Abstract
As promising alternatives to lithium-ion batteries, rechargeable anion-shuttle batteries (ASBs) with anions as charge carriers stand out because of their low cost, long cyclic lifetime, and/or high energy density. In this review, we provide for the first time, comprehensive insights into the anion shuttling mechanisms of ASBs, including anion-based rocking-chair batteries (ARBs), dual-ion batteries (DIBs), including insertion-type, conversion-type, and conversion-insertion-type, and reverse dual-ion batteries (RDIBs). Thereafter, we review the latest progresses and challenges regarding electrode materials and electrolytes for ASBs. In addition, we summarize the existing dilemmas of ASBs and outline the perspective of ASB technology for future grid storage.
Original language | English (US) |
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Pages (from-to) | 1993-2021 |
Number of pages | 29 |
Journal | Chem |
Volume | 7 |
Issue number | 8 |
DOIs | |
State | Published - Aug 12 2021 |
Bibliographical note
Funding Information:B.L. would like to acknowledge the support by National Nature Science Foundation of China ( 51872157 and 52072208 ), Shenzhen Technical Plan Project ( JCYJ20170412170911187 and JCYJ20170817161753629 ), Special Fund Project for Strategic Emerging Industry Development of Shenzhen ( 20170428145209110 ), Guangdong Technical Plan Project ( 2017B090907005 ), and Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program ( 2017BT01N111 ). Devices Testing Center in Tsinghua Shenzhen International Graduate School was also gratefully acknowledged. G.W. would like to acknowledge the support by the Australian Research Council (ARC) Discovery projects ( DP170100436 , DP180102297 , and DP200101249 ). X.J. is grateful for the financial support from U.S. National Science Foundation awards DMR-2004636 and CBET-1551693 .
Publisher Copyright:
© 2021 Elsevier Inc.
Keywords
- anion-shuttle batteries
- dual-ion batteries
- grid energy storages
- reverse dual-ion batteries
- rocking-chair batteries
- SDG7: Affordable and clean energy
ASJC Scopus subject areas
- General Chemistry
- Biochemistry
- Environmental Chemistry
- General Chemical Engineering
- Biochemistry, medical
- Materials Chemistry