Remote stabilization of copper paddlewheel based molecular building blocks in metal-organic frameworks

Wenyang Gao; Rong Cai; Tony T. Pham; Katherine A. Forrest; Adam Hogan; Patrick S. Nugent; Kia R. Williams; Łukasz Wojtas; Ryan Luebke; Lukasz Jan Weselinski; Michael J. Zaworotko; Brian Space; Yusheng Chen; Mohamed Eddaoudi; Xiaodong Shi; Shengqian Ma

doi:10.1021/acs.chemmater.5b00084

Remote stabilization of copper paddlewheel based molecular building blocks in metal-organic frameworks

Wenyang Gao, Rong Cai, Tony T. Pham, Katherine A. Forrest, Adam Hogan, Patrick S. Nugent, Kia R. Williams, Łukasz Wojtas, Ryan Luebke, Lukasz Jan Weselinski, Michael J. Zaworotko, Brian Space, Yusheng Chen, Mohamed Eddaoudi, Xiaodong Shi, Shengqian Ma

Research output: Contribution to journal › Article › peer-review

74 Scopus citations

Abstract

Copper paddlewheel based molecular building blocks (MBBs) are ubiquitous and have been widely employed for the construction of highly porous metal-organic frameworks (MOFs). However, most copper paddlewheel based MOFs fail to retain their structural integrity in the presence of water. This instability is directly correlated to the plausible displacement of coordinating carboxylates in the copper paddlewheel MBB, [Cu2(O2C-)4], by the strongly coordinating water molecules. In this comprehensive study, we illustrate the chemical stability control in the rht-MOF platform via strengthening the coordinating bonds within the triangular inorganic MBB, [Cu3O(N4-x(CH)xC-)3] (x = 0, 1, or 2). Remotely, the chemical stabilization propagated into the paddlewheel MBB to afford isoreticular rht-MOFs with remarkably enhanced water/chemical stabilities compared to the prototypal rht-MOF-1. © 2015 American Chemical Society.

Original language	English (US)
Pages (from-to)	2144-2151
Number of pages	8
Journal	Chemistry of Materials
Volume	27
Issue number	6
DOIs	https://doi.org/10.1021/acs.chemmater.5b00084
State	Published - Mar 13 2015

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: The authors acknowledge NSF (DMR-1352065) and USF for financial support of this work. B.S. acknowledges the National Science Foundation (Award No. CHE-1152362), the computational resources that were made available by an XSEDE Grant (No. TG-DMR090028), and the use of the services provided by Research Computing at the University of South Florida. X.S. thanks NSF for the financial support (CHE-0844602). The single-crystal X-ray diffraction of rht-MOF-tri and rht-MOF-pyr was carried out at the Advanced Photon Source on beamline 15-ID-B of ChemMatCARS Sector 15, supported by the National Science Foundation under grant number NSF/CHE-1346572. This research used resources of the Advanced Photon Source, a U.S. Department of Energy (DOE) Office of Science User Facility operated for the DOE Office of Science by Argonne National Laboratory under Contract No. DE-AC02-06CH11357. M.E. acknowledges the financial support from King Abdullah University of Science and Technology.

ASJC Scopus subject areas

Materials Chemistry
General Chemical Engineering
General Chemistry

Access to Document

10.1021/acs.chemmater.5b00084

Cite this

Gao, W., Cai, R., Pham, T. T., Forrest, K. A., Hogan, A., Nugent, P. S., Williams, K. R., Wojtas, Ł., Luebke, R., Weselinski, L. J., Zaworotko, M. J., Space, B., Chen, Y., Eddaoudi, M., Shi, X., & Ma, S. (2015). Remote stabilization of copper paddlewheel based molecular building blocks in metal-organic frameworks. Chemistry of Materials, 27(6), 2144-2151. https://doi.org/10.1021/acs.chemmater.5b00084

