Sodium and Potassium Ion Selective Conjugated Polymers for Optical Ion Detection in Solution and Solid State

Alexander Giovannitti*, Christian B. Nielsen, Jonathan Rivnay, Mindaugas Kirkus, David J. Harkin, Andrew J.P. White, Henning Sirringhaus, George G. Malliaras, Iain McCulloch

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

49 Scopus citations


This paper presents the development of alkali metal ion selective small molecules and conjugated polymers for optical ion sensing. A crown ether bithiophene unit is chosen as the detecting unit, as both a small molecule and incorporated into a conjugated aromatic structure. The complex formation and the resulting backbone twist of the detector unit is investigated by UV-vis and NMR spectroscopy where a remarkable selectivity toward sodium or potassium ions is found. X-ray diffraction analysis of single crystals with and without alkali metal ions is carried out and a difference of the dihedral angle of more than 70' is observed. In a conjugated polymer structure, the detector unit has a higher sensitivity for alkali metal ion detection than its small molecule analog. Ion selectivity is retained in polymers with solubility in polar solvents facilitated by the attachment of polar ethylene glycol side chains. This design concept is further evolved to develop a sodium-salt solid state sensor based on blends of the detecting polymer with a polyvinyl alcohol matrix where the detection of sodium ions is achieved in aqueous salt solutions with concentrations similar to biologically important environments.

Original languageEnglish (US)
Pages (from-to)514-523
Number of pages10
JournalAdvanced Functional Materials
Issue number4
StatePublished - Jan 26 2016

Bibliographical note

Funding Information:
We thank EPSRC Project EP/G037515/1, EC FP7 Project SC2 (610115), EC FP7 Project ArtESun (604397), and EC FP7 POLYMED (612538) for the fi nancial support.

Publisher Copyright:
© 2015 The Authors. Published by WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.


  • alkali metal ion selective polymers
  • backbone twist
  • chromoionophore
  • optical solid state sensor
  • polymer-polymer blend

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics


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