Selective Acetylene Adsorption within an Imino-Functionalized Nanocage-Based Metal-Organic Framework.

Lingkun Meng; Lixia Yang; Cailing Chen; Xinglong Dong; Siyuan Ren; Guanghua Li; Yi Li; Yu Han; Zhan Shi; Shouhua Feng

doi:10.1021/acsami.9b21938

Selective Acetylene Adsorption within an Imino-Functionalized Nanocage-Based Metal-Organic Framework.

Lingkun Meng, Lixia Yang, Cailing Chen, Xinglong Dong, Siyuan Ren, Guanghua Li, Yi Li, Yu Han, Zhan Shi, Shouhua Feng

Research output: Contribution to journal › Article › peer-review

34 Scopus citations

Abstract

Removal of CH4 and CO2 from C2H2 streams remains challenging in the chemical industry. Herein, a robust three-dimensional metal-organic framework, Cu-CPAH, was designed and synthesized through a hydrothermal method. Cu-CPAH exhibits highly selective C2H2 adsorption capacity with respect to both CH4 and CO2, which is ascribed to the enrichment of active sites in the framework. Dynamic breakthrough results reveal that Cu-CPAH serves as a solid adsorbent for high-efficiency purification of C2H2 from an equal proportion of C2H2/CO2 or C2H2/CO2/CH4 at room temperature. Discrete Fourier transform simulations confirm that various active sites preferentially interact with C2H2 other than CO2 and CH4, signifying for the first time that the imino functional groups in the cage contribute greatly to the preferential affinity to C2H2 over CO2 and CH4.

Original language	English (US)
Pages (from-to)	5999-6006
Number of pages	8
Journal	ACS Applied Materials & Interfaces
Volume	12
Issue number	5
DOIs	https://doi.org/10.1021/acsami.9b21938
State	Published - Jan 27 2020

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: This work was supported by the Natural Science Foundation of China (21771077, 21771084, and 21621001), the National Key Research and Development Program of China (2016YFB0701100), and the 111 Project (B17020). The authors also gratefully acknowledge the financial support by the Program for the JLU Science and Technology Innovative Research Team (JLUSTIRT).

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@article{1e3804d6eca14a5fb9575f9e23b984fc,

title = "Selective Acetylene Adsorption within an Imino-Functionalized Nanocage-Based Metal-Organic Framework.",

abstract = "Removal of CH4 and CO2 from C2H2 streams remains challenging in the chemical industry. Herein, a robust three-dimensional metal-organic framework, Cu-CPAH, was designed and synthesized through a hydrothermal method. Cu-CPAH exhibits highly selective C2H2 adsorption capacity with respect to both CH4 and CO2, which is ascribed to the enrichment of active sites in the framework. Dynamic breakthrough results reveal that Cu-CPAH serves as a solid adsorbent for high-efficiency purification of C2H2 from an equal proportion of C2H2/CO2 or C2H2/CO2/CH4 at room temperature. Discrete Fourier transform simulations confirm that various active sites preferentially interact with C2H2 other than CO2 and CH4, signifying for the first time that the imino functional groups in the cage contribute greatly to the preferential affinity to C2H2 over CO2 and CH4.",

author = "Lingkun Meng and Lixia Yang and Cailing Chen and Xinglong Dong and Siyuan Ren and Guanghua Li and Yi Li and Yu Han and Zhan Shi and Shouhua Feng",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: This work was supported by the Natural Science Foundation of China (21771077, 21771084, and 21621001), the National Key Research and Development Program of China (2016YFB0701100), and the 111 Project (B17020). The authors also gratefully acknowledge the financial support by the Program for the JLU Science and Technology Innovative Research Team (JLUSTIRT).",

year = "2020",

month = jan,

day = "27",

doi = "10.1021/acsami.9b21938",

language = "English (US)",

volume = "12",

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journal = "ACS Applied Materials & Interfaces",

issn = "1944-8244",

publisher = "American Chemical Society",

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TY - JOUR

T1 - Selective Acetylene Adsorption within an Imino-Functionalized Nanocage-Based Metal-Organic Framework.

AU - Meng, Lingkun

AU - Yang, Lixia

AU - Chen, Cailing

AU - Dong, Xinglong

AU - Ren, Siyuan

AU - Li, Guanghua

AU - Li, Yi

AU - Han, Yu

AU - Shi, Zhan

AU - Feng, Shouhua

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: This work was supported by the Natural Science Foundation of China (21771077, 21771084, and 21621001), the National Key Research and Development Program of China (2016YFB0701100), and the 111 Project (B17020). The authors also gratefully acknowledge the financial support by the Program for the JLU Science and Technology Innovative Research Team (JLUSTIRT).

PY - 2020/1/27

Y1 - 2020/1/27

N2 - Removal of CH4 and CO2 from C2H2 streams remains challenging in the chemical industry. Herein, a robust three-dimensional metal-organic framework, Cu-CPAH, was designed and synthesized through a hydrothermal method. Cu-CPAH exhibits highly selective C2H2 adsorption capacity with respect to both CH4 and CO2, which is ascribed to the enrichment of active sites in the framework. Dynamic breakthrough results reveal that Cu-CPAH serves as a solid adsorbent for high-efficiency purification of C2H2 from an equal proportion of C2H2/CO2 or C2H2/CO2/CH4 at room temperature. Discrete Fourier transform simulations confirm that various active sites preferentially interact with C2H2 other than CO2 and CH4, signifying for the first time that the imino functional groups in the cage contribute greatly to the preferential affinity to C2H2 over CO2 and CH4.

AB - Removal of CH4 and CO2 from C2H2 streams remains challenging in the chemical industry. Herein, a robust three-dimensional metal-organic framework, Cu-CPAH, was designed and synthesized through a hydrothermal method. Cu-CPAH exhibits highly selective C2H2 adsorption capacity with respect to both CH4 and CO2, which is ascribed to the enrichment of active sites in the framework. Dynamic breakthrough results reveal that Cu-CPAH serves as a solid adsorbent for high-efficiency purification of C2H2 from an equal proportion of C2H2/CO2 or C2H2/CO2/CH4 at room temperature. Discrete Fourier transform simulations confirm that various active sites preferentially interact with C2H2 other than CO2 and CH4, signifying for the first time that the imino functional groups in the cage contribute greatly to the preferential affinity to C2H2 over CO2 and CH4.

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Selective Acetylene Adsorption within an Imino-Functionalized Nanocage-Based Metal-Organic Framework.

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