@article{1c5ac6c0c8cb431dba04e7d062df4c21,

title = "Remote stabilization of copper paddlewheel based molecular building blocks in metal-organic frameworks",

abstract = "Copper paddlewheel based molecular building blocks (MBBs) are ubiquitous and have been widely employed for the construction of highly porous metal-organic frameworks (MOFs). However, most copper paddlewheel based MOFs fail to retain their structural integrity in the presence of water. This instability is directly correlated to the plausible displacement of coordinating carboxylates in the copper paddlewheel MBB, [Cu2(O2C-)4], by the strongly coordinating water molecules. In this comprehensive study, we illustrate the chemical stability control in the rht-MOF platform via strengthening the coordinating bonds within the triangular inorganic MBB, [Cu3O(N4-x(CH)xC-)3] (x = 0, 1, or 2). Remotely, the chemical stabilization propagated into the paddlewheel MBB to afford isoreticular rht-MOFs with remarkably enhanced water/chemical stabilities compared to the prototypal rht-MOF-1. {\textcopyright} 2015 American Chemical Society.",

author = "Wenyang Gao and Rong Cai and Pham, {Tony T.} and Forrest, {Katherine A.} and Adam Hogan and Nugent, {Patrick S.} and Williams, {Kia R.} and {\L}ukasz Wojtas and Ryan Luebke and Weselinski, {Lukasz Jan} and Zaworotko, {Michael J.} and Brian Space and Yusheng Chen and Mohamed Eddaoudi and Xiaodong Shi and Shengqian Ma",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: The authors acknowledge NSF (DMR-1352065) and USF for financial support of this work. B.S. acknowledges the National Science Foundation (Award No. CHE-1152362), the computational resources that were made available by an XSEDE Grant (No. TG-DMR090028), and the use of the services provided by Research Computing at the University of South Florida. X.S. thanks NSF for the financial support (CHE-0844602). The single-crystal X-ray diffraction of rht-MOF-tri and rht-MOF-pyr was carried out at the Advanced Photon Source on beamline 15-ID-B of ChemMatCARS Sector 15, supported by the National Science Foundation under grant number NSF/CHE-1346572. This research used resources of the Advanced Photon Source, a U.S. Department of Energy (DOE) Office of Science User Facility operated for the DOE Office of Science by Argonne National Laboratory under Contract No. DE-AC02-06CH11357. M.E. acknowledges the financial support from King Abdullah University of Science and Technology.",

year = "2015",

month = mar,

day = "13",

doi = "10.1021/acs.chemmater.5b00084",

language = "English (US)",

volume = "27",

pages = "2144--2151",

journal = "Chemistry of Materials",

issn = "0897-4756",

publisher = "American Chemical Society",

number = "6",

}

Gao, W, Cai, R, Pham, TT, Forrest, KA, Hogan, A, Nugent, PS, Williams, KR, Wojtas, Ł, Luebke, R, Weselinski, LJ, Zaworotko, MJ, Space, B, Chen, Y, Eddaoudi, M, Shi, X & Ma, S 2015, 'Remote stabilization of copper paddlewheel based molecular building blocks in metal-organic frameworks', Chemistry of Materials, vol. 27, no. 6, pp. 2144-2151. https://doi.org/10.1021/acs.chemmater.5b00084

TY - JOUR

T1 - Remote stabilization of copper paddlewheel based molecular building blocks in metal-organic frameworks

AU - Gao, Wenyang

AU - Cai, Rong

AU - Pham, Tony T.

AU - Forrest, Katherine A.

AU - Hogan, Adam

AU - Nugent, Patrick S.

AU - Williams, Kia R.

AU - Wojtas, Łukasz

AU - Luebke, Ryan

AU - Weselinski, Lukasz Jan

AU - Zaworotko, Michael J.

AU - Space, Brian

AU - Chen, Yusheng

AU - Eddaoudi, Mohamed

AU - Shi, Xiaodong

AU - Ma, Shengqian

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: The authors acknowledge NSF (DMR-1352065) and USF for financial support of this work. B.S. acknowledges the National Science Foundation (Award No. CHE-1152362), the computational resources that were made available by an XSEDE Grant (No. TG-DMR090028), and the use of the services provided by Research Computing at the University of South Florida. X.S. thanks NSF for the financial support (CHE-0844602). The single-crystal X-ray diffraction of rht-MOF-tri and rht-MOF-pyr was carried out at the Advanced Photon Source on beamline 15-ID-B of ChemMatCARS Sector 15, supported by the National Science Foundation under grant number NSF/CHE-1346572. This research used resources of the Advanced Photon Source, a U.S. Department of Energy (DOE) Office of Science User Facility operated for the DOE Office of Science by Argonne National Laboratory under Contract No. DE-AC02-06CH11357. M.E. acknowledges the financial support from King Abdullah University of Science and Technology.

