Reticular Chemistry for the Construction of Highly Porous Aluminum-Based nia-Metal–Organic Frameworks

Dalal Alezi; Jiangtao Jia; Prashant Bhatt; Aleksander Shkurenko; Vera Solovyeva; Zhijie Chen; Youssef Belmabkhout; Mohamed Eddaoudi

doi:10.1021/acs.inorgchem.2c00756

Reticular Chemistry for the Construction of Highly Porous Aluminum-Based nia-Metal–Organic Frameworks

Dalal Alezi, Jiangtao Jia, Prashant Bhatt, Aleksander Shkurenko, Vera Solovyeva, Zhijie Chen, Youssef Belmabkhout, Mohamed Eddaoudi

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

Edge-transitive nets are regarded as appropriate blueprints for the practice of reticular chemistry, and in particular, for the rational design and synthesis of functional metal–organic frameworks (MOFs). Among edge-transitive nets, type I edge-transitive nets have unique coordination figures, offering only one edge-transitive target for their associated expressed net-cBUs. Here, we report the reticulation of the binodal edge-transitive (6, 6)-c nia net in MOF chemistry, namely, the deliberate assembly of trinuclear aluminum clusters and 6-connected hexacarboxylate ligands into highly porous nia-MOFs. Further studies reveal that Al-nia-MOF-1 shows promising attributes as a storage media for oxygen (O2) at high-pressure adsorption studies.

Original language	English (US)
Journal	Inorganic Chemistry
DOIs	https://doi.org/10.1021/acs.inorgchem.2c00756
State	Published - Jun 30 2022

Bibliographical note

KAUST Repository Item: Exported on 2022-07-06
Acknowledgements: The research reported in this publication was supported by funding from the King Abdullah University of Science and Technology (KAUST).

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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10.1021/acs.inorgchem.2c00756

Cite this

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title = "Reticular Chemistry for the Construction of Highly Porous Aluminum-Based nia-Metal–Organic Frameworks",

abstract = "Edge-transitive nets are regarded as appropriate blueprints for the practice of reticular chemistry, and in particular, for the rational design and synthesis of functional metal–organic frameworks (MOFs). Among edge-transitive nets, type I edge-transitive nets have unique coordination figures, offering only one edge-transitive target for their associated expressed net-cBUs. Here, we report the reticulation of the binodal edge-transitive (6, 6)-c nia net in MOF chemistry, namely, the deliberate assembly of trinuclear aluminum clusters and 6-connected hexacarboxylate ligands into highly porous nia-MOFs. Further studies reveal that Al-nia-MOF-1 shows promising attributes as a storage media for oxygen (O2) at high-pressure adsorption studies.",

author = "Dalal Alezi and Jiangtao Jia and Prashant Bhatt and Aleksander Shkurenko and Vera Solovyeva and Zhijie Chen and Youssef Belmabkhout and Mohamed Eddaoudi",

note = "KAUST Repository Item: Exported on 2022-07-06 Acknowledgements: The research reported in this publication was supported by funding from the King Abdullah University of Science and Technology (KAUST).",

year = "2022",

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doi = "10.1021/acs.inorgchem.2c00756",

language = "English (US)",

journal = "Inorganic Chemistry",

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T1 - Reticular Chemistry for the Construction of Highly Porous Aluminum-Based nia-Metal–Organic Frameworks

AU - Alezi, Dalal

AU - Jia, Jiangtao

AU - Bhatt, Prashant

AU - Shkurenko, Aleksander

AU - Solovyeva, Vera

AU - Chen, Zhijie

AU - Belmabkhout, Youssef

AU - Eddaoudi, Mohamed

N1 - KAUST Repository Item: Exported on 2022-07-06 Acknowledgements: The research reported in this publication was supported by funding from the King Abdullah University of Science and Technology (KAUST).

PY - 2022/6/30

Y1 - 2022/6/30

N2 - Edge-transitive nets are regarded as appropriate blueprints for the practice of reticular chemistry, and in particular, for the rational design and synthesis of functional metal–organic frameworks (MOFs). Among edge-transitive nets, type I edge-transitive nets have unique coordination figures, offering only one edge-transitive target for their associated expressed net-cBUs. Here, we report the reticulation of the binodal edge-transitive (6, 6)-c nia net in MOF chemistry, namely, the deliberate assembly of trinuclear aluminum clusters and 6-connected hexacarboxylate ligands into highly porous nia-MOFs. Further studies reveal that Al-nia-MOF-1 shows promising attributes as a storage media for oxygen (O2) at high-pressure adsorption studies.

AB - Edge-transitive nets are regarded as appropriate blueprints for the practice of reticular chemistry, and in particular, for the rational design and synthesis of functional metal–organic frameworks (MOFs). Among edge-transitive nets, type I edge-transitive nets have unique coordination figures, offering only one edge-transitive target for their associated expressed net-cBUs. Here, we report the reticulation of the binodal edge-transitive (6, 6)-c nia net in MOF chemistry, namely, the deliberate assembly of trinuclear aluminum clusters and 6-connected hexacarboxylate ligands into highly porous nia-MOFs. Further studies reveal that Al-nia-MOF-1 shows promising attributes as a storage media for oxygen (O2) at high-pressure adsorption studies.

UR - http://hdl.handle.net/10754/679621

UR - https://pubs.acs.org/doi/10.1021/acs.inorgchem.2c00756

U2 - 10.1021/acs.inorgchem.2c00756

DO - 10.1021/acs.inorgchem.2c00756

M3 - Article

C2 - 35771949

SN - 0020-1669

JO - Inorganic Chemistry

JF - Inorganic Chemistry

ER -

Reticular Chemistry for the Construction of Highly Porous Aluminum-Based nia-Metal–Organic Frameworks

Abstract

Bibliographical note

ASJC Scopus subject areas

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