoreduction efficiency is investigated as a function of their porosity, optical properties, energy levels and photoluminescence. All polymers successfully form carbon monoxide as the main product, without the addition of metal co-catalysts. The best performing single component polymer yields a rate of 66 μmol h−1 m−2, which we attribute to the polymer exhibiting macroporosity and the longest exciton lifetimes. The addition of copper iodide, as a source of a copper co-catalyst in the polymers shows an increase in rate, with the best performing polymer achieving a rate of 175 μmol h−1 m−2. The polymers are active for over 100 h under operating conditions. This work shows the potential of processable polymers of intrinsic porosity for use in the gas phase photoreduction of carbon dioxide towards solar fuels.

AB - Four solution-processable, linear conjugated polymers of intrinsic porosity are synthesised and tested for gas phase carbon dioxide photoreduction. The polymers’ photoreduction efficiency is investigated as a function of their porosity, optical properties, energy levels and photoluminescence. All polymers successfully form carbon monoxide as the main product, without the addition of metal co-catalysts. The best performing single component polymer yields a rate of 66 μmol h−1 m−2, which we attribute to the polymer exhibiting macroporosity and the longest exciton lifetimes. The addition of copper iodide, as a source of a copper co-catalyst in the polymers shows an increase in rate, with the best performing polymer achieving a rate of 175 μmol h−1 m−2. The polymers are active for over 100 h under operating conditions. This work shows the potential of processable polymers of intrinsic porosity for use in the gas phase photoreduction of carbon dioxide towards solar fuels.

UR - http://hdl.handle.net/10754/692581

UR - https://www.nature.com/articles/s41467-023-39161-6

U2 - 10.1038/s41467-023-39161-6

DO - 10.1038/s41467-023-39161-6

M3 - Article

C2 - 37301872

SN - 2041-1723

VL - 14

JO - Nature Communications

JF - Nature Communications

IS - 1

ER -

Solution-processable polymers of intrinsic microporosity for gas-phase carbon dioxide photoreduction.

Abstract

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