PY - 2015/3/13

Y1 - 2015/3/13

N2 - Copper paddlewheel based molecular building blocks (MBBs) are ubiquitous and have been widely employed for the construction of highly porous metal-organic frameworks (MOFs). However, most copper paddlewheel based MOFs fail to retain their structural integrity in the presence of water. This instability is directly correlated to the plausible displacement of coordinating carboxylates in the copper paddlewheel MBB, [Cu2(O2C-)4], by the strongly coordinating water molecules. In this comprehensive study, we illustrate the chemical stability control in the rht-MOF platform via strengthening the coordinating bonds within the triangular inorganic MBB, [Cu3O(N4-x(CH)xC-)3] (x = 0, 1, or 2). Remotely, the chemical stabilization propagated into the paddlewheel MBB to afford isoreticular rht-MOFs with remarkably enhanced water/chemical stabilities compared to the prototypal rht-MOF-1. © 2015 American Chemical Society.

AB - Copper paddlewheel based molecular building blocks (MBBs) are ubiquitous and have been widely employed for the construction of highly porous metal-organic frameworks (MOFs). However, most copper paddlewheel based MOFs fail to retain their structural integrity in the presence of water. This instability is directly correlated to the plausible displacement of coordinating carboxylates in the copper paddlewheel MBB, [Cu2(O2C-)4], by the strongly coordinating water molecules. In this comprehensive study, we illustrate the chemical stability control in the rht-MOF platform via strengthening the coordinating bonds within the triangular inorganic MBB, [Cu3O(N4-x(CH)xC-)3] (x = 0, 1, or 2). Remotely, the chemical stabilization propagated into the paddlewheel MBB to afford isoreticular rht-MOFs with remarkably enhanced water/chemical stabilities compared to the prototypal rht-MOF-1. © 2015 American Chemical Society.

UR - http://hdl.handle.net/10754/564111

UR - https://pubs.acs.org/doi/10.1021/acs.chemmater.5b00084

UR - http://www.scopus.com/inward/record.url?scp=84925737770&partnerID=8YFLogxK

U2 - 10.1021/acs.chemmater.5b00084

DO - 10.1021/acs.chemmater.5b00084

M3 - Article

SN - 0897-4756

VL - 27

SP - 2144

EP - 2151

JO - Chemistry of Materials

JF - Chemistry of Materials

IS - 6

ER -

Remote stabilization of copper paddlewheel based molecular building blocks in metal-organic frameworks

Abstract

Bibliographical note

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

CCDC 884202: Experimental Crystal Structure Determination : catena-[hexakis(mu-4-(3,5-dicarboxylatophenyl)-2H-1,2,3-triazol-2-yl)-bis(mu-oxo)-tetracosaoxo-dodeca-copper unknown solvate]

CCDC 1061183: Experimental Crystal Structure Determination : catena-[hexakis(mu-4-(3,5-dicarboxylatophenyl)pyrazolato)-bis(mu-oxo)-dodecaoxo-dodeca-copper unknown solvate]

Cite this

Remote stabilization of copper paddlewheel based molecular building blocks in metal-organic frameworks

Abstract

Bibliographical note

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Datasets

CCDC 884202: Experimental Crystal Structure Determination : catena-[hexakis(mu-4-(3,5-dicarboxylatophenyl)-2H-1,2,3-triazol-2-yl)-bis(mu-oxo)-tetracosaoxo-dodeca-copper unknown solvate]

CCDC 1061183: Experimental Crystal Structure Determination : catena-[hexakis(mu-4-(3,5-dicarboxylatophenyl)pyrazolato)-bis(mu-oxo)-dodecaoxo-dodeca-copper unknown solvate]

Cite this