Regiodivergent Hydroborative Ring Opening of Epoxides via Selective C-O Bond Activation.

Keyphrases

• C-O Bond Activation 100%
• Epoxide Ring Opening 100%
• Regiodivergent 100%
• Secondary Alcohols 33%
• Epoxides 33%
• Oxetane 33%
• Regioselectivity 33%
• DFT Calculations 33%
• Product Formation 33%
• Excellent Yields 33%
• Mechanistic Investigation 33%
• Magnesium 33%
• C-O Bond Cleavage 33%
• Hydroboration 33%
• Tertiary Alcohols 33%
• Magnesium Catalyst 33%

Chemistry

• Epoxide 100%
• Ring Opening Reaction 100%
• Magnesium 100%
• Secondary Alcohol 50%
• Density Functional Theory 50%
• Regioselectivity 50%
• Tertiary Alcohol 50%
• Oxetane 50%
• Hydroboration 50%