Selective adsorption of volatile hydrocarbons and gases in high surface area chalcogels containing [ES3]3- anions (E = As, Sb)

Ejaz Ahmed; Jayaprakash Khanderi; Dalaver H. Anjum; Alexander Rothenberger

doi:10.1021/cm502942w

Selective adsorption of volatile hydrocarbons and gases in high surface area chalcogels containing [ES3]3- anions (E = As, Sb)

Ejaz Ahmed, Jayaprakash Khanderi, Dalaver H. Anjum, Alexander Rothenberger

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

We describe the sol-gel synthesis of the two new chalcogels KFeSbS3 and NaFeAsS3, which demonstrate excellent adsorption selectivity for volatile hydrocarbons and gases. These predominantly mesoporous materials have been synthesized by reacting Fe(OAc)2 with K3SbS3 or Na3AsS3 in a formamide/water mixture at room temperature. Aerogels obtained after supercritical drying have BET surface areas of 636 m2/g and 505 m2/g for KFeSbS3 and NaFeAsS3, respectively, with pore sizes in the micro- (below 2 nm), meso- (2-50 nm), and macro- (above 50 nm) regions.

Original language	English (US)
Pages (from-to)	6454-6460
Number of pages	7
Journal	Chemistry of Materials
Volume	26
Issue number	22
DOIs	https://doi.org/10.1021/cm502942w
State	Published - Nov 7 2014

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: Electron microscope imaging work (TEM, SEM) was performed in the Advanced Nanofabrication, Imaging and Characterization Core Lab at KAUST. This research was supported by King Abdullah University of Science and Technology (KAUST) baseline funding.

ASJC Scopus subject areas

Materials Chemistry
General Chemical Engineering
General Chemistry

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10.1021/cm502942w

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title = "Selective adsorption of volatile hydrocarbons and gases in high surface area chalcogels containing [ES3]3- anions (E = As, Sb)",

abstract = "We describe the sol-gel synthesis of the two new chalcogels KFeSbS3 and NaFeAsS3, which demonstrate excellent adsorption selectivity for volatile hydrocarbons and gases. These predominantly mesoporous materials have been synthesized by reacting Fe(OAc)2 with K3SbS3 or Na3AsS3 in a formamide/water mixture at room temperature. Aerogels obtained after supercritical drying have BET surface areas of 636 m2/g and 505 m2/g for KFeSbS3 and NaFeAsS3, respectively, with pore sizes in the micro- (below 2 nm), meso- (2-50 nm), and macro- (above 50 nm) regions.",

author = "Ejaz Ahmed and Jayaprakash Khanderi and Anjum, {Dalaver H.} and Alexander Rothenberger",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: Electron microscope imaging work (TEM, SEM) was performed in the Advanced Nanofabrication, Imaging and Characterization Core Lab at KAUST. This research was supported by King Abdullah University of Science and Technology (KAUST) baseline funding.",

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AU - Ahmed, Ejaz

AU - Khanderi, Jayaprakash

AU - Anjum, Dalaver H.

AU - Rothenberger, Alexander

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: Electron microscope imaging work (TEM, SEM) was performed in the Advanced Nanofabrication, Imaging and Characterization Core Lab at KAUST. This research was supported by King Abdullah University of Science and Technology (KAUST) baseline funding.

PY - 2014/11/7

Y1 - 2014/11/7

N2 - We describe the sol-gel synthesis of the two new chalcogels KFeSbS3 and NaFeAsS3, which demonstrate excellent adsorption selectivity for volatile hydrocarbons and gases. These predominantly mesoporous materials have been synthesized by reacting Fe(OAc)2 with K3SbS3 or Na3AsS3 in a formamide/water mixture at room temperature. Aerogels obtained after supercritical drying have BET surface areas of 636 m2/g and 505 m2/g for KFeSbS3 and NaFeAsS3, respectively, with pore sizes in the micro- (below 2 nm), meso- (2-50 nm), and macro- (above 50 nm) regions.

AB - We describe the sol-gel synthesis of the two new chalcogels KFeSbS3 and NaFeAsS3, which demonstrate excellent adsorption selectivity for volatile hydrocarbons and gases. These predominantly mesoporous materials have been synthesized by reacting Fe(OAc)2 with K3SbS3 or Na3AsS3 in a formamide/water mixture at room temperature. Aerogels obtained after supercritical drying have BET surface areas of 636 m2/g and 505 m2/g for KFeSbS3 and NaFeAsS3, respectively, with pore sizes in the micro- (below 2 nm), meso- (2-50 nm), and macro- (above 50 nm) regions.

UR - http://hdl.handle.net/10754/563871

UR - https://pubs.acs.org/doi/10.1021/cm502942w

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U2 - 10.1021/cm502942w

DO - 10.1021/cm502942w

M3 - Article

SN - 0897-4756

VL - 26

SP - 6454

EP - 6460

JO - Chemistry of Materials

JF - Chemistry of Materials

IS - 22

ER -

Selective adsorption of volatile hydrocarbons and gases in high surface area chalcogels containing [ES3]3- anions (E = As, Sb)

Abstract

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