Solubility of carbon dioxide in systems with [bmim][BF4] and some selected organic compounds of interest for the pharmaceutical industry

Eliane Kühne; Cor J. Peters; Jaap van Spronsen; Geert Jan Witkamp

doi:10.1039/b513132d

Solubility of carbon dioxide in systems with [bmim][BF₄] and some selected organic compounds of interest for the pharmaceutical industry

Eliane Kühne, Cor J. Peters^*, Jaap van Spronsen, Geert Jan Witkamp

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

24 Scopus citations

Abstract

This work presents phase equilibrium data of the ternary system CO₂+ [bmim][BF₄] + solute. Three different organic compounds were studied as the solute in the ternary system: 1-methyl-3-phenylpiperazine (MPhPz), 2-chloro-nicotinonitrile (NtN) and 2-(4-methyl-2-phenyl-1-piperazinyl)-3-pyridinecarbonitrile (PCN). Experiments were carried out in a pressure and temperature range of 1–14 MPa and 343.15–443.15 K, respectively. Samples were prepared with CO₂ molar fractions of 0.10 until 0.40 for the system with NtN as the solute, and 0.20 for the other two systems for comparison. The data collected show how the various solutes affect the phase behavior of the binary system CO₂ + [bmim][BF₄], and at which conditions homogeneous phase can be obtained.

Original language	English (US)
Pages (from-to)	287-291
Number of pages	5
Journal	Green Chemistry
Volume	8
Issue number	3
DOIs	https://doi.org/10.1039/b513132d
State	Published - Mar 2 2006
Externally published	Yes

ASJC Scopus subject areas

Environmental Chemistry
Pollution

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title = "Solubility of carbon dioxide in systems with [bmim][BF4] and some selected organic compounds of interest for the pharmaceutical industry",

abstract = "This work presents phase equilibrium data of the ternary system CO2+ [bmim][BF4] + solute. Three different organic compounds were studied as the solute in the ternary system: 1-methyl-3-phenylpiperazine (MPhPz), 2-chloro-nicotinonitrile (NtN) and 2-(4-methyl-2-phenyl-1-piperazinyl)-3-pyridinecarbonitrile (PCN). Experiments were carried out in a pressure and temperature range of 1–14 MPa and 343.15–443.15 K, respectively. Samples were prepared with CO2 molar fractions of 0.10 until 0.40 for the system with NtN as the solute, and 0.20 for the other two systems for comparison. The data collected show how the various solutes affect the phase behavior of the binary system CO2 + [bmim][BF4], and at which conditions homogeneous phase can be obtained.",

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AU - Kühne, Eliane

AU - Peters, Cor J.

AU - van Spronsen, Jaap

AU - Witkamp, Geert Jan

PY - 2006/3/2

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N2 - This work presents phase equilibrium data of the ternary system CO2+ [bmim][BF4] + solute. Three different organic compounds were studied as the solute in the ternary system: 1-methyl-3-phenylpiperazine (MPhPz), 2-chloro-nicotinonitrile (NtN) and 2-(4-methyl-2-phenyl-1-piperazinyl)-3-pyridinecarbonitrile (PCN). Experiments were carried out in a pressure and temperature range of 1–14 MPa and 343.15–443.15 K, respectively. Samples were prepared with CO2 molar fractions of 0.10 until 0.40 for the system with NtN as the solute, and 0.20 for the other two systems for comparison. The data collected show how the various solutes affect the phase behavior of the binary system CO2 + [bmim][BF4], and at which conditions homogeneous phase can be obtained.

AB - This work presents phase equilibrium data of the ternary system CO2+ [bmim][BF4] + solute. Three different organic compounds were studied as the solute in the ternary system: 1-methyl-3-phenylpiperazine (MPhPz), 2-chloro-nicotinonitrile (NtN) and 2-(4-methyl-2-phenyl-1-piperazinyl)-3-pyridinecarbonitrile (PCN). Experiments were carried out in a pressure and temperature range of 1–14 MPa and 343.15–443.15 K, respectively. Samples were prepared with CO2 molar fractions of 0.10 until 0.40 for the system with NtN as the solute, and 0.20 for the other two systems for comparison. The data collected show how the various solutes affect the phase behavior of the binary system CO2 + [bmim][BF4], and at which conditions homogeneous phase can be obtained.

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Solubility of carbon dioxide in systems with [bmim][BF₄] and some selected organic compounds of interest for the pharmaceutical industry

Abstract

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