Site-Selective Doping Strategy of Carbon Anodes with Remarkable K-Ion Storage Capacity.

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The limited potassium-ion intercalation capacity of graphite hampers the development of potassium-ion batteries (PIB). Edge-nitrogen doping (pyrrolic and pyridinic) has been demonstrated as an effective approach to enhance K-ion storage in carbonaceous materials. One primary shortcoming of current methods is the lack of precise control over producing edge-nitrogen configuration. In this work, we present a molecular-scale copolymer pyrolysis strategy for precisely controlling edge-nitrogen doping in carbonaceous materials. Our optimized process results in defect-rich, edge-nitrogen doped carbons (ENDC) with a high nitrogen doping level up to 10.5 at. % and high edge-nitrogen ratio of 87.6%. The optimized ENDC exhibits a high reversible capacity of 423 mAh g-1, a high initial Cloulombic efficiency of 65%, superior rate capability, and long cycle life (93.8% retention after three months). This edge-nitrogen control strategy can be extended to design other edge-heteroatom rich carbons through pyrolysis of copolymers for efficient storage of various mobile ions.
Original languageEnglish (US)
JournalAngewandte Chemie (International ed. in English)
StatePublished - Jan 29 2020

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledged KAUST grant number(s): URF/1/2980-01-01
Acknowledgements: The research reported in this publication is supported by King Abdullah University of Science and Technology (KAUST) (URF/1/2980-01-01). The computational work was performed on KAUST supercomputers. The authors thank the Core Laboratories at KAUST for their excellent support.


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