Real-time field measurements of stable isotopes in water and CO₂ by Fourier transform infrared spectrometry

Continuous records of isotope behaviour in the environment are invaluable to understanding mass and energy fluxes. Although techniques such as isotope ratio mass spectrometry provide high precision data, they are not well suited to the analysis of a large number of samples and are currently restricted to use in the laboratory. Fourier transform infrared spectrometers are relatively cheap and sufficiently portable and robust to be taken into the field to collect continuous records of gas-phase isotope behaviour. Several examples of the application of this technique will be presented. One data set provides half-hourly determinations of vertical profiles of D/H in water vapour above agricultural fields over a 3-week period; the same infrared spectra can also be used to determine ¹³C/¹²C in CO₂. The technique has also been applied to the study of CO₂ in ambient air and in a limestone cave system. Some of the features and complications associated with the method will also be considered.