Simple synthetic access to [Au(IBiox)Cl] complexes

Ekaterina A. Martynova; Marco Zuccarello; Domenic Kronenberg; Marek Beliš; Agnieszka Czapik; Ziyun Zhang; Kristof Van Hecke; Marcin Kwit; Olivier Baudoin; Luigi Cavallo; Steven P. Nolan

doi:10.1039/d3dt01357j

Simple synthetic access to [Au(IBiox)Cl] complexes

Ekaterina A. Martynova, Marco Zuccarello, Domenic Kronenberg, Marek Beliš, Agnieszka Czapik, Ziyun Zhang, Kristof Van Hecke, Marcin Kwit, Olivier Baudoin^*, Luigi Cavallo^*, Steven P. Nolan^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

Green and sustainable access to chiral and achiral gold-IBiox complexes is reported. The gold complexes were synthesized using a simple, air-tolerant, weak base protocol carried out in a green solvent. Their catalytic activity was examined in the hydroamination of alkynes. The steric protection afforded the gold center by these ligands was quantified using the %V_bur model and compared with the most commonly encountered NHCs.

Original language	English (US)
Pages (from-to)	7558-7563
Number of pages	6
Journal	Dalton transactions
Volume	52
Issue number	22
DOIs	https://doi.org/10.1039/d3dt01357j
State	Published - May 10 2023

Bibliographical note

Publisher Copyright:
© 2023 The Royal Society of Chemistry.

ASJC Scopus subject areas

Inorganic Chemistry

Access to Document

10.1039/d3dt01357j

Cite this

@article{999050c5a1ef4acc8af8124cd98e6128,

title = "Simple synthetic access to [Au(IBiox)Cl] complexes",

abstract = "Green and sustainable access to chiral and achiral gold-IBiox complexes is reported. The gold complexes were synthesized using a simple, air-tolerant, weak base protocol carried out in a green solvent. Their catalytic activity was examined in the hydroamination of alkynes. The steric protection afforded the gold center by these ligands was quantified using the %Vbur model and compared with the most commonly encountered NHCs.",

author = "Martynova, {Ekaterina A.} and Marco Zuccarello and Domenic Kronenberg and Marek Beli{\v s} and Agnieszka Czapik and Ziyun Zhang and {Van Hecke}, Kristof and Marcin Kwit and Olivier Baudoin and Luigi Cavallo and Nolan, {Steven P.}",

note = "Publisher Copyright: {\textcopyright} 2023 The Royal Society of Chemistry.",

year = "2023",

month = may,

day = "10",

doi = "10.1039/d3dt01357j",

language = "English (US)",

volume = "52",

pages = "7558--7563",

journal = "Dalton transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "22",

}

TY - JOUR

T1 - Simple synthetic access to [Au(IBiox)Cl] complexes

AU - Martynova, Ekaterina A.

AU - Zuccarello, Marco

AU - Kronenberg, Domenic

AU - Beliš, Marek

AU - Czapik, Agnieszka

AU - Zhang, Ziyun

AU - Van Hecke, Kristof

AU - Kwit, Marcin

AU - Baudoin, Olivier

AU - Cavallo, Luigi

AU - Nolan, Steven P.

PY - 2023/5/10

Y1 - 2023/5/10

N2 - Green and sustainable access to chiral and achiral gold-IBiox complexes is reported. The gold complexes were synthesized using a simple, air-tolerant, weak base protocol carried out in a green solvent. Their catalytic activity was examined in the hydroamination of alkynes. The steric protection afforded the gold center by these ligands was quantified using the %Vbur model and compared with the most commonly encountered NHCs.

AB - Green and sustainable access to chiral and achiral gold-IBiox complexes is reported. The gold complexes were synthesized using a simple, air-tolerant, weak base protocol carried out in a green solvent. Their catalytic activity was examined in the hydroamination of alkynes. The steric protection afforded the gold center by these ligands was quantified using the %Vbur model and compared with the most commonly encountered NHCs.

UR - http://www.scopus.com/inward/record.url?scp=85159689096&partnerID=8YFLogxK

U2 - 10.1039/d3dt01357j

DO - 10.1039/d3dt01357j

M3 - Article

C2 - 37191083

AN - SCOPUS:85159689096

SN - 1477-9226

VL - 52

SP - 7558

EP - 7563

JO - Dalton transactions

JF - Dalton transactions

IS - 22

ER -

Simple synthetic access to [Au(IBiox)Cl] complexes

Abstract

Bibliographical note

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this