Shape- and morphology-controlled sustainable synthesis of Cu, Co, and in metal organic frameworks with high CO2 capture capacity

Pradip Sarawade; Hua Tan; Vivek Polshettiwar

doi:10.1021/sc300036p

Shape- and morphology-controlled sustainable synthesis of Cu, Co, and in metal organic frameworks with high CO2 capture capacity

Pradip Sarawade, Hua Tan, Vivek Polshettiwar

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67 Scopus citations

Abstract

We studied the effects of various surfactants on the shape and morphology of three metal organic frameworks (MOFs), i.e., Co-MOF, Cu-MOF, and In-MOF, which were synthesized under microwave irradiation. The as-synthesized materials were characterized by X-ray powder diffraction (XRD), scanning electron microscopy (SEM), thermogravimetric analysis (TGA), and nitrogen sorption. The effects of microwave irradiation time, temperature, and surfactant template were investigated. The synthetic parameters, including the type of surfactant template and the reaction temperature, played crucial roles in the size, shape, and morphology of the MOF microcrystals. We also evaluated these MOFs as sorbents for capturing CO2. Of the synthesized materials, Cu-MOF demonstrated the highest CO2 capture capacity, even at atmospheric pressure and ambient temperature. © 2012 American Chemical Society.

Original language	English (US)
Pages (from-to)	66-74
Number of pages	9
Journal	ACS Sustainable Chemistry & Engineering
Volume	1
Issue number	1
DOIs	https://doi.org/10.1021/sc300036p
State	Published - Nov 6 2012

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: We thank King Abdullah University of Science and Technology (KAUST) for their funding and support. We also thank Prof. Mohamed Eddaoudi for his lecture on MOFs, which inspired us to engage in this work.

ASJC Scopus subject areas

Renewable Energy, Sustainability and the Environment
Environmental Chemistry
General Chemical Engineering
General Chemistry

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1021/sc300036p

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title = "Shape- and morphology-controlled sustainable synthesis of Cu, Co, and in metal organic frameworks with high CO2 capture capacity",

abstract = "We studied the effects of various surfactants on the shape and morphology of three metal organic frameworks (MOFs), i.e., Co-MOF, Cu-MOF, and In-MOF, which were synthesized under microwave irradiation. The as-synthesized materials were characterized by X-ray powder diffraction (XRD), scanning electron microscopy (SEM), thermogravimetric analysis (TGA), and nitrogen sorption. The effects of microwave irradiation time, temperature, and surfactant template were investigated. The synthetic parameters, including the type of surfactant template and the reaction temperature, played crucial roles in the size, shape, and morphology of the MOF microcrystals. We also evaluated these MOFs as sorbents for capturing CO2. Of the synthesized materials, Cu-MOF demonstrated the highest CO2 capture capacity, even at atmospheric pressure and ambient temperature. {\textcopyright} 2012 American Chemical Society.",

author = "Pradip Sarawade and Hua Tan and Vivek Polshettiwar",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: We thank King Abdullah University of Science and Technology (KAUST) for their funding and support. We also thank Prof. Mohamed Eddaoudi for his lecture on MOFs, which inspired us to engage in this work.",

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AU - Sarawade, Pradip

AU - Tan, Hua

AU - Polshettiwar, Vivek

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: We thank King Abdullah University of Science and Technology (KAUST) for their funding and support. We also thank Prof. Mohamed Eddaoudi for his lecture on MOFs, which inspired us to engage in this work.

PY - 2012/11/6

Y1 - 2012/11/6

N2 - We studied the effects of various surfactants on the shape and morphology of three metal organic frameworks (MOFs), i.e., Co-MOF, Cu-MOF, and In-MOF, which were synthesized under microwave irradiation. The as-synthesized materials were characterized by X-ray powder diffraction (XRD), scanning electron microscopy (SEM), thermogravimetric analysis (TGA), and nitrogen sorption. The effects of microwave irradiation time, temperature, and surfactant template were investigated. The synthetic parameters, including the type of surfactant template and the reaction temperature, played crucial roles in the size, shape, and morphology of the MOF microcrystals. We also evaluated these MOFs as sorbents for capturing CO2. Of the synthesized materials, Cu-MOF demonstrated the highest CO2 capture capacity, even at atmospheric pressure and ambient temperature. © 2012 American Chemical Society.

AB - We studied the effects of various surfactants on the shape and morphology of three metal organic frameworks (MOFs), i.e., Co-MOF, Cu-MOF, and In-MOF, which were synthesized under microwave irradiation. The as-synthesized materials were characterized by X-ray powder diffraction (XRD), scanning electron microscopy (SEM), thermogravimetric analysis (TGA), and nitrogen sorption. The effects of microwave irradiation time, temperature, and surfactant template were investigated. The synthetic parameters, including the type of surfactant template and the reaction temperature, played crucial roles in the size, shape, and morphology of the MOF microcrystals. We also evaluated these MOFs as sorbents for capturing CO2. Of the synthesized materials, Cu-MOF demonstrated the highest CO2 capture capacity, even at atmospheric pressure and ambient temperature. © 2012 American Chemical Society.

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JO - ACS Sustainable Chemistry & Engineering

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IS - 1

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Shape- and morphology-controlled sustainable synthesis of Cu, Co, and in metal organic frameworks with high CO2 capture capacity

Abstract

Bibliographical note

ASJC Scopus subject areas

UN SDGs

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