[(≡SiO)TaV (=CH2)Cl2], the first tantalum methylidene species prepared and identified on the silica surface

Yin Chen; Emmanuel Callens; Edy Abou-Hamad; Jean-Marie Basset

doi:10.1016/j.jorganchem.2013.04.050

[(≡SiO)TaV (=CH2)Cl2], the first tantalum methylidene species prepared and identified on the silica surface

Yin Chen, Emmanuel Callens, Edy Abou-Hamad, Jean-Marie Basset

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

A novel surface tantalum methylidene [(≡SiO)TaV (=CH 2)Cl2] was obtained via thermal decomposition of the well-defined surface species [(≡SiO)TaVCl2Me 2]. This first surface tantalum methylidene ever synthesized has been fully characterized and the kinetics of the a-hydrogen abstraction reaction has also been investigated in the heterogeneous system. © 2013 Elsevier B.V. All rights reserved.

Original language	English (US)
Pages (from-to)	3-6
Number of pages	4
Journal	Journal of Organometallic Chemistry
Volume	744
DOIs	https://doi.org/10.1016/j.jorganchem.2013.04.050
State	Published - Nov 2013

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: We thanks KAUST for the financial support and YC gratefully acknowledges generous donation from SABIC.

ASJC Scopus subject areas

Materials Chemistry
Biochemistry
Organic Chemistry
Physical and Theoretical Chemistry
Inorganic Chemistry

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10.1016/j.jorganchem.2013.04.050

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title = "[(≡SiO)TaV (=CH2)Cl2], the first tantalum methylidene species prepared and identified on the silica surface",

abstract = "A novel surface tantalum methylidene [(≡SiO)TaV (=CH 2)Cl2] was obtained via thermal decomposition of the well-defined surface species [(≡SiO)TaVCl2Me 2]. This first surface tantalum methylidene ever synthesized has been fully characterized and the kinetics of the a-hydrogen abstraction reaction has also been investigated in the heterogeneous system. {\textcopyright} 2013 Elsevier B.V. All rights reserved.",

author = "Yin Chen and Emmanuel Callens and Edy Abou-Hamad and Jean-Marie Basset",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: We thanks KAUST for the financial support and YC gratefully acknowledges generous donation from SABIC.",

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doi = "10.1016/j.jorganchem.2013.04.050",

language = "English (US)",

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journal = "Journal of Organometallic Chemistry",

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T1 - [(≡SiO)TaV (=CH2)Cl2], the first tantalum methylidene species prepared and identified on the silica surface

AU - Chen, Yin

AU - Callens, Emmanuel

AU - Abou-Hamad, Edy

AU - Basset, Jean-Marie

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: We thanks KAUST for the financial support and YC gratefully acknowledges generous donation from SABIC.

PY - 2013/11

Y1 - 2013/11

N2 - A novel surface tantalum methylidene [(≡SiO)TaV (=CH 2)Cl2] was obtained via thermal decomposition of the well-defined surface species [(≡SiO)TaVCl2Me 2]. This first surface tantalum methylidene ever synthesized has been fully characterized and the kinetics of the a-hydrogen abstraction reaction has also been investigated in the heterogeneous system. © 2013 Elsevier B.V. All rights reserved.

AB - A novel surface tantalum methylidene [(≡SiO)TaV (=CH 2)Cl2] was obtained via thermal decomposition of the well-defined surface species [(≡SiO)TaVCl2Me 2]. This first surface tantalum methylidene ever synthesized has been fully characterized and the kinetics of the a-hydrogen abstraction reaction has also been investigated in the heterogeneous system. © 2013 Elsevier B.V. All rights reserved.

UR - http://hdl.handle.net/10754/563064

UR - https://linkinghub.elsevier.com/retrieve/pii/S0022328X13003562

UR - http://www.scopus.com/inward/record.url?scp=84884535334&partnerID=8YFLogxK

U2 - 10.1016/j.jorganchem.2013.04.050

DO - 10.1016/j.jorganchem.2013.04.050

M3 - Article

SN - 0022-328X

VL - 744

SP - 3

EP - 6

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

ER -

[(≡SiO)TaV (=CH2)Cl2], the first tantalum methylidene species prepared and identified on the silica surface

Abstract

Bibliographical note

ASJC Scopus subject areas

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