Solute influence on the high-pressure phase equilibrium of ternary systems with carbon dioxide and an ionic liquid

To study the potential of performing hydrogenation reactions in ionic liquid-CO₂ media, the high-pressure phase equilibrium of the ternary system 1-butyl-3-methylimidazolium tetrafluoroborate (bmim[BF₄]) + 4-isobutylacetophenone + carbon dioxide (CO₂) has been investigated. Experiments were performed in the Cailletet apparatus in a temperature range from 278.15 up to 368.15 K while pressures up to 14 MPa were applied. In this system, not only liquid-vapor boundaries were found, but also at high CO₂ concentrations liquid-liquid biphasic equilibrium occurred.¹1Additional experiments are in progress. These results will be presented in a subsequent contribution. A comparison between the experimental results of this work, the data collected for the binary system bmim[BF₄] + CO₂ and a ternary system with acetophenone as the solute shows that the type of solute added can dramatically change the phase behavior of the system.