Simple ligand modifications as a key to playing with the stability of Cu(I), Cu(II), and Cu(III) organometallic complexes

Albert Poater; Luigi Cavallo

doi:10.1021/ic8020063

Simple ligand modifications as a key to playing with the stability of Cu(I), Cu(II), and Cu(III) organometallic complexes

Albert Poater, Luigi Cavallo^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

Elusive Cu(III) organometallic complexes are extremely attractive intermediates in catalysis. Using a computational approach, we show that C-X activation by some Cu(I) complexes to yield Cu(III) intermediates is actually feasible, although ligands of appropriate structure must be used.

Original language	English (US)
Pages (from-to)	2340-2342
Number of pages	3
Journal	Inorganic chemistry
Volume	48
Issue number	6
DOIs	https://doi.org/10.1021/ic8020063
State	Published - Mar 16 2009
Externally published	Yes

ASJC Scopus subject areas

Inorganic Chemistry
Physical and Theoretical Chemistry

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title = "Simple ligand modifications as a key to playing with the stability of Cu(I), Cu(II), and Cu(III) organometallic complexes",

abstract = "Elusive Cu(III) organometallic complexes are extremely attractive intermediates in catalysis. Using a computational approach, we show that C-X activation by some Cu(I) complexes to yield Cu(III) intermediates is actually feasible, although ligands of appropriate structure must be used.",

author = "Albert Poater and Luigi Cavallo",

year = "2009",

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T1 - Simple ligand modifications as a key to playing with the stability of Cu(I), Cu(II), and Cu(III) organometallic complexes

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AU - Cavallo, Luigi

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Y1 - 2009/3/16

N2 - Elusive Cu(III) organometallic complexes are extremely attractive intermediates in catalysis. Using a computational approach, we show that C-X activation by some Cu(I) complexes to yield Cu(III) intermediates is actually feasible, although ligands of appropriate structure must be used.

AB - Elusive Cu(III) organometallic complexes are extremely attractive intermediates in catalysis. Using a computational approach, we show that C-X activation by some Cu(I) complexes to yield Cu(III) intermediates is actually feasible, although ligands of appropriate structure must be used.

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U2 - 10.1021/ic8020063

DO - 10.1021/ic8020063

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JO - Inorganic chemistry

JF - Inorganic chemistry

IS - 6

ER -

Simple ligand modifications as a key to playing with the stability of Cu(I), Cu(II), and Cu(III) organometallic complexes

Abstract

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