Sodium benzenesulfonothioate

Alexander Rothenberger; Robert Langer

doi:10.1107/S1600536807059065

Sodium benzenesulfonothioate

Alexander Rothenberger^*, Robert Langer

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

The title compound, Na⁺·C6H5O2S2 ^-, at 100 (2) K has ortho-rhom-bic (Cmca) symmetry. The compound has a network structure. It is of inter-est with respect to inclusion phenomena and structure-activity relationships. The Na atoms are chelated by two different benzenesulfonothioate anions via -S and O atoms. Additional coordination by O atoms of two other benzenesulfonothioate anions results in coordination number 6 for each Na atom in the extended two-dimensional polymeric structure. The structure exhibits disorder of the anion in the two-dimensional arrangement. The phenyl group is disordered equally over two positions.

Original language	English (US)
Pages (from-to)	m3093
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	63
Issue number	12
DOIs	https://doi.org/10.1107/S1600536807059065
State	Published - Nov 9 2007
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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10.1107/S1600536807059065

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title = "Sodium benzenesulfonothioate",

abstract = "The title compound, Na+·C6H5O2S2 -, at 100 (2) K has ortho-rhom-bic (Cmca) symmetry. The compound has a network structure. It is of inter-est with respect to inclusion phenomena and structure-activity relationships. The Na atoms are chelated by two different benzenesulfonothioate anions via -S and O atoms. Additional coordination by O atoms of two other benzenesulfonothioate anions results in coordination number 6 for each Na atom in the extended two-dimensional polymeric structure. The structure exhibits disorder of the anion in the two-dimensional arrangement. The phenyl group is disordered equally over two positions.",

author = "Alexander Rothenberger and Robert Langer",

year = "2007",

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day = "9",

doi = "10.1107/S1600536807059065",

language = "English (US)",

volume = "63",

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publisher = "International Union of Crystallography",

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T1 - Sodium benzenesulfonothioate

AU - Rothenberger, Alexander

AU - Langer, Robert

PY - 2007/11/9

Y1 - 2007/11/9

N2 - The title compound, Na+·C6H5O2S2 -, at 100 (2) K has ortho-rhom-bic (Cmca) symmetry. The compound has a network structure. It is of inter-est with respect to inclusion phenomena and structure-activity relationships. The Na atoms are chelated by two different benzenesulfonothioate anions via -S and O atoms. Additional coordination by O atoms of two other benzenesulfonothioate anions results in coordination number 6 for each Na atom in the extended two-dimensional polymeric structure. The structure exhibits disorder of the anion in the two-dimensional arrangement. The phenyl group is disordered equally over two positions.

AB - The title compound, Na+·C6H5O2S2 -, at 100 (2) K has ortho-rhom-bic (Cmca) symmetry. The compound has a network structure. It is of inter-est with respect to inclusion phenomena and structure-activity relationships. The Na atoms are chelated by two different benzenesulfonothioate anions via -S and O atoms. Additional coordination by O atoms of two other benzenesulfonothioate anions results in coordination number 6 for each Na atom in the extended two-dimensional polymeric structure. The structure exhibits disorder of the anion in the two-dimensional arrangement. The phenyl group is disordered equally over two positions.

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U2 - 10.1107/S1600536807059065

DO - 10.1107/S1600536807059065

M3 - Article

AN - SCOPUS:36849022743

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VL - 63

SP - m3093

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 12

ER -

Sodium benzenesulfonothioate

Abstract

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