Redox mediation enabled by immobilised centres in the pores of a metal–organic framework grown by liquid phase epitaxy

André Dragässer, Osama Shekhah, Olexandra Zybaylo, Cai Shen, Manfred Buck, Christof Wöll, Derck Schlettwein*

*Corresponding author for this work

    Research output: Contribution to journalArticlepeer-review

    89 Scopus citations

    Abstract

    A layer of a metal–organic framework (SURMOF) was prepared on a thiol monolayer on Au. Charge transport across the insulating membrane could be established by using ferrocene as an immobilised redox mediator. Reversibility of the immobilisation and its role in the electrode kinetics are discussed.

    Original languageEnglish (US)
    Pages (from-to)663-665
    Number of pages3
    JournalCHEMICAL COMMUNICATIONS
    Volume48
    Issue number5
    DOIs
    StatePublished - Dec 12 2012

    ASJC Scopus subject areas

    • Catalysis
    • Electronic, Optical and Magnetic Materials
    • Ceramics and Composites
    • General Chemistry
    • Surfaces, Coatings and Films
    • Metals and Alloys
    • Materials Chemistry

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