Slow Energy Transfer in Self-Doped β-Conformation Film of Steric Polydiarylfluorenes toward Stable Dual Deep-Blue Amplified Spontaneous Emission

Man Xu; Lili Sun; Shengjie Wang; Jinyi Lin; Mengna Yu; Xuhua Wang; Paul N. Stavrinou; Linghai Xie; Nathan J. Cheetham; Xuehua Ding; Donal Bradley; Wei Huang

doi:10.1002/adom.202100723

Slow Energy Transfer in Self-Doped β-Conformation Film of Steric Polydiarylfluorenes toward Stable Dual Deep-Blue Amplified Spontaneous Emission

Man Xu, Lili Sun, Shengjie Wang, Jinyi Lin, Mengna Yu, Xuhua Wang, Paul N. Stavrinou, Linghai Xie, Nathan J. Cheetham, Xuehua Ding, Donal Bradley, Wei Huang

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

Exciton behavior is crucial for improving the optoelectronic property of a light-emitting conjugated polymer. Herein, the photoexcitation dynamics of exciton migration and energy transfer in a self-doped β-conformation film of the polydiarylfluorenes (poly[4-(octyloxy)-9,9-diphenylfluoren-2,7-diyl]-co-[5-(octyloxy)-9,9- diphenylfluoren-2,7-diyl], PODPF) are demonstrated. Compared to the first generation of the β-conformation polyfluorene, poly(9,9-dioctylfluorene) (PFO), energy transfer occurs in PODPF β-conformation films in a time period of ≈150 ps, much longer than those of the PFO ones (

Original language	English (US)
Pages (from-to)	2100723
Journal	Advanced Optical Materials
DOIs	https://doi.org/10.1002/adom.202100723
State	Published - Oct 18 2021

Bibliographical note

KAUST Repository Item: Exported on 2021-10-26
Acknowledgements: M.X. and L.S. contributed equally to this work. The work was supported by the National Natural Science Foundation of China (22075136, 61874053), National Key Research and Development Program of China (2020YFA0709900), Natural Science Funds of the Education Committee of Jiangsu Province (18KJA430009), Natural Science Foundation of Jiangsu Province (BK20200700), “High-Level Talents in Six Industries” of Jiangsu Province (XYDXX-019), Research Innovation in University of Jiangsu Province (KYCX21_0771), the open research fund from State Key Laboratory of Supramolecular Structure, Materials (sklssm202108) and Anhui Province Key Laboratory of Environment-friendly Polymer Materials and and Anhui Province Key Laboratory of Optoelectronic Materials Science and Technology. N.C. received support from an EPSRC Doctoral Training Studentship at the Centre for Plastic Electronics at Imperial College London.

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Atomic and Molecular Physics, and Optics

Access to Document

10.1002/adom.202100723

Cite this

@article{6a49c94859a74e40922acc441cf121da,

title = "Slow Energy Transfer in Self-Doped β-Conformation Film of Steric Polydiarylfluorenes toward Stable Dual Deep-Blue Amplified Spontaneous Emission",

abstract = "Exciton behavior is crucial for improving the optoelectronic property of a light-emitting conjugated polymer. Herein, the photoexcitation dynamics of exciton migration and energy transfer in a self-doped β-conformation film of the polydiarylfluorenes (poly[4-(octyloxy)-9,9-diphenylfluoren-2,7-diyl]-co-[5-(octyloxy)-9,9- diphenylfluoren-2,7-diyl], PODPF) are demonstrated. Compared to the first generation of the β-conformation polyfluorene, poly(9,9-dioctylfluorene) (PFO), energy transfer occurs in PODPF β-conformation films in a time period of ≈150 ps, much longer than those of the PFO ones (",

author = "Man Xu and Lili Sun and Shengjie Wang and Jinyi Lin and Mengna Yu and Xuhua Wang and Stavrinou, {Paul N.} and Linghai Xie and Cheetham, {Nathan J.} and Xuehua Ding and Donal Bradley and Wei Huang",

