Solid-State Molecular Nanomagnet Inclusion into a Magnetic Metal-Organic Framework: Interplay of the Magnetic Properties

Marta Mon; Alejandro Pascual-Álvarez; Thais Grancha; Joan Cano; Jesús Ferrando-Soria; Francesc Lloret; Jorge Gascon; Jorge Pasán; Donatella Armentano; Emilio Pardo

doi:10.1002/chem.201504176

Solid-State Molecular Nanomagnet Inclusion into a Magnetic Metal-Organic Framework: Interplay of the Magnetic Properties

Marta Mon, Alejandro Pascual-Álvarez, Thais Grancha, Joan Cano, Jesús Ferrando-Soria, Francesc Lloret, Jorge Gascon, Jorge Pasán, Donatella Armentano^*, Emilio Pardo

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

62 Scopus citations

Abstract

Single-ion magnets (SIMs) are the smallest possible magnetic devices and are a controllable, bottom-up approach to nanoscale magnetism with potential applications in quantum computing and high-density information storage. In this work, we take advantage of the promising, but yet insufficiently explored, solid-state chemistry of metal-organic frameworks (MOFs) to report the single-crystal to single-crystal inclusion of such molecular nanomagnets within the pores of a magnetic MOF. The resulting host-guest supramolecular aggregate is used as a playground in the first in-depth study on the interplay between the internal magnetic field created by the long-range magnetic ordering of the structured MOF and the slow magnetic relaxation of the SIM.

Original language	English (US)
Pages (from-to)	539-545
Number of pages	7
Journal	Chemistry - A European Journal
Volume	22
Issue number	2
DOIs	https://doi.org/10.1002/chem.201504176
State	Published - Jan 11 2016
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Keywords

magnetic ordering
metal-organic frameworks
multifunctional materials
quantum tunneling effects
single-ion magnet

ASJC Scopus subject areas

Catalysis
Organic Chemistry

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10.1002/chem.201504176

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abstract = "Single-ion magnets (SIMs) are the smallest possible magnetic devices and are a controllable, bottom-up approach to nanoscale magnetism with potential applications in quantum computing and high-density information storage. In this work, we take advantage of the promising, but yet insufficiently explored, solid-state chemistry of metal-organic frameworks (MOFs) to report the single-crystal to single-crystal inclusion of such molecular nanomagnets within the pores of a magnetic MOF. The resulting host-guest supramolecular aggregate is used as a playground in the first in-depth study on the interplay between the internal magnetic field created by the long-range magnetic ordering of the structured MOF and the slow magnetic relaxation of the SIM.",

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AU - Mon, Marta

AU - Pascual-Álvarez, Alejandro

AU - Grancha, Thais

AU - Cano, Joan

AU - Ferrando-Soria, Jesús

AU - Lloret, Francesc

AU - Gascon, Jorge

AU - Pasán, Jorge

AU - Armentano, Donatella

AU - Pardo, Emilio

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KW - metal-organic frameworks

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KW - quantum tunneling effects

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Solid-State Molecular Nanomagnet Inclusion into a Magnetic Metal-Organic Framework: Interplay of the Magnetic Properties

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

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