Shifting from Ziegler-Natta to Philips-type catalyst? A simple and safe access to reduced titanium systems for ethylene polymerization

Nicolas Popoff; Jeff Espinas; Eric Gouré; Olivier Boyron; Erwan Le Roux; Jean-Marie Basset; Régis M. Gauvin; Aimery De Mallmann; Mostafa Taoufik

doi:10.1002/marc.201100477

Shifting from Ziegler-Natta to Philips-type catalyst? A simple and safe access to reduced titanium systems for ethylene polymerization

Nicolas Popoff, Jeff Espinas, Eric Gouré, Olivier Boyron, Erwan Le Roux, Jean-Marie Basset, Régis M. Gauvin, Aimery De Mallmann, Mostafa Taoufik

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

Silica-supported titanium(IV) chloride is readily reduced by Mashima and co-workers' reagent (1-methyl-3,6-bis(trimethylsilyl)-1,4-cyclohexadiene) to afford materials active in ethylene polymerisation without need of aluminum alkyl cocatalyst. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Original language	English (US)
Pages (from-to)	1921-1924
Number of pages	4
Journal	Macromolecular Rapid Communications
Volume	32
Issue number	23
DOIs	https://doi.org/10.1002/marc.201100477
State	Published - Sep 22 2011

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01

ASJC Scopus subject areas

Materials Chemistry
Organic Chemistry
Polymers and Plastics

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10.1002/marc.201100477

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title = "Shifting from Ziegler-Natta to Philips-type catalyst? A simple and safe access to reduced titanium systems for ethylene polymerization",

abstract = "Silica-supported titanium(IV) chloride is readily reduced by Mashima and co-workers' reagent (1-methyl-3,6-bis(trimethylsilyl)-1,4-cyclohexadiene) to afford materials active in ethylene polymerisation without need of aluminum alkyl cocatalyst. {\textcopyright} 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.",

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T1 - Shifting from Ziegler-Natta to Philips-type catalyst? A simple and safe access to reduced titanium systems for ethylene polymerization

AU - Popoff, Nicolas

AU - Espinas, Jeff

AU - Gouré, Eric

AU - Boyron, Olivier

AU - Le Roux, Erwan

AU - Basset, Jean-Marie

AU - Gauvin, Régis M.

AU - De Mallmann, Aimery

AU - Taoufik, Mostafa

N1 - KAUST Repository Item: Exported on 2020-10-01

PY - 2011/9/22

Y1 - 2011/9/22

N2 - Silica-supported titanium(IV) chloride is readily reduced by Mashima and co-workers' reagent (1-methyl-3,6-bis(trimethylsilyl)-1,4-cyclohexadiene) to afford materials active in ethylene polymerisation without need of aluminum alkyl cocatalyst. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

AB - Silica-supported titanium(IV) chloride is readily reduced by Mashima and co-workers' reagent (1-methyl-3,6-bis(trimethylsilyl)-1,4-cyclohexadiene) to afford materials active in ethylene polymerisation without need of aluminum alkyl cocatalyst. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

UR - http://hdl.handle.net/10754/566032

UR - http://doi.wiley.com/10.1002/marc.201100477

UR - http://www.scopus.com/inward/record.url?scp=82455175746&partnerID=8YFLogxK

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DO - 10.1002/marc.201100477

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C2 - 21948353

SN - 1022-1336

VL - 32

SP - 1921

EP - 1924

JO - Macromolecular Rapid Communications

JF - Macromolecular Rapid Communications

IS - 23

ER -

Shifting from Ziegler-Natta to Philips-type catalyst? A simple and safe access to reduced titanium systems for ethylene polymerization

Abstract

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