note = "KAUST Repository Item: Exported on 2021-10-26 Acknowledgements: M.X. and L.S. contributed equally to this work. The work was supported by the National Natural Science Foundation of China (22075136, 61874053), National Key Research and Development Program of China (2020YFA0709900), Natural Science Funds of the Education Committee of Jiangsu Province (18KJA430009), Natural Science Foundation of Jiangsu Province (BK20200700), “High-Level Talents in Six Industries” of Jiangsu Province (XYDXX-019), Research Innovation in University of Jiangsu Province (KYCX21_0771), the open research fund from State Key Laboratory of Supramolecular Structure, Materials (sklssm202108) and Anhui Province Key Laboratory of Environment-friendly Polymer Materials and and Anhui Province Key Laboratory of Optoelectronic Materials Science and Technology. N.C. received support from an EPSRC Doctoral Training Studentship at the Centre for Plastic Electronics at Imperial College London.",

year = "2021",

month = oct,

day = "18",

doi = "10.1002/adom.202100723",

language = "English (US)",

pages = "2100723",

journal = "Advanced Optical Materials",

issn = "2195-1071",

publisher = "John Wiley & Sons Inc.",

}

TY - JOUR

T1 - Slow Energy Transfer in Self-Doped β-Conformation Film of Steric Polydiarylfluorenes toward Stable Dual Deep-Blue Amplified Spontaneous Emission

AU - Xu, Man

AU - Sun, Lili

AU - Wang, Shengjie

AU - Lin, Jinyi

AU - Yu, Mengna

AU - Wang, Xuhua

AU - Stavrinou, Paul N.

AU - Xie, Linghai

AU - Cheetham, Nathan J.

AU - Ding, Xuehua

AU - Bradley, Donal

AU - Huang, Wei

N1 - KAUST Repository Item: Exported on 2021-10-26 Acknowledgements: M.X. and L.S. contributed equally to this work. The work was supported by the National Natural Science Foundation of China (22075136, 61874053), National Key Research and Development Program of China (2020YFA0709900), Natural Science Funds of the Education Committee of Jiangsu Province (18KJA430009), Natural Science Foundation of Jiangsu Province (BK20200700), “High-Level Talents in Six Industries” of Jiangsu Province (XYDXX-019), Research Innovation in University of Jiangsu Province (KYCX21_0771), the open research fund from State Key Laboratory of Supramolecular Structure, Materials (sklssm202108) and Anhui Province Key Laboratory of Environment-friendly Polymer Materials and and Anhui Province Key Laboratory of Optoelectronic Materials Science and Technology. N.C. received support from an EPSRC Doctoral Training Studentship at the Centre for Plastic Electronics at Imperial College London.

PY - 2021/10/18

Y1 - 2021/10/18

N2 - Exciton behavior is crucial for improving the optoelectronic property of a light-emitting conjugated polymer. Herein, the photoexcitation dynamics of exciton migration and energy transfer in a self-doped β-conformation film of the polydiarylfluorenes (poly[4-(octyloxy)-9,9-diphenylfluoren-2,7-diyl]-co-[5-(octyloxy)-9,9- diphenylfluoren-2,7-diyl], PODPF) are demonstrated. Compared to the first generation of the β-conformation polyfluorene, poly(9,9-dioctylfluorene) (PFO), energy transfer occurs in PODPF β-conformation films in a time period of ≈150 ps, much longer than those of the PFO ones (

AB - Exciton behavior is crucial for improving the optoelectronic property of a light-emitting conjugated polymer. Herein, the photoexcitation dynamics of exciton migration and energy transfer in a self-doped β-conformation film of the polydiarylfluorenes (poly[4-(octyloxy)-9,9-diphenylfluoren-2,7-diyl]-co-[5-(octyloxy)-9,9- diphenylfluoren-2,7-diyl], PODPF) are demonstrated. Compared to the first generation of the β-conformation polyfluorene, poly(9,9-dioctylfluorene) (PFO), energy transfer occurs in PODPF β-conformation films in a time period of ≈150 ps, much longer than those of the PFO ones (

UR - http://hdl.handle.net/10754/672948

UR - https://onlinelibrary.wiley.com/doi/10.1002/adom.202100723

UR - http://www.scopus.com/inward/record.url?scp=85117143100&partnerID=8YFLogxK

U2 - 10.1002/adom.202100723

DO - 10.1002/adom.202100723

M3 - Article

SN - 2195-1071

SP - 2100723

JO - Advanced Optical Materials

JF - Advanced Optical Materials

ER -

Slow Energy Transfer in Self-Doped β-Conformation Film of Steric Polydiarylfluorenes toward Stable Dual Deep-Blue Amplified Spontaneous Emission

Abstract

Bibliographical note

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this