Size- and shape-dependent catalytic performances of oxidation and reduction reactions on nanocatalysts

Shaowen Cao; Franklin (Feng) Tao; Yu Tang; Yuting Li; Jiaguo Yu

doi:10.1039/c6cs00094k

Size- and shape-dependent catalytic performances of oxidation and reduction reactions on nanocatalysts

Shaowen Cao, Franklin (Feng) Tao, Yu Tang, Yuting Li, Jiaguo Yu

Research output: Contribution to journal › Article › peer-review

592 Scopus citations

Abstract

Heterogeneous catalysis is one of the most important chemical processes of various industries performed on catalyst nanoparticles with different sizes or/and shapes. In the past two decades, the catalytic performances of different catalytic reactions on nanoparticles of metals and oxides with well controlled sizes or shapes have been extensively studied thanks to the spectacular advances in syntheses of nanomaterials of metals and oxides. This review discussed the size and shape effects of catalyst particles on catalytic activity and selectivity of reactions performed at solid–gas or solid–liquid interfaces with a purpose of establishing correlations of size- and shape-dependent chemical and structural factors of surface of a catalyst with the corresponding catalytic performances toward understanding of catalysis at a molecular level.

Original language	English (US)
Pages (from-to)	4747-4765
Number of pages	19
Journal	Chemical Society Reviews
Volume	45
Issue number	17
DOIs	https://doi.org/10.1039/c6cs00094k
State	Published - Jun 8 2016
Externally published	Yes

Bibliographical note

KAUST Repository Item: Exported on 2022-05-26
Acknowledged KAUST grant number(s): OCRF-2014-CRG3-62140393
Acknowledgements: This work was supported by the NSF Career Award NSF-CHE-1462121, Chemical Sciences, Geosciences and Biosciences Division, Office of Basic Energy Sciences, Office of Science, U.S. Department of Energy under Grant No. DE-SC0014561 and National Science Foundation under the grants NSF-CBET-1264798 and NSF-OIA-1539105, and the King Abdullah University of Science and Technology (KAUST) Office of Sponsored Research (OSR) under Award No: OCRF-2014-CRG3-62140393. FT appreciates Bala Subramanian for the valuable discussion of the manuscript when FT was using the concept of density of under-coordinated metal atoms to interpret size- and shape-dependent catalytic performances during FT's preparation of the manuscript.
This publication acknowledges KAUST support, but has no KAUST affiliated authors.

ASJC Scopus subject areas

General Chemistry

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title = "Size- and shape-dependent catalytic performances of oxidation and reduction reactions on nanocatalysts",

abstract = "Heterogeneous catalysis is one of the most important chemical processes of various industries performed on catalyst nanoparticles with different sizes or/and shapes. In the past two decades, the catalytic performances of different catalytic reactions on nanoparticles of metals and oxides with well controlled sizes or shapes have been extensively studied thanks to the spectacular advances in syntheses of nanomaterials of metals and oxides. This review discussed the size and shape effects of catalyst particles on catalytic activity and selectivity of reactions performed at solid–gas or solid–liquid interfaces with a purpose of establishing correlations of size- and shape-dependent chemical and structural factors of surface of a catalyst with the corresponding catalytic performances toward understanding of catalysis at a molecular level.",

author = "Shaowen Cao and Tao, {Franklin (Feng)} and Yu Tang and Yuting Li and Jiaguo Yu",

note = "KAUST Repository Item: Exported on 2022-05-26 Acknowledged KAUST grant number(s): OCRF-2014-CRG3-62140393 Acknowledgements: This work was supported by the NSF Career Award NSF-CHE-1462121, Chemical Sciences, Geosciences and Biosciences Division, Office of Basic Energy Sciences, Office of Science, U.S. Department of Energy under Grant No. DE-SC0014561 and National Science Foundation under the grants NSF-CBET-1264798 and NSF-OIA-1539105, and the King Abdullah University of Science and Technology (KAUST) Office of Sponsored Research (OSR) under Award No: OCRF-2014-CRG3-62140393. FT appreciates Bala Subramanian for the valuable discussion of the manuscript when FT was using the concept of density of under-coordinated metal atoms to interpret size- and shape-dependent catalytic performances during FT's preparation of the manuscript. This publication acknowledges KAUST support, but has no KAUST affiliated authors.",

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language = "English (US)",

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AU - Cao, Shaowen

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AU - Tang, Yu

AU - Li, Yuting

AU - Yu, Jiaguo

N1 - KAUST Repository Item: Exported on 2022-05-26 Acknowledged KAUST grant number(s): OCRF-2014-CRG3-62140393 Acknowledgements: This work was supported by the NSF Career Award NSF-CHE-1462121, Chemical Sciences, Geosciences and Biosciences Division, Office of Basic Energy Sciences, Office of Science, U.S. Department of Energy under Grant No. DE-SC0014561 and National Science Foundation under the grants NSF-CBET-1264798 and NSF-OIA-1539105, and the King Abdullah University of Science and Technology (KAUST) Office of Sponsored Research (OSR) under Award No: OCRF-2014-CRG3-62140393. FT appreciates Bala Subramanian for the valuable discussion of the manuscript when FT was using the concept of density of under-coordinated metal atoms to interpret size- and shape-dependent catalytic performances during FT's preparation of the manuscript. This publication acknowledges KAUST support, but has no KAUST affiliated authors.

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AB - Heterogeneous catalysis is one of the most important chemical processes of various industries performed on catalyst nanoparticles with different sizes or/and shapes. In the past two decades, the catalytic performances of different catalytic reactions on nanoparticles of metals and oxides with well controlled sizes or shapes have been extensively studied thanks to the spectacular advances in syntheses of nanomaterials of metals and oxides. This review discussed the size and shape effects of catalyst particles on catalytic activity and selectivity of reactions performed at solid–gas or solid–liquid interfaces with a purpose of establishing correlations of size- and shape-dependent chemical and structural factors of surface of a catalyst with the corresponding catalytic performances toward understanding of catalysis at a molecular level.

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Size- and shape-dependent catalytic performances of oxidation and reduction reactions on nanocatalysts

Abstract

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