TY - JOUR
T1 - Selective Hydrogen Generation from Formic Acid with Well-Defined Complexes of Ruthenium and Phosphorus-Nitrogen PN3-Pincer Ligand
AU - Pan, Yupeng
AU - Pan, Chengling
AU - Zhang, Yufan
AU - Li, Huaifeng
AU - Min, Shixiong
AU - Guo, Xunmun
AU - Zheng, Bin
AU - Chen, Hailong
AU - Anders, Addison
AU - Lai, Zhiping
AU - Zheng, Junrong
AU - Huang, Kuo-Wei
N1 - KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: K.-W.H. acknowledges the financial support from KAUST and a SABIC Chair Professorship. J.Z. thanks the supports from NSF (CHE-1503865), the Welch foundation under Award No. C-1752, Packard fellowship, and Sloan fellowship. Y.Z. thanks a Schlumberger future faculty award.
PY - 2016/4/21
Y1 - 2016/4/21
N2 - An unsymmetrically protonated PN3-pincer complex in which ruthenium is coordinated by one nitrogen and two phosphorus atoms was employed for the selective generation of hydrogen from formic acid. Mechanistic studies suggest that the imine arm participates in the formic acid activation/deprotonation step. A long life time of 150 h with a turnover number over 1 million was achieved. Grabbing hold: A PN3-pincer complex was employed for the selective hydrogen generation from formic acid. Mechanistic studies suggest the imine arm participates in the formic acid activation/deprotonation step. A long life time of 150 h with a turnover number over 1 million was achieved. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
AB - An unsymmetrically protonated PN3-pincer complex in which ruthenium is coordinated by one nitrogen and two phosphorus atoms was employed for the selective generation of hydrogen from formic acid. Mechanistic studies suggest that the imine arm participates in the formic acid activation/deprotonation step. A long life time of 150 h with a turnover number over 1 million was achieved. Grabbing hold: A PN3-pincer complex was employed for the selective hydrogen generation from formic acid. Mechanistic studies suggest the imine arm participates in the formic acid activation/deprotonation step. A long life time of 150 h with a turnover number over 1 million was achieved. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
UR - http://hdl.handle.net/10754/621577
UR - http://doi.wiley.com/10.1002/asia.201600169
UR - http://www.scopus.com/inward/record.url?scp=84966377299&partnerID=8YFLogxK
U2 - 10.1002/asia.201600169
DO - 10.1002/asia.201600169
M3 - Article
C2 - 27101381
SN - 1861-4728
VL - 11
SP - 1357
EP - 1360
JO - Chemistry - An Asian Journal
JF - Chemistry - An Asian Journal
IS - 9
ER -